Patent application number | Description | Published |
20080254979 | MERCURY REMOVAL SORBENT - A sorbent composition comprising a vanadium compound and a TiO | 10-16-2008 |
20080274877 | MERCURY REMOVAL SORBENT - A composition comprising a vanadium oxide compound and an alkali metal promoter loaded onto a porous support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels. | 11-06-2008 |
20080279739 | MERCURY REMOVAL SORBENT - A composition comprising a vanadium oxide compound and an alkali metal promoter loaded onto a porous support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels. | 11-13-2008 |
20080281134 | PROPANE UTILIZATION IN DIRECT HYDROTREATING OF OILS AND/OR FATS - Methods for producing C10-C30 hydrocarbons from fatty compounds are provided in which at least a portion of the hydrogen required to accomplish the conversion is generated from by-products of the conversion process. Light hydrocarbons, especially propane, produced during the conversion of triglyceride compounds are used to generate hydrogen which is used in the conversion process thereby reducing the need for outside hydrogen sources. | 11-13-2008 |
20080295689 | MERCURY REMOVAL SORBENT - A sorbent composition comprising a vanadium compound and a ZrO | 12-04-2008 |
20080300132 | MERCURY REMOVAL SORBENT - A sorbent composition comprising a vanadium compound and a ZrO | 12-04-2008 |
20080305023 | PROCESS FOR SELECTIVE OXIDATION OF CARBON MONOXIDE IN A HYDROGEN CONTAINING STREAM - A method of making a composition, said method comprising, spraying a substance comprising platinum and iron into or onto an alumina-containing compound is disclosed. The resulting composition can then be used in a process for oxidizing carbon monoxide with free oxygen. | 12-11-2008 |
20080305949 | MERCURY REMOVAL SORBENT - A sorbent composition comprising a vanadium compound and a ZrO | 12-11-2008 |
20090019763 | HYDROTREATING AND CATALYTIC DEWAXING PROCESS FOR MAKING DIESEL FROM OILS AND/OR FATS - Methods for producing C10-C30 hydrocarbons from fatty materials, such as triglyceride compounds, are provided. Hydrocarbon compounds, particularly those boiling in the temperature range of between about 80° F. to about 1000° F., are produced by contacting a fatty material with at least one catalyst comprising cobalt and molybdenum on a zeolite support under hydrotreating conditions. Additional hydrotreating catalysts may also be used to further improve the properties of the hydrocarbon product. | 01-22-2009 |
20090092528 | PROCESS FOR THE REMOVAL OF HEAVY METALS FROM GASES, AND COMPOSITIONS THEREFOR AND THEREWITH - A composition, containing vanadium and a support, wherein at least a portion of the vanadium has crystallite sizes of less than about 100 Å as determined by an analytical method such as X-Ray Diffraction, is disclosed. A method of preparing such composition is also disclosed. The composition is employed in a process to remove a heavy metal from a gaseous feed stream which can optionally include a separate mercury adsorption stage. | 04-09-2009 |
20090099008 | PROCESS FOR THE REMOVAL OF HEAVY METALS FROM GASES, AND COMPOSITIONS THEREFOR AND THEREWITH - A composition, containing vanadium and a support, wherein at least a portion of the vanadium has crystallite sizes of less than about 100 Å as determined by an analytical method such as X-Ray Diffraction, is disclosed. A method of preparing such composition is also disclosed. The composition is employed in a process to remove a heavy metal from a gaseous feed stream which can optionally include a separate mercury adsorption stage. | 04-16-2009 |
20090266743 | THERMAL TREATMENT OF TRIGLYCERIDES - A triglyceride or a triglyceride/hydrocarbon combination can be heated to produce thermally treated feeds. The thermally treated feeds can then be contacted with a hydrotreating catalyst in a reaction zone. | 10-29-2009 |
20100099933 | INTEGRATED PROCESS FOR CONVERTING CARBOHYDRATES TO HYDROCARBONS - An integrated process for the conversion of carbohydrate containing materials to gasoline boiling range hydrocarbons is disclosed. A carbohydrate containing material may be converted to a hydrogenated carbohydrate containing material with a bi-functional catalyst. The hydrogenated carbohydrate containing material may be reacted in the presence of another catalyst to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons. | 04-22-2010 |
