Patent application number | Description | Published |
20080255327 | NICKEL-BASED CATALYST COMPOSITION - In general the present invention provides a process for forming conjugated diene polymer, the process comprising the step of polymerizing conjugated diene monomer in the presence of a catalytically effective amount of a catalyst composition formed by combining (a) a nickel-containing compound, (b) an alkylating agent, (c) a fluorine-containing compound, (d) a carboxylic acid, and (e) an alcohol. | 10-16-2008 |
20090143551 | NICKEL-BASED CATALYSTS FOR PREPARING HIGH CIS 1,4-POLYDIENES - A nickel-carbene polymerization catalyst system for preparing high cis polydienes is provided. The catalyst system comprises (a) a nickel N-heterocyclic carbene complex, (b) an organoaluminum compound, (c) a fluorine-containing compound, and (d) optionally, an alcohol. Also provided is a process for producing a polydiene comprising reacting a conjugated diene in the presence of a polymerization catalyst comprising (a) a nickel N-heterocyclic carbene complex, (b) an organoaluminum compound, (c) a fluorine-containing compound, and (d) optionally, an alcohol. | 06-04-2009 |
20090171046 | PROCESS FOR PRODUCING POLYDIENES - A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system. | 07-02-2009 |
20090299019 | PROCESS FOR PRODUCING POLYDIENES - A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides. | 12-03-2009 |
20100004413 | BULK POLYMERIZATION PROCESS FOR PRODUCING POLYDIENES - A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer with a lanthanide-based catalyst system including the combination or reaction product of: (a) a lanthanide compound selected from the group consisting of lanthanide organophosphates, lanthanide organophosphonates, and lanthanide organophosphinates, (b) an alkylating agent, and (c) a chlorine-containing compound, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of solvent based on the total weight of the polymerization mixture. | 01-07-2010 |
20100160542 | HYBRID POLYMER AND METHOD FOR MAKING - A macromolecule includes a polymer directly tethered or bonded to a polyatomic functionality. The polyatomic functionality can be located at a terminus of the polymer and can be generated concurrent with or soon after formation of the polymer. The macro-molecule can be prepared from a functionalized polymer by hydrolyzing and condensing (e.g., by a sol-gel process) functionalities in which one or more alkoxy groups are bound to a silica atom in the presence of an excess of a compound that includes a Si, Ti, Zr, Sn, Al, or Fe atom. Such macromolecules can be used in the manufacture of vulcanizates and tire components, either alone or blended with other polymers and/or other particulate fillers. | 06-24-2010 |
20100216956 | PROCESS AND CATALYST SYSTEM FOR POLYDIENE PRODUCTION - Compositions and polydiene production processes involving catalyst systems comprising at least one lanthanide-containing compound, at least one alkylating agent, at least one halogen source, and at least one N,N-dihydrocarbylhydroxylamine. | 08-26-2010 |
20100273963 | PROCESS FOR PRODUCING POLYDIENES - A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system. | 10-28-2010 |
20100286348 | HYDROXYARYL FUNCTIONALIZED POLYMERS - Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing aryl functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers. | 11-11-2010 |
20100311899 | FUNCTIONALIZED POLYMER AND METHODS FOR MAKING AND USING - A functionalized polymer includes a polymer chain and a terminal functionality that includes at least one disilylamino group. The polymer can be the reaction product of a terminally active polymer chain and a compound that includes at least one disilylamino group and a group capable of reacting with terminally active polymers. Methods for making and using such polymers also are provided, as are compositions containing the polymer and one or more types of filler particles as well as vulcanizates provided from such compositions. | 12-09-2010 |
20120077941 | POLYMERS FUNCTIONALIZED WITH PROTECTED OXIME COMPOUNDS - A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing conjugated diene monomer by employing a lanthanide-based catalyst to form a reactive polymer, and (ii) reacting the reactive polymer with a protected oxime compound. | 03-29-2012 |
20120196995 | PROCESS FOR PRODUCING POLYDIENES - A process for preparing a polydiene, the process comprising the step of: polymerizing conjugated diene monomer in the presence of a (hydrocarbyloxyhydrocarbyl)amine, where said step of polymerizing employs a lanthanide-based catalyst system. | 08-02-2012 |
20130137838 | NICKEL-BASED CATALYST COMPOSITION - In general the present invention provides a process for forming conjugated diene polymer, the process comprising the step of polymerizing conjugated diene monomer in the presence of a catalytically effective amount of a catalyst composition formed by combining (a) a nickel-containing compound, (b) an alkylating agent, (c) a fluorine-containing compound, (d) a carboxylic acid, and (e) an alcohol. | 05-30-2013 |
20140316086 | NICKEL-BASED CATALYST COMPOSITION - In general the present invention provides a process for forming conjugated diene polymer, the process comprising the step of polymerizing conjugated diene monomer in the presence of a catalytically effective amount of a catalyst composition formed by combining (a) a nickel-containing compound, (b) an alkylating agent, (c) a fluorine-containing compound, (d) a carboxylic acid, and (e) an alcohol. | 10-23-2014 |