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Michel Daumerie, Houston US

Michel Daumerie, Houston, TX US

Patent application numberDescriptionPublished
20090105433Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins - Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCp04-23-2009
20090171034CONTROLLED RHEOLOGY POLYPROPYLENE HETEROPHASIC COPOLYMERS - This invention relates to the use of a cyclic ketone peroxide of half-life time larger than one second at a temperature of 225 ° C., for producing a controlled rheology polypropylene heterophasic copolymer of melt index MI2 larger than 15 g/10 min, having simultaneously a very high impact resistance and a high flexural modulus.07-02-2009
20090324911Polymeric compositions comprising polylactic acid and methods of making and using same - A multi-component article comprising a first component comprising a biodegradable polymer, and a second component comprising a polyolefin and a reactive modifier. A method of preparing a multi-layer film comprising coextruding first and second film layers, wherein the first layer comprises a polylactic acid and the second layer comprises a polyolefin and an epoxy-functionalized polyolefin. A method of preparing a multi-component fiber comprising coextruding a core component and a sheath component, wherein the core component comprises a polyolefin and an epoxy-functionalized polyolefin and the sheath component comprises a polylactic acid.12-31-2009
20090326130POLYMERIC BLENDS AND METHODS OF USING SAME - A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article.12-31-2009
20090326152Compatibilized polypropylene and polylactic acid blends and methods of making and using same - A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.12-31-2009
20100125124Methods of catalyst activation - A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.05-20-2010
20100227986Methods of Catalyst Activation - A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.09-09-2010
20110207898Method for Transitioning Between Ziegler-Natta and Metallocene Catalysts in a Bulk Loop Reactor for the Production of Polypropylene - Polymerization processes in a bulk loop reactor are described herein. In particular, a method of contacting a flow of metallocene with a flow of propylene is provided. This method includes directing the flow of metallocene towards a junction, directing the flow of propylene towards the junction and maintaining a portion of the flow of metallocene separate from a portion of the flow propylene within a portion of the junction downstream of the flow of propylene into the junction. In another embodiment, a method of introducing a quantity of antifouling agent into a catalyst mixing system is provided. In this embodiment a portion of the antifouling agent is introduced at or downstream of a point of contact of a stream of propylene with a stream of catalyst. The antifouling agent may be a member, alone or in combination with other members, selected from Stadis 450 Conductivity Improver, Synperonic antifouling agent, and Pluronic antifouling agent.08-25-2011

Patent applications by Michel Daumerie, Houston, TX US