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Mario Joseph Nappa, Newark US

Mario Joseph Nappa, Newark, DE US

Patent application numberDescriptionPublished
20080283794HEAT TRANSFER AND REFRIGERANT COMPOSITIONS COMPRISING 3,3,4,4,5,5,6,6,6-NONAFLUORO-1-HEXENE AND A FLUOROETHER - Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with fluoroethers, which are azeotropic or near azeotropic.11-20-2008
20080315149HEAT TRANSFER AND REFRIGERANT COMPOSITIONS COMPRISING 3,3,4,4,5,5,6,6,6-NONAFLUORO-1-HEXENE AND A HYDROCARBON - The present invention relates to:12-25-2008
20090012335Method of Hydrodechlorination to Produce Dihydrofluorinated Olefins - Disclosed herein is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents with hydrogen. Also disclosed is a catalyst composition for the hydrodechlorination of chlorofluoroalkenes comprising copper metal deposited on a support.01-08-2009
20090012336Selectively Reacting Olefins Having a Terminal CF2 Group in A Mixture - A process is disclosed for reducing the mole ratio of (1) compounds of the formula Y01-08-2009
20090018375COPRODUCTION OF HYDROFLUOROOLEFINS - Disclosed is a process for the co-manufacture of the hydrofluoroolefins HFC-1225ye and HFC-1234yf. The process comprises contacting a blend of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2,3-pentafluoropropane at a temperature of from about 200° C. to about 500° C. with a catalyst, optionally in the presence of an inert gas. The catalyst includes, but is not limited to, aluminum fluoride; fluorided alumina; metals on aluminum fluoride; metals on fluorided alumina; oxides, fluorides, and oxyfluorides of magnesium, zinc and mixtures of magnesium and zinc and/or aluminum; lanthanum oxide and fluorided lanthanum oxide; chromium oxides, fluorided chromium oxides, and cubic chromium trifluoride; carbon, acid-washed carbon, activated carbon, three dimensional matrix carbonaceous materials; and metal compounds supported on carbon. The metal compounds are oxides, fluorides, and oxyfluorides of at least one metal selected from the group consisting of sodium, potassium, rubidium, cesium, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, chromium, iron, cobalt, rhodium, nickel, copper, zinc, and mixtures thereof. The product hydrofluoroolefins are separated from unreacted hydrofluorocarbons and hydrogen fluoride. In another embodiment, the unreacted hydrofluorocarbons optionally may be recirculated back through the process.01-15-2009
20090056349COMPOSITIONS COMPRISING 3,3,4,4,5,5,6,6,6-NONAFLUORO-1-HEXENE - Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with at least one bromofluorocarbon, ketones, alcohols, chlorocarbons, ethers, esters, 4-chloro-1,1,2,3,3,4-hexafluorobutene, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof, which are azeotropic or near azeotropic.03-05-2009
20090120619METHOD FOR EXCHANGING HEAT IN VAPOR COMPRESSION HEAT TRANSFER SYSTEMS - The present disclosure relates to a method for exchanging heat in a vapor compression heat transfer system. In particular, it relates to use of an intermediate heat exchanger to improve performance of a vapor compression heat transfer system utilizing a working fluid comprising at least one fluoroolefin. In addition, the present disclosure relates to a vapor compression heat transfer system comprising an intermediate heat exchanger in combination with a dual-row evaporator or a dual-row condenser, or both.05-14-2009
20090127496Tetrafluoropropene Production Processes - A process is disclosed for the manufacture of CF05-21-2009
20090143604Synthesis of hydrofluoroalkanols and hydrofluoroalkenes - Described herein is a process for the manufacture of hydrofluoroalkanols of the structure R06-04-2009
20090156869PROCESSES FOR THE SYNTHESIS OF 2-CHLORO-1,1,1,3,3,4,4,4-HEPTAFLUORO-2-BUTENE AND HEXAFLUORO-2-BUTYNE - Disclosed is a process comprising reacting CF06-18-2009
20090240089METHOD OF HYDRODECHLORINATION TO PRODUCE DIHYDROFLUORINATED OLEFINS - Disclosed herein is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents with hydrogen. Also disclosed is a catalyst composition for the hydrodechlorination of chlorofluoroalkenes comprising copper metal deposited on a support.09-24-2009
20090264689Tetrafluoropropene Production Processes - A process is disclosed for producing 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene. The process involves pyrolyzing 1,1,1,2,3-pentafluoropropane.10-22-2009
200902646901,2,3,3,3-Pentafluoropropene Production Processes - A process is disclosed for making CF10-22-2009
20090267022 PROCESS AND METHODS OF PURIFICATION FOR THE MANUFACTURE FLUOROCARBONS - Halocarbons of the structure CF10-29-2009
