Patent application number | Description | Published |
20080210087 | MEMBRANES FOR SEPARATION OF CARBON DIOXIDE - Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200° C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La | 09-04-2008 |
20080299436 | COMPOSITE CERAMIC ELECTROLYTE STRUCTURE AND METHOD OF FORMING; AND RELATED ARTICLES - A composite ceramic electrolyte is provided. The composite ceramic electrolyte has a microstructure, which comprises a first ceramic composition comprising a plurality of nano-dimensional microcracks, and a second ceramic composition substantially embedded within at least a portion of the plurality of nano-dimensional microcracks. The first and the second compositions are different. A solid oxide fuel cell comprising a composite ceramic electrolyte having such a microstructure is provided. A method of making a composite ceramic electrolyte is also described. The method includes the steps of: providing a first ceramic composition comprising a plurality of nano-dimensional microcracks; and closing a number of the nano-dimensional microcracks with a second ceramic composition, wherein the first and the second compositions are different, so as to form a composite ceramic electrolyte having a microstructure which comprises a first ceramic composition comprising a plurality of nano-dimensional microcracks and a second ceramic composition substantially embedded within at least a portion of the plurality of nano-dimensional microcracks. | 12-04-2008 |
20090075146 | METHOD OF PROCESSING A CERAMIC LAYER AND RELATED ARTICLES - A method of processing a ceramic layer is provided. The method comprises the steps of providing a ceramic layer comprising a plurality of microcracks; infiltrating at least some of the plurality of microcracks with a liquid precursor comprising at least one oxidizable metal ion; and exposing the ceramic layer to a base having a pH value of at least about 9, so as to chemically convert the oxidizable metal ion into an oxide, thereby decreasing the porosity of the ceramic layer. A solid oxide fuel cell is provided. The solid oxide fuel cell comprises an anode; a cathode; and a ceramic electrolyte disposed between the anode and the cathode. The ceramic electrolyte is processed by the method comprising the steps of providing a ceramic electrolyte comprising a plurality of microcracks; infiltrating at least some of the plurality of microcracks with a liquid precursor comprising at least one oxidizable metal ion; and exposing the ceramic electrolyte to a base having a pH value of at least about 9, so as to chemically convert the oxidizable metal ion into an oxide, thereby decreasing the porosity of the ceramic electrolyte. | 03-19-2009 |
20090139874 | SYSTEM AND METHOD FOR THE PRODUCTION OF HYDROGEN - Disclosed herein are a system and a method for the production of hydrogen. The system advantageously combines an independent high temperature heat source with a solid oxide electrolyzer cell and a heat exchanger located between the cathode inlet and the cathode outlet. The heat exchanger is used to extract heat from the molecular components such as hydrogen derived from the electrolysis. A portion of the hydrogen generated in the solid oxide electrolyzer cell is recombined with steam and recycled to the solid oxide electrolyzer cell. The oxygen generated on the anode side is swept with compressed air and used to drive a gas turbine that is in operative communication with a generator. Electricity generated by the generator is used to drive the electrolysis in the solid oxide electrolyzer cell. | 06-04-2009 |
20090155566 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One particular embodiment is an article that comprises a coating having a surface connected porosity content of up to about 5 percent by volume. The coating comprises a material that comprises a primary oxide and a secondary oxide, wherein (i) the primary oxide comprises a cation selected from the group consisting of cerium, praseodymium, terbium, and hafnium, and (ii) the secondary oxide comprises a cation selected from the group consisting of the rare earth elements, yttrium, and scandium. | 06-18-2009 |
20090155609 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One embodiment is a material comprising a primary oxide and a secondary oxide. The primary oxide comprises cerium and hafnium. The secondary oxide comprises a secondary oxide cation selected from the group consisting of the rare earth elements, yttrium, and scandium. Another embodiment is a material comprising a primary oxide and a secondary oxide. The primary oxide comprises cerium or hafnium. The secondary oxide comprises (i) praseodymium or ytterbium, and (ii) another cation selected from the group consisting of the rare earth elements, yttrium, and scandium. | 06-18-2009 |
20090218275 | MEMBRANE STRUCTURE AND METHOD OF MAKING - A membrane structure is provided. The membrane structure includes a polymer layer having a plurality of pores; and a ceramic layer disposed on the polymer layer. The ceramic layer has a plurality of substantially unconnected pores. Each of the substantially unconnected pores is in fluid communication with at least one of the pores of the polymer layer. A method of manufacturing a membrane structure is provided. The method includes the steps of providing a polymer layer having a plurality of pores; and disposing a ceramic layer on the polymer layer. Disposing a ceramic layer includes depositing a metal layer on the polymer layer; and anodizing the metal layer to convert the metal layer into a porous layer. At least one of the depositing step and the anodizing step is performed as a continuous process. Alternatively, at least one of the depositing and the anodizing step is performed as a batch process. | 09-03-2009 |
20090280246 | MESOPOROUS MEMBRANES WITH COMPLEX FUNCTIONAL ARCHITECTURES AND METHODS FOR MAKING - In some embodiments, the present invention is directed to methods of making structures with complex functional architectures, where such structures generally comprise at least two mesoporous regions comprising different chemical activity, and where such methods afford spatial control over the placement of such regions of differing chemical activity. In some embodiments, the present invention is also directed to the structures formed by such methods, where such structures are themselves novel. | 11-12-2009 |
20090280298 | PROTECTIVE COATING WITH HIGH ADHESION AND ARTICLES MADE THEREWITH - Coatings and articles suitable for use in high temperature environments, for example, are presented. One embodiment is a coating that comprises a plurality of elongate material growth domains defined between domain boundaries. The domains have an intra-domain density of at least about 75% of theoretical density, have a substantially equiaxed grain morphology, and comprise a plurality of at least partially melted and solidified particles. Another embodiment is a coating that comprises a matrix comprising a substantially equiaxed grain morphology and a plurality of vertically oriented cracks disposed in the matrix. Further embodiments include articles comprising one or more of the coatings described above. | 11-12-2009 |
