Patent application number | Description | Published |
20080200685 | Method for Preforming Oxidation Catalysts - Processes comprising providing a catalyst precursor, and heating the catalyst precursor to a temperature of at least 350° C. in an atmosphere comprising air, wherein air is fed into the atmosphere at a rate of 0.05 to 4.0 standard m | 08-21-2008 |
20090286999 | CATALYST SYSTEM FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES - The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides which has at least three catalyst layers arranged one on top of the other in the reaction tube, with the proviso that the most inactive catalyst layer is preceded in the upstream direction by a more active catalyst layer. The invention further relates to a process for gas phase oxidation in which a gaseous stream which comprises one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers, the least active catalyst layer being upstream of a more active catalyst layer. | 11-19-2009 |
20090291845 | CONVERSION OF A PRECATALYST TO A CATALYTICALLY ACTIVE SILVER-VANADIUM OXIDE BRONZE - A process is described for converting a precatalyst which comprises an inert support, an organic carbon source and a multimetal oxide comprising silver and vanadium to a gas phase oxidation catalyst which comprises the inert support and a catalytically active silver vanadium oxide bronze, by treating the precatalyst thermally at a temperature of at least 350° C. in a gas atmosphere which comprises less than 10% by volume of oxygen, wherein, before the thermal treatment, the amount of the carbon source in the precatalyst is adjusted to a value below a critical amount The carbon content is reduced by burning-off at a temperature of from 80 to 200° C. in an oxygenous atmosphere with decomposition of a portion of the carbon source. The catalysts obtained serve for the gas phase partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and/or carboxylic anhydrides. | 11-26-2009 |
20090318712 | CATALYST SYSTEM AND METHOD FOR PRODUCING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ACID ANHYDRIDES - Catalyst systems for preparing carboxylic acids and/or anhydrides, the catalyst system comprising a reaction zone and a layered catalyst, the reaction zone comprises a gas inlet region and a gas outlet region, the layered catalyst comprises an active composition and one or more middle layers, one or more first layers disposed on a side of the one or more middle layers toward the gas inlet region, and one or more second layers on a side of the one or more middle layers toward the gas outlet region, wherein the active composition content of one or more of the middle catalyst layers, based on total mass of the layered catalyst, is lower than the active composition content of the one or more first catalyst layers and is lower than one or more second catalyst layers; and processes for gas phase oxidation employing a layered catalyst of the present invention. | 12-24-2009 |
20100029955 | CATALYST SYSTEM AND METHOD FOR GAS PHASE OXIDATION USING AN UPSTREAM LAYER - The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone. | 02-04-2010 |
20100210857 | Three-Layered or Four-Layered Catalyst Systems for Producing Phthalic Anhydride - Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems | 08-19-2010 |
20110250124 | CATALYST FOR THE OXIDATION OF SO2 TO SO3 - The invention relates to a catalyst for the oxidation of SO | 10-13-2011 |
20110251052 | CATALYST FOR THE OXIDATION OF SO2 TO SO3 - The invention relates to a catalyst for the oxidation of SO | 10-13-2011 |
20120004425 | MULTILAYER CATALYST FOR PREPARING PHTHALIC ANHYDRIDE AND PROCESS FOR PREPARING PHTHALIC ANHYDRIDE - The present invention relates to a multilayer catalyst for preparing phthalic anhydride which has a plurality of catalyst layers arranged in succession in the reaction tube, with the individual catalyst layers having alkali metal contents which decrease in the flow direction. The present invention further relates to a process for the oxidation of naphthalene or o-xylene/naphthalene mixtures over such a multilayer catalyst and the use of such multilayer catalysts for the oxidation of naphthalene or o-xylene/naphthalene mixtures to phthalic anhydride. | 01-05-2012 |
20140018550 | CATALYST FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES - The present invention relates to a catalyst for preparing carboxylic acids and/or carboxylic anhydrides, which has a plurality of catalyst zones arranged in series and has been produced using a vanadium antimonate having a maximum content of crystalline valentinite of 5% by weight. The present invention further relates to a process for gas-phase oxidation in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst which has a plurality of catalyst zones arranged in series and has been produced using a vanadium antimonate having a maximum content of crystalline valentinite of 5% by weight. | 01-16-2014 |
20140213801 | MULTILAYER CATALYST HAVING VANADIUM ANTIMONATE IN AT LEAST ONE CATALYST LAYER FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES AND PROCESS FOR PREPARING PHTHALIC ANHYDRIDE HAVING A LOW HOT SPOT TEMPERATURE - The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides, which system comprises a plurality of superposed catalyst layers arranged in a reaction tube, where vanadium antimonate is introduced into the active material in at least one of the catalyst layers. The present invention further relates to a process for gas-phase oxidation, in which a gaseous stream comprising at least one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers and the maximum hot spot temperature is below 425° C. | 07-31-2014 |
Patent application number | Description | Published |
20090286999 | CATALYST SYSTEM FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES - The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides which has at least three catalyst layers arranged one on top of the other in the reaction tube, with the proviso that the most inactive catalyst layer is preceded in the upstream direction by a more active catalyst layer. The invention further relates to a process for gas phase oxidation in which a gaseous stream which comprises one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers, the least active catalyst layer being upstream of a more active catalyst layer. | 11-19-2009 |
