Patent application number | Description | Published |
20080249231 | Soft homogeneous isotactic polypropylene compositions - The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent. | 10-09-2008 |
20080249232 | Soft heterogeneous isotactic polypropylene compositions - The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent. | 10-09-2008 |
20080249248 | Isotactic Polypropylene Nucleation - Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % α-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method. | 10-09-2008 |
20090053959 | Soft and Elastic Nonwoven Polypropylene Compositions - This invention relates to a nonwoven fabric having a first component of from 5% to 99% by weight based on the total weight of the composition wherein the first component is selected from the group consisting of homopolymers of propylene and random copolymers of propylene, the first component having a heat of fusion as determined by DSC of less than 50 J/g and stereoregular propylene crystallinity; and a second component having from 95% to 1% by weight based on the total weight of the composition of a propylene polymer or blends of propylene polymers; wherein the nonwoven fabric has a permanent set of less than 60%. | 02-26-2009 |
20090076216 | IN-LINE PROCESS FOR PRODUCING PLASTICIZED POLYMERS AND PLASTICIZED POLYMER BLENDS - A process for fluid phase in-line blending of plasticized polymers is provided. The process includes providing two or more reactor trains configured in parallel and a separator for product blending and product-feed separation, wherein one or more of the reactor trains produces one or more polymers and one or more of the reactor trains produces one or more plasticizers; contacting in at least one of the parallel reactor trains olefin monomers, catalyst systems, optional comonomers, optional scavengers, and optional diluents or solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa; forming a reactor effluent including a homogeneous fluid phase polymer-monomer mixture and plasticizer-monomer mixture in each parallel reactor train; passing the reactor effluents through the separator; maintaining the temperature and pressure within the separator above the solid-fluid phase transition point but below the cloud point pressure and temperature to form a fluid-fluid two-phase system including a plasticized polymer-rich blend phase and a monomer-rich phase; and separating the monomer-rich phase from the plasticized polymer-rich blend phase. The polymer-rich blend phase is conveyed to a downstream finishing stage for further monomer stripping, drying and/or pelletizing to form a plasticized polymer product blend. Suitable plasticizers for in-line production and blending include polyalphaolefin oligomers, polybutenes, low glass transition temperature polymers and combinations thereof. | 03-19-2009 |
20090111945 | Soft Homogeneous Isotactic Polypropylene Compositions - Provided are homogeneous blend compositions comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230C) of the first polymer component is between 300 g/10 min to 5000 g/1 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent. The provided compositions are useful in high temperature applications. | 04-30-2009 |
20090111946 | Soft Heterogeneous Isotactic Polypropylene Compositions - Provided are heterogeneous blend compositions comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230 C) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent. The provided compositions are useful in high temperature applications. | 04-30-2009 |
20090156729 | Polypropylene-Based Adhesive Compositions - An adhesive blend is described that can include a semi-crystalline copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and at least one C | 06-18-2009 |
20090270545 | Propylene Copolymers In Soft Thermoplastic Blends - Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles. | 10-29-2009 |
20100029162 | EXTENSIBLE POLYPROPYLENE-BASED NONWOVENS - Disclosed herein is a nonwoven fabric comprising within the range of from 50 to 99 wt %, by weight of the composition, of a reactor grade propylene-α-olefin copolymer possessing within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C | 02-04-2010 |
20100029164 | Soft Polypropylene-Based Nonwovens - Disclosed herein is a nonwoven fabric comprising within the range of from 1 to 49 wt %, by weight of the fabric, of a reactor grade propylene-α-olefin copolymer possessing; within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C | 02-04-2010 |
20100273692 | Ethylene-Based Copolymers, Lubricating Oil Compositions Containing the Same, and Methods for Making Them - Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include less than about 80 wt. % of units derived from ethylene and one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers have a melting peak (Tm), as measured by DSC, of 80° C. or less, and a polydispersity index of about 2.8 or less. In some embodiments, the ethylene-based copolymers have an intramolecular composition distribution of about 50 wt. % or less and/or an intermolecular composition distribution of about 50 wt. % or less. | 10-28-2010 |
20100273693 | Polymeric Compositions Useful as Rheology Modifiers and Methods for Making Such Compositions - Disclosed are rheology modifiers comprising compositionally disperse polymeric compositions and/or crystallinity disperse polymeric compositions that may be useful in modifying the rheological properties of lubrication fluids, and methods for making such compositions. The compositionally disperse polymeric composition are formed from at least two discrete compositions of ethylene copolymers. The crystallinity disperse polymeric composition are formed from ethylene copolymers having at least two discrete values of residual crystallinity. | 10-28-2010 |