20090278075COMPOSITIONS COMPRISING 1,1,1,2,3-PENTAFLUOROPROPANE OR 2,3,3,3- TETRAFLUOROPROPENE - Disclosed are compositions comprising HFC-245eb and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, and HFC-254fb. Compositions comprising HFC-245eb are useful in processes to make HFO-1234yf. Also disclosed are compositions comprising HFO-1 234yf and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFC-254fb, HFO-1243zf, HFCHFC-245eb, HFC-245fa, HFC-245cb, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-134, HFC-134a, HFO-1132a and FC-1216. Compositions comprising HFO-1234yf are useful as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.11-12-2009
20090299108CATALYTIC ADDITION OF HYDROFLUOROCARBONS TO FLUOROOLEFINS - A process is disclosed for making RR12-03-2009
200903064381,2,3,3,3-PENTAFLUOROPROPENE PRODUCTION PROCESSES - The present disclosure relates to a new and efficient manufacturing process for the production of HFC-1225ye. The process involves contacting at least one hexafluoropropane selected from the group consisting of 1,1,1,2,2,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane with a suitable catalyst in a reactor to obtain a product mixture containing HFC-1225ye (1,2,3,3,3-pentafluoropropene) where the pressure in the reactor ranges from about 0.5 psig to about 100 psig.12-10-2009
20100004492Catalytic Production Processes for Making Tetrafluoropropenes and Pentafluoropropenes - A process is disclosed for making CF01-07-2010
20100010277Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3-Pentafluoropropene - A process is disclosed to increase the Z/E ratio of 1,2,3,3,3-pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3-pentafluoropropene with a catalyst on AlF01-14-2010
20100025620PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3- TETRAFLUOROPROPENE - A process is disclosed for making CF02-04-2010
20100032610COMPOSITIONS COMPRISING 1,2,3,3,3-PENTAFLUOROPROPENE WITH Z- AND E-ISOMER RATIO OPTIMIZED FOR REFRIGERATION PERFORMANCE - Azeotropic or near-azeotropic compositions are disclosed comprising about 0.1 weight percent to about 99.9 weight percent Z-1,2,3,3,3-pentafluoropropene (Z-1225ye) and about 99.9 weight percent to about 0.1 weight percent E-1,2,3,3,3-pentafluoropropene (E-1225ye).02-11-2010
20100076231PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE, A PROCESS FOR PRODUCING 1-CHLORO-2,3,3,3-PENTAFLUOROPROPANE AND AZEOTROPIC COMPOSITIONS OF 1-CHLORO-2,3,3,3-TETRAFLUOROPROPENE WITH HF - A process is disclosed for making CH03-25-2010
20100090155THIOL AND THIOETHER STABILIZERS FOR FLUOROOLEFINS - The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one thiol or thioether, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.04-15-2010
20100090156COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE, 2-CHLORO-2,3,3,3-TETRAFLUOROPROPANOL, 2-CHLORO-2,3,3,3-TETRAFLUORO-PROPYL ACETATE OR ZINC (2-CHLORO-2,3,3,3-TETRAFLUOROPROPOXY) CHLORIDE - Compositions comprising CF04-15-2010
20100105967CONVERSION OF 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE TO 2,3,3,3-TETRAFLUOROPROPENE - Described is a method for producing fluoropropenes of formula CF04-29-2010
20100121115DEHYDROFLUORINATION PROCESS TO MANUFACTURE HYDROFLUOROOLEFINS - Disclosed is a process for the manufacture of hydrofluoroolefins of the structure CF05-13-2010
20100127208COMPOSITIONS COMPRISING FLUOROOLEFINS AND USES THEREOF - The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.05-27-2010
20100132387COMPOSITIONS COMPRISING FLUOROOLEFINS AND USES THEREOF - The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.06-03-2010
20100152093SOLVENT COMPOSITIONS COMPRISING UNSATURATED FLUORINATED HYDROCARBONS - This invention relates to cleaning compositions comprising unsaturated fluorinated hydrocarbons. The invention further relates to use of said cleaning compositions in methods to clean, degrease, deflux, dewater, and deposit fluorolubricant. The invention further relates to novel unsaturated fluorinated hydrocarbons and their use as cleaning compositions and in the methods listed above.06-17-2010
20100160696METHOD OF HYDRODECHLORINATION TO PRODUCE DIHYDROFLUORINATED OLEFINS - Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkene with hydrogen to produce a fluorine-containing olefin, wherein said catalyst is a composition comprising chromium, nickel and optionally an alkali metal selected from potassium and cesium. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkenes comprising copper, nickel, and an alkali metal selected from potassium and cesium, and methods of making such catalysts.06-24-2010
20100189885SOLVENT COMPOSITIONS COMPRISING UNSATURATED FLUORINATED HYDROCARBONS - Disclosed is a method for removing residue from a surface comprising: contacting the surface with a composition comprising at least one unsaturated fluorinated hydrocarbon selected from the group consisting of compounds having the formula E- or Z—R07-29-2010