20090291845 | CONVERSION OF A PRECATALYST TO A CATALYTICALLY ACTIVE SILVER-VANADIUM OXIDE BRONZE - A process is described for converting a precatalyst which comprises an inert support, an organic carbon source and a multimetal oxide comprising silver and vanadium to a gas phase oxidation catalyst which comprises the inert support and a catalytically active silver vanadium oxide bronze, by treating the precatalyst thermally at a temperature of at least 350° C. in a gas atmosphere which comprises less than 10% by volume of oxygen, wherein, before the thermal treatment, the amount of the carbon source in the precatalyst is adjusted to a value below a critical amount The carbon content is reduced by burning-off at a temperature of from 80 to 200° C. in an oxygenous atmosphere with decomposition of a portion of the carbon source. The catalysts obtained serve for the gas phase partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and/or carboxylic anhydrides. | 11-26-2009 |
20090318712 | CATALYST SYSTEM AND METHOD FOR PRODUCING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ACID ANHYDRIDES - Catalyst systems for preparing carboxylic acids and/or anhydrides, the catalyst system comprising a reaction zone and a layered catalyst, the reaction zone comprises a gas inlet region and a gas outlet region, the layered catalyst comprises an active composition and one or more middle layers, one or more first layers disposed on a side of the one or more middle layers toward the gas inlet region, and one or more second layers on a side of the one or more middle layers toward the gas outlet region, wherein the active composition content of one or more of the middle catalyst layers, based on total mass of the layered catalyst, is lower than the active composition content of the one or more first catalyst layers and is lower than one or more second catalyst layers; and processes for gas phase oxidation employing a layered catalyst of the present invention. | 12-24-2009 |
20100029955 | CATALYST SYSTEM AND METHOD FOR GAS PHASE OXIDATION USING AN UPSTREAM LAYER - The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone. | 02-04-2010 |
20100210857 | Three-Layered or Four-Layered Catalyst Systems for Producing Phthalic Anhydride - Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems | 08-19-2010 |
20110124885 | MULTILAYER CATALYST HAVING VANADIUM ANTIMONATE IN AT LEAST ONE CATALYST LAYER FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES AND PROCESS FOR PREPARING PHTHALIC ANHYDRIDE HAVING A LOW HOT SPOT TEMPERATURE - The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides, which system comprises a plurality of superposed catalyst layers arranged in a reaction tube, where vanadium antimonate is introduced into the active material in at least one of the catalyst layers. The present invention further relates to a process for gas-phase oxidation, in which a gaseous stream comprising at least one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers and the maximum hot spot temperature is below 425° C. | 05-26-2011 |
20110251405 | PROCESS FOR CONTROLLING A GAS PHASE OXIDATION REACTOR FOR PREPARATION OF PHTHALIC ANHYDRIDE - In a process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride, by passing a gas stream which comprises an aromatic hydrocarbon and molecular oxygen through a multitude of reaction tubes arranged in the gas phase oxidation reactor, each of which comprises a bed of at least one catalyst and the temperature of which can be controlled by means of a heat transfer medium, at least one control parameter is measured and correcting interventions for control of the control parameter are determined, the at least one control parameter comprising the phthalic anhydride yield and the correcting parameter used being the temperature of the heat carrier medium. Over at least 90% of the lifetime of the catalyst, the change in the correcting parameter is limited to a maximum of 0.5 K within a period of 30 days. In this way, the cumulated phthalic anhydride yield over the lifetime of the catalyst is maximized. | 10-13-2011 |
20120004425 | MULTILAYER CATALYST FOR PREPARING PHTHALIC ANHYDRIDE AND PROCESS FOR PREPARING PHTHALIC ANHYDRIDE - The present invention relates to a multilayer catalyst for preparing phthalic anhydride which has a plurality of catalyst layers arranged in succession in the reaction tube, with the individual catalyst layers having alkali metal contents which decrease in the flow direction. The present invention further relates to a process for the oxidation of naphthalene or o-xylene/naphthalene mixtures over such a multilayer catalyst and the use of such multilayer catalysts for the oxidation of naphthalene or o-xylene/naphthalene mixtures to phthalic anhydride. | 01-05-2012 |
20120029214 | CATALYST FOR THE OXIDATION OF O-XYLENE AND/OR NAPHTHALENE TO PHTHALIC ANHYDRIDE - The present invention relates to a catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride, which has a plurality of catalyst zones which are arranged in series in the reaction tube and have been produced using an antimony trioxide which comprises a significant proportion of valentinite. The present invention further relates to a process for gas-phase oxidation, in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst produced using an antimony trioxide which comprises a significant proportion of valentinite. | 02-02-2012 |
20120264952 | CATALYST FOR PREPARING ETHYLENE OXIDE - Catalyst for preparing ethylene oxide, at least comprising silver applied to a support, the support having a BET constant C in the range from 0 to 800, determined in accordance with DIN ISO 9277. | 10-18-2012 |
20120264953 | ZINC-COMPRISING CATALYST FOR PREPARING ETHYLENE OXIDE - Process for preparing a catalyst for preparing ethylene oxide, which comprises silver and zinc applied to a support, where the process comprises at least
| 10-18-2012 |