20110183879 | Lubricating Oil Compositions and Method for Making Them - Provided are ethylene propylene copolymers compositions thereof and methods for making the same. The composition may include an ethylene copolymer, comprising 40 wt % to 70 wt % of units derived from ethylene, and at least 30 wt % of units derived from at least one α-olefin having 3 to 20 carbon atoms. The composition can have a melting point (Tm) in ° C., as measured by DSC, that satisfies the relation: Tm>3.4×E−180, where E is the weight % of units derived from ethylene in the copolymer. The composition can also have a Mw/Mn ratio of about 1.5 to about 3.5. The composition can further have a content of Group 4 metals derived from a catalyst of 25 ppm or less. | 07-28-2011 |
20110184134 | Copolymers, Compositions Thereof, and Methods for Making Them - Provided are amorphous ethylene propylene copolymer, compositions thereof, and methods for making same, whereby the copolymer can include of from about 40 wt. % to about 60 wt. % ethylene derived units; and of from about 60 wt. % to about 40 wt. % propylene derived units. The copolymer can be characterized by having no discernable melting point as measured by DSC, an MFRR (MI (2.16 kg; 230° C.)/MI 21.6 kg; 230° C.) of about 38 or more, a molecular weight distribution (MWD) of from about 1.5 to about 2.5, and a shear viscosity η* at 0.01 rad/sec measured at 70° C. that satisfies the relation |η*| | 07-28-2011 |
20110207637 | Vicinally Disubstituted Internal Olefins as Constituents of Olefin Copolymers for Lubricating Oil Rheology Modifiers - This invention relates to an ethylene copolymer for lubricating oil, comprising: ethylene; at least one alpha-olefin having 3 or more carbon atoms; and at least one vicinally substituted olefin having 2 to 40 carbon atoms, wherein: the copolymer has a weight-average molecular weight (Mw) of about 50,000 to about 500,000; and an intensity ratio of S | 08-25-2011 |
20110313117 | Propylene Ethylene Polymers And Production Process - Ethylene propylene copolymers, substantially free of diene, are described. The copolymers will have a uniform distribution of both tacticity and comonomer between copolymer chains. Further, the copolymers will exhibit a statistically insignificant intramolecular difference of tacticity. The copolymers are made in the presence of a metallocene catalyst. | 12-22-2011 |
20120028865 | Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers - The present invention is directed to polymer blend compositions for use as viscosity modifiers comprising at least three ethylene-based copolymer components. The viscosity modifiers described herein comprise a first ethylene-based copolymer having an ethylene content of from about 35 to about 55 wt % and/or a heat of fusion of from about 0 to about 30 J/g, a second ethylene-based copolymer having an ethylene content of from about 55 to about 85 wt % and/or a heat of fusion of from about 30 to about 50 J/g, and a third ethylene-based copolymer having an ethylene content of from about 65 to about 85 wt % and/or a heat of fusion of from about 40 to about 70 J/g. The invention is also directed to lubricant compositions comprising a lubricating basestock and a polymer blend as described herein. | 02-02-2012 |
20120028866 | Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers - The present invention is directed to polymer blend compositions for use as viscosity modifiers comprising at least two ethylene-based copolymer components. The viscosity modifiers described herein comprise a first ethylene-based copolymer having an ethylene content of from about 44 to about 52 wt % and/or a heat of fusion of from about 0 to about 15 J/g and a second ethylene-based copolymer having an ethylene content of from about 68 to about 75 wt % and/or a heat of fusion of from about 40 to about 65 J/g. The invention is also directed to lubricant compositions comprising a lubricating basestock and a polymer blend of the invention. | 02-02-2012 |
20120028867 | Ethylene Based Copolymer Compositions as Viscosity Modifiers and Methods for Making Them - Polymeric compositions and methods for making and using the same are provided. The polymeric composition can include a first ethylene-based copolymer and a second ethylene-based copolymer. The first ethylene-based copolymer can have a weight percent of ethylene-derived units based on a weight of the polymeric composition (E | 02-02-2012 |
20120196497 | EXTENSIBLE POLYPROPYLENE-BASED NONWOVENS - Disclosed herein is a nonwoven fabric comprising within the range of from 50 to 99 wt %, by weight of the composition, of a reactor grade propylene-α-olefin copolymer possessing within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C | 08-02-2012 |
20120319318 | Cooling And Pelletizing Process For Semi-Crystalline Polymers - Methods and systems for pelletizing low molecular weight semi-crystalline polymers are provided herein. Polymer compositions comprising the semi-crystalline polymer and a solvent are provided to a devolatilizing device, where the solvent is at least partially evaporated under vacuum conditions, resulting in removal of heat from the polymer by evaporative cooling and crystallization of the polymer. Once the polymer has reached the desired temperature, the polymer exits the devolatilizer and is pelletized. Semi-crystalline polymers that may be used in the present invention include propylene-based copolymers, such as propylene-ethylene and propylene-hexene copolymers having a heat of fusion, Hf, from about 5 to about 75 J/g and a weight average molecular weight, Mw, from about 10,000 to about 200,000 g/mol. | 12-20-2012 |
