Patent application number | Description | Published |
20090012339 | Catalytic Cracking Process Using Fast Fluidization for the Production of Light Olefins from Hydrocarbon Feedstock - Disclosed is a catalytic cracking process for the production of light olefins from a hydrocarbon feedstock using fast fluidization, which is a preferred process for more efficiently increasing the production of light olefin hydrocarbons. According to this invention, a fast fluidization regime is applied to a fluidized bed catalytic cracking process of producing light olefins using zeolite, such that a volume fraction and distribution of the catalyst sufficient to induce the catalytic cracking reaction can be provided, thus effectively enhancing the production of light olefin hydrocarbons, in particular, ethylene and propylene, at high selectivity. | 01-08-2009 |
20090018291 | METHOD OF REGENERATION OF TITANIUM-CONTAINING MOLECULAR SIEVE CATALYST - Disclosed herein is a method of regenerating a titanium-containing molecular sieve catalyst. Particularly, this invention provides a method of regenerating a titanium-containing molecular sieve catalyst used in epoxidation of olefin through simple treatment using a mixture solvent comprising aqueous hydrogen peroxide and alcohol. According to the method of this invention, when the catalyst having decreased activity is regenerated, the activity of the regenerated catalyst is equal to that of new catalyst and can be maintained stable for a long period of time. | 01-15-2009 |
20090088594 | BISMUTH MOLYBDATE-BASED CATALYSTS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING 1,3-BUTADIENE USING THEREOF - This invention relates to a bismuth molybdate catalyst, a preparation method thereof, and a method of preparing 1,3-butadiene using the same, and to a bismuth molybdate catalyst, a preparation method thereof, and a method of preparing 1,3-butadiene using the same, in which 1,3-butadiene can be prepared through oxidative dehydrogenation directly using a C4 mixture including n-butene and n-butane as a reactant in the presence of a mixed-phase bismuth molybdate catalyst including α-bismuth molybdate (Bi2Mo3On) and γ-bismuth molybdate (Bi2MoO6). According to this invention, the C4 raffinate, containing many impurities, is used as a reactant, without an additional n-butane separation process, thus obtaining 1,3-butadiene at high yield. Unlike complicated multicomponent-based metal oxides, the catalyst of the invention has simple constituents and synthesis routes, and can be easily formed through physical mixing, and thus is very advantageous in assuring reproducibility and can be directly applied to commercial processes. | 04-02-2009 |
20090326175 | ARYLPHENOXY CATALYST SYSTEM FOR PRODUCING ETHYLENE HOMOPOLYMER OR COPOLYMERS OF ETHYLENE AND a-OLEFINS - The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes. | 12-31-2009 |
20100121123 | ZINC FERRITE CATALYSTS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING 1,3-BUTADIENE USING THEREOF - The present invention relates to a zinc ferrite catalyst, a method of producing the same, and a method of preparing 1,3-butadiene using the same. Specifically, the present invention relates to a zinc ferrite catalyst which is produced in a pH-adjusted solution using a coprecipitation method, a method of producing the same, and a method of preparing 1,3-butadiene using the same, in which the 1,3-butadiene can be prepared directly using a C4 mixture including n-butene and n-butane through an oxidative dehydrogenation reaction. The present invention is advantageous in that 1,3-butadiene can be obtained at a high yield directly using a C4 fraction without performing an additional process for separating n-butene, as a reactant, from a C4 fraction containing impurities. | 05-13-2010 |
20100125161 | METHOD OF PREPARING MULTICOMPONENT BISMUTH MOLYBRDATE CATALYSTS WITH CONTROLLING PH AND A METHOD OF PREPARING 1,3-BUTADIENE USING THEREOF - This invention relates to a method of preparing a multicomponent bismuth molybdate catalyst by changing the pH of a coprecipitation solution upon coprecipitation and a method of preparing 1,3-butadiene using the catalyst. The multicomponent bismuth molybdate catalyst, coprecipitated using a solution having an adjusted pH, the preparation method thereof, and the method of preparing 1,3-butadiene through oxidative dehydrogenation using a C4 mixture including n-butene and n-butane as a reactant are provided. The C4 raffinate, containing many impurities, is directly used as a reactant without an additional process for separating n-butane or extracting n-butene, thus obtaining 1,3-butadiene at high yield. The activity of the multicomponent bismuth molybdate catalyst can be simply increased through precise pH adjustment upon coprecipitation, which is not disclosed in the conventional techniques. This method can be applied to the increase in the activity of multicomponent bismuth molybdate catalysts reported in the art. | 05-20-2010 |