20100300937 | NAPHTHENIC ACID REMOVAL AND CONVERSION - Methods and apparatus relate to handling of organic contaminants in aqueous streams. The methods and apparatus enable removing the contaminants, such as naphthenic acids, from the aqueous streams and then converting the contaminants into hydrocarbons. The removing and converting of the organic contaminates results in treated discharge and generation of the hydrocarbons, which add to amount of hydrocarbon recovery. | 12-02-2010 |
20110046423 | HYDROTREATING CARBOHYDRATES - Conversion of renewable hydrocarbons to transportation fuels is required to reduce carbon emission, limit the use of fossil fuels, and develop renewable energy sources. Sorbitol, xylitol and trehelose are polyalcohols generated from the liquefaction of various sugars and carbohydrates in biomass from algae, corn, sugarcane, switchgrasses, and biological wastes. Mixtures of aqueous polyols and fuel feedstocks are catalyzed over metal catalysts to produce hexanes, pentanes, and lighter hydrocarbons. By managing the catalyst, reaction conditions and sulfur content, the octane value of the product fuel is dramatically increased. | 02-24-2011 |
20110047866 | REMOVAL OF IMPURITIES FROM OILS AND/OR FATS - Disclosed is a process for removing solids, metals, phosphorus compounds and other impurities from low quality triglyceride containing feedstock. The final treated triglyceride containing feedstock may be converted to fuel range hydrocarbons via hydrotreating process. | 03-03-2011 |
20110077436 | PRETREATMENT OF OILS AND/OR FATS - Disclosed are methods for pretreating triglyceride containing material prior to contacting with a hydrotreating catalyst to produce fuel range hydrocarbons without causing reactor fouling or catalyst plugging. | 03-31-2011 |
20110087060 | SUGAR ALCOHOL SPLIT INJECTION CONVERSION - A method of hydrotreating liquefied biomass feedstock with diesel feedstock to produce alkanes is demonstrated that prevents damage to the reactor catalyst, reduces coke production, and converts nearly all of the polyols to alkanes. In order to mitigate the potential coking issue and to moderate the temperature of the catalyst bed while maintaining high conversion for sugar alcohol to hydrocarbon via a hydrotreating process, a diesel feedstock is fed over the reactor catalyst with multiple injections of polyol feedstock along the reactor. | 04-14-2011 |
20110124931 | PROCESS TO MITIGATE THE CORROSION OF OILS/FATS - It has been discovered that the residence time of oils/fats in metal apparatus, particularly in the upstream of a hydrotreating unit, for example, a heat exchanger and/or a storage/feed tank, can impact significantly on corrosiveness of oils/fats in combination with and without conventional hydrocarbons. In addition, it is also found that the presence of hydrogen in the metal apparatus can also inhibit the corrosion rate of oils/fats. | 05-26-2011 |
20110126449 | BLENDED FUEL COMPOSITION HAVING IMPROVED COLD FLOW PROPERTIES - There is provided a fuel composition comprising petroleum based component and a renewable based component, wherein at least 20% of the compounds in said petroleum based component having boiling point range equal or greater than the boiling point of said renewable based component. | 06-02-2011 |
20110152513 | CONVERSION OF CARBOHYDRATES TO HYDROCARBONS - Materials and processes for the conversion of carbohydrates and polyols to gasoline boiling range hydrocarbons. Carbohydrates and polyols are reacted in the presence of modified zeolite catalysts to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons. | 06-23-2011 |
20110152588 | PRODUCTION OF HYDROCARBON FROM HIGH FREE FATTY ACID CONTAINING FEEDSTOCKS - There is provided a process for converting high free fatty acid containing feedstock such as acidulated soapstock into hydrocarbon compound especially fuel range hydrocarbons using amidation as a pretreatment step followed by hydroprocessing. | 06-23-2011 |
20110237851 | THERMAL CRACKING OF IMPURITIES IN TRIGLYCERIDE FEEDSTOCK - A triglyceride or a triglyceride/hydrocarbon combination can be thermally cracked to remove its impurities in situ prior to be upgraded to fuel range hydrocarbon. This process allows the use of a variety of low cost feedstock and reduce reactor fouling tendency. The process also reduces the use of chemicals required for conventional clean up processes such as degumming. | 09-29-2011 |