20130085092 | RHEOLOGICAL METHODS TO DETERMINE THE PREDISPOSITION OF A POLYMER TO FORM NETWORK OR GEL - A method is provided to determine the predisposition of a polymer to form network or gel in a lubricating oil which comprises obtaining a composition of a polymer in a diluent, measuring the shear stress as a function of shear rate, determining the yield stress using the Herschel-Bulkley equation and assessing the yield stress. A method is also provided to determine the predisposition of a polymer to form network or gel in a lubricating oil which comprises obtaining a composition of a polymer in a diluent, determining at least one of (i) the storage modulus G′ and loss modulus G″ of the composition by subjecting the composition to sinusoidal (oscillating) stress or strain of certain amplitude and frequency, (ii) the phase lag (angle) of the response strain or stress δ, or (iii) the tangent (tan) δ, and (c) assessing at least one of the G′, G″, δ, or tan(δ) determined. | 04-04-2013 |
20130131256 | Polymeric Compositions Useful as Rheology Modifiers and Methods for Making Such Compositions - Disclosed are rheology modifiers comprising compositionally disperse polymeric compositions and/or crystallinity disperse polymeric compositions that may be useful in modifying the rheological properties of lubrication fluids, and methods for making such compositions. The compositionally disperse polymeric composition are formed from at least two discrete compositions of ethylene copolymers. The crystallinity disperse polymeric composition are formed from ethylene copolymers having at least two discrete values of residual crystallinity. | 05-23-2013 |
20130203640 | POLYMER COMPOSITIONS HAVING IMPROVED PROPERTIES AS VISCOSITY INDEX IMPROVERS AND USE THEREOF IN LUBRICATING OILS - Polymer compositions for use as viscosity modifiers comprising at least two ethylene-based copolymer components are provided. The polymer composition comprises (a) a first ethylene-α-olefin copolymer and (b) a second ethylene-α-olefin copolymer. The first ethylene-α-olefin copolymer (a) has an ethylene content from about 60 to about 80 wt % and the second ethylene-α-olefin copolymer (b) has an ethylene content of less than about 60 wt %. The first ethylene-α-olefin copolymer (a) has a Melt Flow Rate Ratio (MFRR), defined as the ratio of the MFR measured at 230° C./21.6 kg and at 230° C./2.16 kg, of greater than 30 and optionally also has a Melt Flow Rate (MFR) of at least about 1.5 g/10 min, measured by ASTM D 1238 condition L (230° C./2.16 kg). The present disclosure is also directed to lubricant compositions comprising a lubricating basestock and a polymer composition of the present disclosure and is further directed to reducing gelation in the lubricant compositions. | 08-08-2013 |
20130225752 | Polypropylene-Based Adhesive Compositions - The present invention is related to adhesive compositions and their applications. In particular, the adhesive compositions described herein comprise a two or more propylene-based copolymers with varying comonomer content. | 08-29-2013 |
20130281339 | Ethylene-Based Copolymers, Lubricating Oil Compositions Containing the Same, and Methods for Making Them - Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include from about 35 wt. % to about 60 wt. % of units derived from ethylene and at least 1.0 wt. % of one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers are substantially amorphous and have a polydispersity index of about 2.8 or less. | 10-24-2013 |
20140221514 | Polymerization Activators for Supported Ziegler-Natta Catalysts - Processes for producing impact copolymers are provided. Ethylene and at least one copolymer can be polymerized in the presence of one or more catalysts, polypropylene particles, and one or more halocarbon compounds to produce an impact copolymer that includes the polypropylene particles and an ethylene copolymer. | 08-07-2014 |
20140221515 | Incipient Wetness Method to Enhance Productivity of Supported Ziegler-Natta Catalysts - Processes for producing impact copolymers are provided. Ethylene and at least one comonomer can be polymerized in the presence of one or more catalysts, polypropylene particles, and an inert solvent to produce an impact copolymer. The polypropylene particles can have a weight average particle size along the longest cross-sectional length thereof of about 0.05 mm to about 5 mm and a pore volume of less than 80%. The inert solvent can be present in a volume amount of about 0.1 to about 2 times the pore volume of the polypropylene particles. | 08-07-2014 |
20140374967 | Soft Polypropylene-Based Nonwovens - Disclosed herein is a nonwoven fabric comprising within the range of from 1 to 49 wt %, by weight of the fabric, of a reactor grade propylene-α-olefin copolymer possessing; within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C | 12-25-2014 |
20140374968 | Extensible Polypropylene-Based Nonwovens - Disclosed herein is a nonwoven fabric comprising within the range of from 50 to 99 wt %, by weight of the composition, of a reactor grade propylene-α-olefin copolymer possessing within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C | 12-25-2014 |