20100197979Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3 Pentafluoropropene Using Aluminum Catalyst - A starting material comprising 1,2,3,3,3-pentafluoropropene is contacted with an aluminum chlorofluoride (AlCl08-05-2010
20100197980Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3 Pentafluoropropene Using Aluminum Catalyst - Disclosed herein is a process comprising: contacting a starting material comprising 1,2,3,3,3-pentafluoropropene in the vapor phase with an aluminum catalyst to obtain a final product, wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene of the final product is increased or decreased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in said starting material.08-05-2010
20100200798Tetrafluoropropene Production Processes - A process is disclosed for the manufacture of CF08-12-2010
20100203167AZEOTROPE COMPOSITIONS COMPRISING DECAFLUOROPENTANE AND HYDROGEN FLUORIDE AND USES THEREOF - Disclosed herein are azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride. The azeotrope compositions are useful in processes to produce and in processes to purify 1,2,3,3,3-pentafluoropropene. Additionally, disclosed herein are azeotrope and near-azeotrope compositions comprising 1,1,1,2,3,4,4,5,5,5-decafluoropentane and hydrogen fluoride.08-12-2010
20100268001PROCESS FOR THE PREPARATION OF HALO-OLEFINS - Described is a process for preparing a halo-olefin comprising contacting a halogenated hydrocarbon with a metal dehalogenating agent, in a solvent, in the presence of a phase transfer catalyst, under conditions sufficient to dehalogenate said halogenated hydrocarbon to produce a product stream comprising said halo-olefin. In one embodiment, the halogenated hydrocarbon is trifluorotrichloroethane and the halo-olefin is chlorotrifluoroethylene.10-21-2010
20100288965TERPENE, TERPENOID, AND FULLERENE STABILIZERS FOR FLUOROOLEFINS - The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be a terpene, terpenoid or fullerene; or a mixture of a terpene, terpenoid or fullerene with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.11-18-2010
20100288966ASCORBIC ACID, TEREPHTHALATE AND NITROMETHANE STABILIZERS FOR FLUOROOLEFINS - The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one ascorbic acid, terephthalate, or nitromethane, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.11-18-2010
20100301259PHOSPHORUS-CONTAINING STABILIZERS FOR FLUOROOLEFINS - The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one phosphorus-containing compound selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, and organophosphates. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.12-02-2010
20100320412PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3-TETRAFLUOROPROPENE - A process is disclosed for making CF12-23-2010
20110028769PROCESS FOR MAKING 1,1,1,4,4,4-HEXAFLUORO-2-BUTENE - A process is disclosed for making 1,1,1,4,4,4-hexafluoro-2-butene. The process involves reacting 2,2-dichloro-1,1,1-trifluoroethane with copper in the presence of an amide solvent and 2,2′-bipyridine. A process is also disclosed for making 1,1,1,4,4,4-hexafluoro-2-butene. The process involves reacting 2,2-dichloro-1,1,1-trifluoroethane with copper in the presence of an amide solvent and a Cu(I) salt. A process is further disclosed for making 1,1,1,4,4,4-hexafluoro-2-butene. The process involves reacting 2,2-dichloro-1,1,1-trifluoroethane with copper in the presence of an amide solvent, 2,2′-bipyridine and a Cu(I) salt.02-03-2011
20110031436COMPOSITIONS COMPRISING 2,3-DICHLORO-1,1,1-TRIFLUOROPROPANE, 2-CHLORO-1,1,1-TRIFLUOROPROPENE, 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE OR 2,3,3,3-TETRAFLUOROPROPENE - Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, HCFC-1131, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.02-10-2011
20110041530AMINE STABILIZERS FOR FLUOROOLEFINS - The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an amine or a mixture of an amine with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.02-24-2011
20110041878Solvent Compositions Comprising Unsaturated Fluorinated Hydrocarbons - Disclosed is a method for removing residue from a surface comprising: contacting the surface with a composition comprising at least one unsaturated fluorinated hydrocarbon selected from the group consisting of compounds having the formula E- or Z—R02-24-2011
20110118512PROCESSES FOR PRODUCTION AND PURIFICATION OF HYDROFLUOROOLEFINS - Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.05-19-2011

Patent applications by Mario Joseph Nappa, Newark, DE US