20110263916 | CARBOHYDRATES UPGRADING AND HYDROTREATING TO HYDROCARBONS - Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A process was designed to reduce the coke by co-feeding sugars/sugar derivatives with a saturated recycle stream containing hydrogenated products. | 10-27-2011 |
20120000820 | HYDROPROCESSING PROCESS FOR THE IMPROVEMENT OF THE CATALYST LIFE - This invention relates to a hydroprocessing process for the improvement of catalyst life. Such inventive process is carried out with intermittent or discontinuous addition of a co-feed stream when hydroprocessing petroleum based feedstock or an oxygen containing feedstock. More specifically, it has been found that intermittent or discontinuous addition of the co-feed stream such as carbon monoxide, carbon dioxide, or their precursors to the hydrogen stream can reduce the long term deactivation, extend the life and increase run length of a cobalt/molybdenum hydrotreating catalyst. | 01-05-2012 |
20120017496 | HYDROPROCESSING PROCESS WITH IMPROVED CATALYST ACTIVITY - This invention relates to a hydroprocessing process with improved catalyst activity when hydroprocessing petroleum based feedstock or an oxygen containing feedstock. This invention also relates to a hydrotreating process with improved hydrodesulfurization (HDS) activity of a hydrotreating catalyst such as Co/Mo by co-feeding carbon monoxide or its precursors. Such inventive process confirms that adding a small amount of CO to H2 in a hydrotreater for a few days leads to an increase in product sulfur due to the inhibition of CO on the hydrotreating catalyst such as Co/Mo. However, it has been unexpectedly found that after the CO was removed from the hydrogen stream, product sulfur levels decreased to values below they were before CO addition which means the activity of the hydrotreating catalyst increased after the CO treatment. | 01-26-2012 |
20120022305 | HYDROCRACKING PROCESS FOR MAKING RENEWABLE DIESEL FROM OILS AND/OR FATS - Methods for producing C3-C30 hydrocarbons from fatty materials, such as triglyceride compounds, are provided. Hydrocarbon compounds, particularly those boiling in the temperature range of between about 80° F. to about 1000° F., are produced by contacting a fatty material, under hydrocracking conditions, with at least one catalyst comprising a Group VIII metal and a Group VIB metal on a acidic support. | 01-26-2012 |
20120023810 | METAL IMPURITY AND HIGH MOLECULAR WEIGHT COMPONENTS REMOVAL OF BIOMASS DERIVED BIOCRUDE - This invention relates to a process for production of transportation fuels from biomass. More particularly, this invention relates to a process for using solvent to remove metal impurities and high molecular weight components from biomass derived biocrude to prevent potential catalyst poisoning and catalyst bed plugging in biocrude-to-transportation fuel upgrading process. | 02-02-2012 |
20120088945 | CO-PRODUCTION OF RENEWABLE DIESEL AND RENEWABLE GASOLINE - A process for co-production of renewable diesel fuel range hydrocarbons and gasoline fuel range hydrocarbons from biomass-derived oils and fatty materials (e.g. triglycerides, diglycerides, monoglycerides, and free fatty acids) and biomass-derived polyol (e.g. sorbitol, xylitol, trehalose, sucrose, and sugar alcohol), respectively, in a same refinery hydrotreater with or without co-feeding of diesel fuel range hydrocarbons. | 04-12-2012 |
20120095274 | COMBINATION OF ZEOLITE UPGRADING WITH HYDROGENATION UPGRADING TO PRODUCE RENEWABLE GASOLINE FROM BIOMASS - Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A self-sustainable process was designed to reduce the coke by co-feeding sugars/sugar derivatives with the paraffin products from hydrogenation of sugars/sugar derivatives. Paraffins without complete conversion result in products with less aromatics and relatively low density compared with the products directly from zeolite upgrading. Thus, the process is more economically favorable. | 04-19-2012 |
20120157742 | PRODUCTION OF RENEWABLE FUELS - The present disclosure relates to a process for the conversion of oxygen-containing hydrocarbons into long-chain hydrocarbons suitable for use as a fuel. These hydrocarbons may be derived from biomass, and may optionally be mixed with petroleum-derived hydrocarbons prior to conversion. The process utilizes a catalyst comprising Ni and Mo to convert a mixture comprising oxygenated hydrocarbons into product hydrocarbons containing from ten to thirty carbons. Hydro-conversion can be performed at a significantly lower temperature than is required for when utilizing a hydrotreating catalyst comprising Co and Mo (CoMo), while still effectively removing sulfur compounds (via hydrodesulfurization) to a level of 10 ppm (by weight) or less. | 06-21-2012 |
