Patent application number | Description | Published |
20090009768 | Optical Ph Sensor - An optical sensor for pH is described using a cross-linked network of bisilanes to immobilize a pH sensitive chromophore to a surface potentially exposed to a high pressure, high temperature environment such as wellbore effluents at a downhole location. | 01-08-2009 |
20090014325 | ELECTRO-CHEMICAL SENSOR - An electro-chemical sensor for methane is described having a catalyst to react methane or other low molecular weight hydrocarbons and a detector to detect the turnover or reaction rate and using such information to determine the concentration of the methane or other low molecular weight species. The sensor is preferably used for measurements in a wellbore. | 01-15-2009 |
20100050761 | DETECTING GAS COMPOUNDS FOR DOWNHOLE FLUID ANALYSIS - A gas separation and detection tool for performing in situ analysis of borehole fluid is described. A separation system such as a membrane is employed to separate one or more target gasses from the borehole fluid. The separated gas may be detected by reaction with another material or spectroscopy. When spectroscopy is employed, a test chamber defined by a housing is used to hold the gas undergoing test. Various techniques may be employed to protect the gas separation system from damage due to pressure differential. For example, a separation membrane may be integrated with layers that provide strength and rigidity. The integrated membrane separation may include one or more of a water impermeable layer, gas selective layer, inorganic base layer and metal support layer. The gas selective layer itself can also function as a water impermeable layer. The metal support layer enhances resistance to differential pressure. Alternatively, the chamber may be filled with a liquid or solid material. | 03-04-2010 |
20100163430 | EROSION AND WEAR RESISTANT SONOELECTROCHEMICAL PROBE - The present invention, in one set of embodiments, provides methods and systems for integrating conducting diamond electrodes into a high power acoustic resonator. More specifically, but not by way of limitation, in certain embodiments of the present invention, diamond electrodes may be integrated into a high power acoustic resonator to provide a robust sensing device that may provide for acoustic cleaning of the electrodes and increasing the rate of mass transport to the diamond electrodes. The diamond electrodes may be used as working, reference or counter electrodes or a combination of two or more of such electrodes. In certain aspects, the high power acoustic resonator may include an acoustic horn for focusing acoustic energy and the diamond electrodes may be coupled with the acoustic horn. | 07-01-2010 |
20100168454 | CATALYTIC HYDROGENATION - Catalytic hydrogenation of a double bond, notably a C═C or C═N double bond, is carried out using a homogenous catalyst which is a complex of rhodium or other transition metal containing at least one ligand which is a nitrogenous organic base. Preferably the complex is phosphorus-free and the ligand is a bicyclic base having formula | 07-01-2010 |
20100243480 | MEASUREMENT OF HYDROGEN SULPHIDE AND THIOLS IN FLUIDS - A wellbore tool has an electrochemical sensor for measuring the amount of hydrogen sulphide or thiols in a fluid downhole in a wellbore. The sensor comprises a temperature- and pressure-resistant housing containing a flow path for the fluids. The fluids flow over one side of a gas permeable membrane the other side of the membrane being exposed to a chamber containing at least two electrodes and containing a reaction solution which together with the hydrogen sulphide or thiols create a redox reaction resulting in an electrical current dependent upon the amount of hydrogen sulphide or thiols in the fluid. Measurement is made by passing formation fluid along the flow path and repeatedly applying varying potential to one electrode and measuring the peak current flowing between that electrode and a second electrode. | 09-30-2010 |
20100315645 | HIGH POWER ACOUSTIC RESONATOR WITH INTEGRATED OPTICAL INTERFACIAL ELEMENTS - An optical element, which may be part of a system for optical analysis of a material in contact with it, is kept clean by means of the vibrations of a high power acoustic resonator. More specifically, but not by way of limitation, in certain embodiments of the present invention, one or more optical interfacial elements may be integrated with a high power acoustic resonator to provide a robust sensing device that may provide for acoustic cleaning of the optical interfacial elements and/or combining optical and acoustic measurements made by the integrated system for analysis purposes. In certain aspects, the high power acoustic resonator may include an acoustic horn for focusing acoustic energy and the optical interfacial elements may be integrated with the acoustic horn. | 12-16-2010 |
20110104809 | DOWNHOLE SPECTROSCOPIC HYDROGEN SULFIDE DETECTION - Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions. | 05-05-2011 |
20110111507 | DOWNHOLE SPECTROSCOPIC HYDROGEN SULFIDE DETECTION - Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions. | 05-12-2011 |