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Myungahn Ok, Daejeon KR

Myungahn Ok, Daejeon KR

Patent application numberDescriptionPublished
20100029896Novel Coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst - Provided are a complex prepared from ammonium salt-containing ligands and having such an equilibrium structural formula that the metal center takes a negative charge of 2 or higher, and a method for preparing polycarbonate via copolymerization of an epoxide compound and carbon dioxide using the complex as a catalyst. When the complex is used as a catalyst for copolymerizing an epoxide compound and carbon dioxide, it shows high activity and high selectivity and provides high-molecular weight polycarbonate, and thus easily applicable to commercial processes. In addition, after forming polycarbonate via carbon dioxide/epoxide copolymerization using the complex as a catalyst, the catalyst may be separately recovered from the copolymer.02-04-2010
20100081776TRANSITION METAL CATALYTIC SYSTEMS AND METHODS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND a-OLEFINS USING THE SAME - Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.04-01-2010
20100113720METHOD FOR PREPARING ELASTOMERIC COPOLYMERS OF ETHYLENE AND ALPHA-OLEFINS - Provided is a process for preparing copolymers of ethylene with α-olefin. More specifically, provided are transition metal compound being useful as catalyst for preparing those copolymers, a catalyst composition comprising the same, and a process for preparing elastic copolymers of ethylene with α-olefin, having the density of not more than 0.910, which can be adopted to a wide variety of applications including film, electric wires, and hot-melt adhesives. The catalyst composition is a catalytic system which comprises transition metal catalyst comprising a cyclopentadiene derivative and at least one anionic ligand(s) of aryloxy group with an aryl derivative at ortho-position, and boron or aluminum compound as an activator. Provided is a process for copolymerizing ethylene with α-olefin to produce copolymer having narrow molecular weight distribution and uniform density distribution with the density of not more than 0.910, with high activity and excellent reactivity on higher α-olefin.05-06-2010
20100113729ETHYLENE COPOLYMER WITH IMPROVED IMPACT RESISTANCE - Provided are ethylene copolymers with excellent impact resistance. More specifically, provided are ethylene copolymers satisfying certain correlation between the falling dart impact strength (F) or high rate impact resistant breakage energy (E) and Vicat softening point. The ethylene copolymers with improved impact properties are applicable to film, injection, compound, sheet, roto, pipe or blow molding.05-06-2010
20100120981ETHYLENE COPOLYMER AND A METHOD OF PREPARING THE SAME - Provided are ethylene copolymers and a process for preparing the same. More specifically, provided are ethylene copolymers exhibiting excellent processibility and physical properties due to its multimodal molecular weight distribution index, through a multi-stage process by using reactors connected in series or in parallel in the presence of catalyst composition containing transition metal catalyst, and a process for preparing the same.05-13-2010
20100323201Polymeric Thermoplastic Compositions Having Excellent Resistance to Moisture and Oxygen Transmission and Sheet Which are Made of These Polymeric Thermoplastic Compositions - Disclosed is a resin composition for blocking oxygen and moisture, and a sheet for blocking oxygen and moisture manufactured by using thereof, in which the resin composition includes polycarbonate terpolymer produced by reacting different two epoxides compounds with carbon dioxide.12-23-2010
20100324260Catalytic System for CO2/Epoxide Copolymerization - The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal −1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst.12-23-2010
20110054145Continuous Process for Manufacturing Aliphatic Polycarbonates from Carbon Dioxide and Epoxides - Disclosed is a continuous process for manufacturing aliphatic polycarbonate by polymerizing carbon dioxide and one or more epoxide compound in the presence of catalyst, in which carbon dioxide, one or more epoxide compound, and the catalyst are continuously supplied to polymerization reactor to produce aliphatic polycarbonate, separate unreacted carbon dioxide and epoxide compound and recycle them as raw materials.03-03-2011
20110065877ETHYLENE-PROPYLENE-DIENE COPOLYMER PRODUCTION METHOD - The present invention relates to a method for the production of an ethylene/propylene/diene copolymer by means of solution polymerisation, and more specifically one for a copolymer whose main components are ethylene, propylene and diene monomers using a catalyst of a transition metal coordination compound; the constituent components and characteristics of the copolymer being as follows. The catalyst composition provided by the present invention, which is used to produce a copolymer of which (a) the ethylene content is from 30 wt. % to 80 wt. %, (b) the propylene content is from 19.9% to 60 wt. % and (c) the diene content is from more than 0 wt. % to 15 wt. %, comprises a catalyst system using an activating agent of a compound of aluminium or boron, or aluminoxane together with a transition metal catalyst comprising at least one anionic ligand having an aryloxy group substituted with an aryl derivative in the ortho position and a cyclopentadiene derivative, and provides a highly active polymerisation method with outstanding reactivity with respect to ethylene, propylene and diene compounds.03-17-2011
20110098426TRANSITION METAL CATALYTIC SYSTEMS AND METHODS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF THE ETHYLENE AND a-OLEFINS USING THE SAME - Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.04-28-2011
20110105705Metallocene Supported Catalyst Composition and a Process for the Preparation of Polyolefin Using the Same - The invention relates to a metallocene supported catalyst composition and a process for the preparation of polyolefin using the same. A metallocene supported catalyst composition according to the invention is prepared by bringing a compound of a group IV transition metal into contact with an inorganic or organic porous carrier treated with an ionic compound. Advantages of a metallocene supported catalyst composition of the invention include an increase in the catalyst activity during polymerization of slurry and an olefin compound in the vapor phase even at a low content of metallocene metal components within the carrier, and an improvement in solving process problems such as fouling, sheeting, plugging or the like.05-05-2011