Patent application number | Description | Published |
20100130709 | Procatalyst Composition Including Silyl Ester Internal Donor and Method - The present disclosure provides silyl esters and silyl diol esters suitable as internal electron donors in procatalysts for polymer production. Disclosed are procatalyst compositions formed from a procatalyst precursor and an internal electron donor that is a silyl ester or a silyl diol ester. The procatalyst compositions can be used with a cocatalyst and optionally an external electron donor and/or an activity limiting agent to form a Ziegler-Nana catalyst composition. The present catalyst compositions exhibit high catalyst activity and form olefin-based polymers with broad molecular weight distribution, favorable flexural modulus, and high isotacticity. | 05-27-2010 |
20100174105 | Production of Substituted Phenylene Aromatic Diesters - The present disclosure is directed to the production of 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate and the purification thereof. Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate are provided. The precursor is 5-tert-butyl-3-methylcatechol. | 07-08-2010 |
20100204506 | Production of Substituted Phenylene Aromatic Diesters and Compositions - The present disclosure provides processes for the production of substituted phenylene aromatic diesters and the resultant compositions. The processes include reacting an aromatic diol with an aromatic carboxylic acid or a derivative thereof. The aromatic diol and/or the aromatic carboxylic acid (or derivative thereof) is/are substituted. The reaction forms a substituted phenylene aromatic diester with the structure (II): | 08-12-2010 |
20100222530 | Procatalyst Composition with Substitute 1,2-Phenylene Aromatic Diester Internal Donor and Method - Disclosed are procatalyst compositions having an internal electron donor which include a substituted phenylene aromatic diester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit high activity and produce propylene-based olefins with broad molecular weight distribution. | 09-02-2010 |
20100267911 | Procatalyst Composition with Silyl Glutarate and Method - Disclosed are procatalyst compositions having an internal electron donor which includes a silyl glutarate and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit strong activity and produce propylene-based olefins with high isotacticity. | 10-21-2010 |
20100273966 | Procatalyst Composition with Adamantane and Method - Disclosed are procatalyst compositions having an internal electron donor which includes an adamantanedicarboxylate and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions produce propylene-based olefins with broad molecular weight distribution. | 10-28-2010 |
20100301059 | Thermoformed Article with High Stiffness and Good Optics - Disclosed are thermoformed articles composed of propylene homopolymer containing a substituted phenylene aromatic diester. The thermoformed articles have high stiffness, good compression strength, excellent processability, and excellent optics. | 12-02-2010 |
20110130529 | THREE AND FOUR ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE - A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: | 06-02-2011 |
20110130530 | TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE - A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: | 06-02-2011 |
20120157295 | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product - Disclosed herein are processes for preparing procatalyst compositions with an internal electron donor containing greater than 4.5 wt % of a compounded alkoxyalkyl ester. Also disclosed are catalyst compositions containing the procatalyst composition and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions improve catalyst selectivity, catalyst activity, procatalyst morphology and polymer particle morphology, and improve hydrogen response during olefin polymerization. | 06-21-2012 |
20120157296 | Catalyst Composition with Halo-Malonate Internal Electron Donor and Polymer From Same - Disclosed herein are procatalyst compositions, catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions contain a halo-malonate and a 2-fluoro-malonate in particular. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and also improve hydrogen response during polymerization. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 50 g/10 min. | 06-21-2012 |
20120157643 | Procatalyst Composition with Alkoxyalkyl 2-Propenoate Internal Electron Donor and Polymer from Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions contain an internal electron donor of an alkoxyalkyl 2-propenoate and optionally a mixed external electron donor. The present catalyst compositions improve catalyst selectivity and polymer stiffness. Polypropylene homopolymer produced from the present catalyst composition has a xylene solubles content less than 4 wt % and a T | 06-21-2012 |
20120157645 | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions include an internal electron donor with an alkoxypropyl ester. The present catalyst compositions improve catalyst selectivity. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 4 g/10 min. | 06-21-2012 |