20100137664 | PROCESS FOR 1,3-BUTADIENE SEPARATION FROM A CRUDE C4 STREAM WITH ACETYLENE CONVERTER - Disclosed is a method of recovering 1,3-butadiene from a C4 stream containing butane, isobutane, 2-butene, 1-butene, isobutene, butadiene and acetylene. The process of recovering highly pure 1,3-butadiene includes acetylene conversion for selectively converting acetylene through liquid-phase hydrogenation, so that the acetylene content is decreased to 70 wt ppm or less, and 1,3-butadiene extraction using an extractive distillation column, a pre-separator, a solvent stripping column, a solvent recovery column, and a purification column. Through the acetylene conversion, the concentration of vinylacetylene is decreased to 70 wt ppm or less, after which 1,3-butadiene is recovered using only one extractive distillation column, thereby considerably decreasing the degree of utility and the loss of streams in the course of extraction. The number of units necessary for the process is decreased, thus remarkably reducing the time during which impurities can accumulate in a processing unit. | 06-03-2010 |
20100280300 | MIXED MANGANESE FERRITE CATALYSTS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING 1,3-BUTADIENE USING THEREOF - A method of producing a mixed manganese ferrite catalyst, and a method of preparing 1,3-butadiene using the mixed manganese ferrite catalyst. Specifically, a method of producing a mixed manganese ferrite catalyst through a coprecipitation method which is performed at a temperature of 10˜40° C., and a method of preparing 1,3-butadiene using the mixed manganese ferrite catalyst through an oxidative dehydrogenation reaction, in which a C4 mixture containing n-butene, n-butane and other impurities is directly used as reactants without performing additional n-butane separation process or n-butene extraction. 1,3-butadiene can be prepared directly using a C4 mixture including n-butane at a high concentration as a reactant through an oxidative hydrogenation reaction without performing an additional n-butane separation process, and 1,3-butadiene, having high activity, can be also obtained in high yield for a long period of time. | 11-04-2010 |
20110004041 | METHOD OF PRODUCING 1,3-BUTADIENE FROM N-BUTENE USING CONTINUOUS-FLOW DUAL-BED REACTOR - A method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a continuous-flow dual-bed reactor designed such that two kinds of catalysts charged in a fixed-bed reactor are not physically mixed. More particularly, a method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a C4 mixture including n-butene and n-butane as reactants and using a continuous-flow dual-bed reactor in which a multi-component bismuth molybdate catalyst and a zinc ferrite catalyst having different reaction activity in the oxidative dehydrogenation reaction of n-butene isomers (1-butene, trans-2-butene, cis-2-butene). | 01-06-2011 |
20110207979 | METHOD FOR PRODUCING HIGH VALUE AROMATICS AND OLEFIN FROM LIGHT CYCLE OIL PRODUCED BY A FLUIDIZED CATALYTIC CRACKING PROCESS - The present invention relates to a method of producing aromatic products (benzene/toluene/xylene) and olefin products from petroleum fractions obtained by fluid catalytic cracking, and, more particularly, to a method of producing products comprising high-concentration aromatic products and high value-added light olefin products from light cycle oil obtained by fluid catalytic cracking. | 08-25-2011 |
20130004411 | POLYELECTROLYTE MULTILAYER THIN FILM CATALYST AND METHOD FOR PRODUCING SAME - Disclosed herein is a catalyst, including, in one example: a carrier, a polymer electrolyte multilayer film formed on the carrier, and metal particles dispersed in the polymer electrolyte multilayer film. The catalyst can be easily prepared, and can be used to produce hydrogen peroxide in high yield in the presence of a reaction solvent including no acid promoter. | 01-03-2013 |