20120215047 | MOS2 CATALYST FOR THE CONVERSION OF SUGAR ALCOHOL TO HYDROCARBONS - Cellulose and hemicellulose from biomass can be broken down to C6 and C5 sugars and further converted to corresponding sugar alcohols. It is now found that a new catalyst, MoS2, is active for the hydrogenation of sugar alcohols to hydrocarbons. Combining the technologies listed above allows us to convert the cellulose/hemicellulose to liquid hydrocarbons. | 08-23-2012 |
20130144089 | PYROLYSIS OIL UPGRADING TO GASOLINE RANGE LIQUIDS - This invention is a method for converting biomass derived pyrolysis oil (bio-oil) into materials that will be more useful for transportation fuels including the following two steps: 1) solubilizing and extracting bio-oil oxygenates, and 2) zeolite catalyzed hydrogenation of the oxygenates into renewable fuel range materials. | 06-06-2013 |
20130172650 | UPGRADING LIGHT OLEFINS - Methods and systems relate to upgrading light olefins, such as ethylene, propylene and butylenes, diluted in a gas mixture, such as refinery fuel gas. The upgrading yields products in a gasoline, distillate, lube oil or wax range without requiring purification or compression of the gas mixture prior to feeding the gas mixture to a reactor. In operation, the mixture contacts a solid oligomerization catalyst, such as silica supported chromium, within the reactor. This contact occurs at a first temperature suitable to produce oligomers that are formed of the olefins and adsorb on the catalyst in liquid or solid phases. Next, heating the catalyst to a second temperature higher the first temperature desorbs the oligomers that are recovered and separated into the products. | 07-04-2013 |
20130219778 | CONVERTING GLYCOLS TO ALCOHOLS - The conversion of diols to mono-alcohols as fuel blendstocks. In one embodiment hydrotreating processes are described that selectively convert glycols to mono-alcohols that can be blended as biofuels. Both NiMo and CoMo catalysts are active for the reaction and reaction conditions can also impact the selectivity of mono-alcohols. | 08-29-2013 |
20140147344 | MoS2 CATALYST SYSTEM FOR THE CONVERSION OF SUGAR ALCOHOL TO HYDROCARBONS - Cellulose and hemicellulose from biomass can be broken down to C6 and C5 sugars and further converted to corresponding sugar alcohols. It is now found that a new catalyst, MoS2, is active for the hydrogenation of sugar alcohols to hydrocarbons. Combining the technologies listed above allows us to convert the cellulose/hemicellulose to liquid hydrocarbons. | 05-29-2014 |
20140148627 | MOS2 CATALYST PROCESS FOR THE CONVERSION OF SUGAR ALCOHOL TO HYDROCARBONS - Cellulose and hemicellulose from biomass can be broken down to C6 and C5 sugars and further converted to corresponding sugar alcohols. It is now found that a new catalyst, MoS2, is active for the hydrogenation of sugar alcohols to hydrocarbons. Combining the technologies listed above allows us to convert the cellulose/hemicellulose to liquid hydrocarbons. | 05-29-2014 |
20140213836 | THERMAL CRACKING OF IMPURITIES IN TRIGLYCERIDE MIXTURES - A heated petroleum-derived hydrocarbon is contacted with a triglyceride feed in a thermal cracking zone to decompose and remove impurities prior to hydrotreating the mixture to fuel range hydrocarbon. This process allows the use of a variety of low cost triglyceride feeds while reducing fouling of process equipment and catalyst. The process also reduces the use of chemicals required for conventional degumming of triglyceride feeds. | 07-31-2014 |
20140322087 | SUGAR ALCOHOL SPLIT INJECTION CONVERSION - A method of hydrotreating liquefied biomass feedstock with diesel feedstock to produce alkanes is demonstrated that prevents damage to the reactor catalyst, reduces coke production, and converts nearly all of the polyols to alkanes. In order to mitigate the potential coking issue and to moderate the temperature of the catalyst bed while maintaining high conversion for sugar alcohol to hydrocarbon via a hydrotreating process, a diesel feedstock is fed over the reactor catalyst with multiple injections of polyol feedstock along the reactor. | 10-30-2014 |