20120316299 | Amide Ester Internal Electron Donor and Process - Disclosed is a process for producing a procatalyst composition having an amide ester internal electron donor. The process includes pre-halogenating a procatalyst precursor before reaction with the amide ester and forming the procatalyst composition. Ziegler-Natta catalyst compositions containing the present procatalyst composition exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 12-13-2012 |
20120322962 | Procatalyst Composition with Substituted Amide Ester Internal Electron Donor - Disclosed are procatalyst compositions having an internal electron donor which includes a substituted amide ester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 12-20-2012 |
20120322964 | Halogenated Amide Ester and Internal Electron Donor with Same - Disclosed are halogenated amide esters that are suitable as internal electron donors in procatalyst compositions. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 12-20-2012 |
20130035227 | Procatalyst Composition with Substituted 1,2-Phenylene Aromatic Diester Internal Donor and Method - Disclosed are procatalyst compositions having an internal electron donor which include a substituted phenylene aromatic diester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit high activity and produce propylene-based olefins with broad molecular weight distribution. | 02-07-2013 |
20130053525 | Production of Substituted Phenylene Dibenzoate Internal Electron Donor and Procatalyst with Same - The present disclosure is directed to the production of substituted phenylene aromatic diesters and 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate (or “BMPD”) in particular. The processes disclosed herein produce a liquid BMPD product. The liquid BMPD product unexpectedly creates production efficiencies by reducing the number of production steps, reducing the amount and/or number of reagents required for BMPD production. The liquid BMPD product may also be utilized in procatalyst production yielding similar production efficiencies. The procatalyst composition is subsequently used for olefin polymerization. | 02-28-2013 |
20130150234 | Catalyst Composition with Halo-Malonate Internal Electron Donor and Polymer From Same - Disclosed herein are procatalyst compositions, catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions contain a halo-malonate and a 2-fluoro-malonate in particular. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and also improve hydrogen response during polymerization. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 50 g/10 min. | 06-13-2013 |
20130225398 | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product - Disclosed herein are processes for preparing procatalyst compositions with an internal electron donor containing greater than 4.5 wt % of a compounded alkoxyalkyl ester. Also disclosed are catalyst compositions containing the procatalyst composition and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions improve catalyst selectivity, catalyst activity, procatalyst morphology and polymer particle morphology, and improve hydrogen response during olefin polymerization. | 08-29-2013 |
20130245306 | TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE - A compound suitable for use as an internal electron donor having a structure: | 09-19-2013 |
20130261273 | Process for Production of High Melt Flow Propylene-Based Polymer and Product from Same - Disclosed are catalyst compositions having an internal electron donor which includes a 3,6-di-substituted-1,2-phenylene aromatic diester. Ziegler-Natta catalyst compositions containing the present catalyst compositions exhibit very high hydrogen response, high activity, high selectivity and produce propylene-based olefins with high melt flow rate. | 10-03-2013 |
20130289228 | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer from Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions include an internal electron donor with an alkoxypropyl ester. The present catalyst compositions improve catalyst selectivity. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 4 g/10 min. | 10-31-2013 |
20140012035 | Production of Substituted Phenylene Aromatic Diesters - Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1, 2-phenylene dibenzoate are provided. The precursor is methylcatechol and/or 5-tert-butyl-3-methylcatechol. | 01-09-2014 |
20140046009 | Procatalyst Composition with Alkoxyalkyl 2-Propenoate Internal Electron Donor and Polymer from Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions contain an internal electron donor of an alkoxyalkyl 2-propenoate and optionally a mixed external electron donor. The present catalyst compositions improve catalyst selectivity and polymer stiffness. Polypropylene homopolymer produced from the present catalyst composition has a xylene solubles content less than 4 wt % and a T | 02-13-2014 |
20140163184 | Procatalyst Composition with Substituted Amide Ester Internal Electron Donor - Disclosed are procatalyst compositions having an internal electron donor which includes a substituted amide ester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 06-12-2014 |