20130030231 | CATALYST FOR A HYDROGENATION DEWAXING PROCESS AND METHOD FOR MANUFACTURING SAME - The present invention relates to a bifunctional catalyst for a hydrodewaxing process with improved isomerization selectivity, and to a method for manufacturing the same, and more particularly to a bifunctional catalyst and to a method for manufacturing same, which is characterized in that EU-2 zeolite with a controlled degree of phase transformation is used as a catalyst support having an acid site. The EU-2 zeolite, the degree of phase transformation of which is controlled, includes, by controlling synthesis parameters of EU-2, predetermined amounts of materials that are phase-transformed from EU-2 crystals such as cristobalite and quartz. The metal loaded bifunctional catalyst according to the present invention improves selectivity of the isomerization process, rather than a cracking reaction, during a hydroisomerization reaction of n-hexadecane. Therefore, the bifunctional catalyst can be widely used as a catalyst for a dewaxing process such as lubricant base oil and diesel oil. | 01-31-2013 |
20130143733 | CATALYST FOR AQUEOUS PHASE REFORMING OF BIOMASS-DERIVED POLYOLS AND PREPARATION METHOD THEREOF - Disclosed herein is a catalyst for aqueous-phase reforming of biomass-derived polyols, which comprises platinum and copper as active metals and a mixture of magnesia and alumina as a support. The catalyst contains a small amount of platinum and, at the same time, has high hydrogen selectivity and low methane selectivity. | 06-06-2013 |
20130158325 | MIXED MANGANESE FERRITE COATED CATALYST, METHOD OF PREPARING THE SAME, AND METHOD OF PREPARING 1,3-BUTADIENE USING THE SAME - This invention relates to a method of preparing a mixed manganese ferrite coated catalyst, and a method of preparing 1,3-butadiene using the same, and more particularly, to a method of preparing a catalyst by coating a support with mixed manganese ferrite obtained by co-precipitation at 10˜40° C. using a binder and to a method of preparing 1,3-butadiene using oxidative dehydrogenation of a crude C4 mixture containing n-butene and n-butane in the presence of the prepared catalyst. This mixed manganese ferrite coated catalyst has a simple synthetic process, and facilitates control of the generation of heat upon oxidative dehydrogenation and is very highly active in the dehydrogenation of n-butene. | 06-20-2013 |
20140012026 | Adsorbents for the Recovery of Catalyst from Block Co-Polymer Process and Method for Regenerating of the Same - Provided is a process for isolating a catalyst from a solution having a copolymer and a catalyst dissolved therein, after performing copolymerization with the catalyst. More specifically the invention provides selection and application of an adsorbent to be used for the isolation. | 01-09-2014 |
20140213431 | CATALYST FOR CATALYTIC CRACKING OF HYDROCARBON, WHICH IS USED IN PRODUCTION OF LIGHT OLEFIN AND PRODUCTION METHOD THEROF - Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01˜5.0 wt % of MnO | 07-31-2014 |
20140275671 | METHOD OF PRODUCING AROMATIC HYDROCARBONS AND OLEFIN FROM HYDROCARBONACEOUS OILS COMPRISING LARGE AMOUNTS OF POLYCYCLIC AROMATIC COMPOUNDS - This invention relates to a method of producing aromatic hydrocarbons and olefin from hydrocarbonaceous oils including large amounts of polycyclic aromatic compounds having two or more rings via partial hydrogenation in the presence of a hydrogenation catalyst and catalytic cracking in the presence of a catalytic cracking catalyst. | 09-18-2014 |
20140367310 | CATALYST FOR A HYDRODGENATION DEWAXING PROCESS AND METHOD FOR MANUFACTURING SAME - The present invention relates to a bifunctional catalyst for a hydrodewaxing process with improved isomerization selectivity, and to a method for manufacturing the same, and more particularly to a bifunctional catalyst and to a method for manufacturing same, which is characterized in that EU-2 zeolite with a controlled degree of phase transformation is used as a catalyst support having an acid site. The EU-2 zeolite, the degree of phase transformation of which is controlled, includes, by controlling synthesis parameters of EU-2, predetermined amounts of materials that are phase-transformed from EU-2 crystals such as cristobalite and quartz. The metal loaded bifunctional catalyst according to the present invention improves selectivity of the isomerization process, rather than a cracking reaction, during a hydroisomerization reaction of n-hexadecane. Therefore, the bifunctional catalyst can be widely used as a catalyst for a dewaxing process such as lubricant base oil and diesel oil. | 12-18-2014 |