20090317705 | FUEL CELL INTERCONNECT STRUCTURES, AND RELATED DEVICES AND PROCESSES - A method for the formation of a diffusion barrier layer on a surface of at least one fuel cell interconnect structure is described. The interconnect structure is usually formed from ferritic stainless steel, and includes chromium. The method includes the step of coating an austenite phase-stabilizer on the interconnect surface, and then heating the coated surface. The heat treatment transforms the microstructure of the surface region of the interconnect, from a substantially ferritic body-centered cubic (BCC) phase to a substantially austenitic face-centered cubic (FCC) phase. The diffusion rate of chromium through the FCC phase is relatively low. Thus, the formation of a thick layer of chromium oxide can be minimized, leading to better fuel cell performance. Related fuel cells and fuel cell stacks are also disclosed. | 12-24-2009 |
20100006149 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One particular embodiment is an article that comprises a coating having a surface connected porosity content of up to about 5 percent by volume. The coating comprises a material that comprises a primary oxide and a secondary oxide, wherein (i) the primary oxide comprises a cation selected from the group consisting of cerium, praseodymium, terbium, and hafnium, and (ii) the secondary oxide comprises a cation selected from the group consisting of the rare earth elements, yttrium, and scandium. The material is transparent to electromagnetic radiation of at least one type selected from the group consisting of ultraviolet radiation, visible light, and infrared radiation. | 01-14-2010 |
20100029465 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One embodiment is an article comprising a material that is transparent to electromagnetic radiation of at least one type selected from the group consisting of ultraviolet radiation, visible light, and infrared radiation. The material comprises a primary oxide and a secondary oxide. The primary oxide comprises cerium and hafnium. The secondary oxide comprises a secondary oxide cation selected from the group consisting of the rare earth elements, yttrium, and scandium. Another embodiment is an article comprising a material that is transparent to electromagnetic radiation of at least one type selected from the group consisting of ultraviolet radiation, visible light, and infrared radiation. The material comprises a primary oxide and a secondary oxide. The primary oxide comprises cerium or hafnium. The secondary oxide comprises (i) praseodymium or ytterbium, and (ii) another cation selected from the group consisting of the rare earth elements, yttrium, and scandium. | 02-04-2010 |
20100108241 | MEMBRANE STRUCTURE AND METHOD OF MAKING - A membrane structure is provided. The membrane structure includes a first layer having a plurality of pores; and a second layer disposed on the first layer. The second layer has a plurality of unconnected pores. At least a portion of the plurality of unconnected pores of the second layer is at least partially filled with a filler such that the first layer is substantially free of the filler. At least a portion of the plurality of unconnected pores of the second layer is in fluid communication with at least one of the pores of the first layer. A method of making a membrane structure is provided. The method includes the steps of providing a first layer having a plurality of interconnected pores; disposing a second layer on the first layer, and filling at least a portion of the unconnected pores of the second layer with a filler such that the first layer is substantially free of the filler. Disposing a second layer includes depositing a metal layer on the first layer; and anodizing the metal layer to convert the metal layer into porous oxide layer. | 05-06-2010 |
20100129639 | SURFACE HAVING A NANOPOROUS COATING, METHODS OF MANUFACTURE THEREOF AND ARTICLES COMPRISING THE SAME - Disclosed herein is an that includes a substrate; and a nanoporous coating disposed thereon; the nanoporous coating having a thickness of about 5 nanometers to about 10 micrometers; where an interface between the substrate and the nanoporous coating is disposed at an angle of about 60 degrees to about 120 degrees to a horizontal; the nanoporous coating being in contact with a liquid; the nanoporous coating being operative to improve the critical heat flux by an amount of about 20% to about 100% over a surface that does not have a nanoporous coating. | 05-27-2010 |
20100143620 | WETTING RESISTANT MATERIAL AND ARTICLES MADE THEREWITH - An article coated with a highly durable, wetting resistant coating is provided. The article comprises a coating that comprises a cermet material. The cermet material includes a nickel-bearing metal matrix and a phase disposed within the matrix. The phase includes an anion moiety, for example nitrogen, carbon, or boron; and a cation moiety, for example chromium, zirconium, titanium, vanadium, hafnium, niobium, or tantalum. The phase is present in the cermet at a level of at least about 5 volume %. | 06-10-2010 |
20100143655 | ARTICLES FOR HIGH TEMPERATURE SERVICE AND METHODS FOR THEIR MANUFACTURE - Articles coated via a plasma spray process, and methods for making such articles, are presented. For example, one embodiment is an article comprising a substrate comprising a top surface and a channel disposed in the substrate. The channel is defined by an internal channel surface disposed beneath the top surface and having a terminal end at an orifice at the top surface. A coating is disposed on the top surface and on at least a portion of the internal channel surface. A coating thickness at any point on the internal channel surface is less than a nominal coating thickness on the top surface, and the coating comprises a plurality of at least partially melted and solidified particles. | 06-10-2010 |
20100147185 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials. The oxide materials described herein as a class typically contain one or more of ytterbia (Yb | 06-17-2010 |
20100151197 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials. The oxide materials described herein as a class typically contain one or more of ytterbia (Yb | 06-17-2010 |
20100151264 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials. The oxide materials described herein as a class typically contain one or more of ytterbia (Yb | 06-17-2010 |
20100155252 | MEMBRANE STRUCTURE AND METHOD OF MAKING - A membrane structure is provided. The membrane structure includes a first layer having a plurality of interconnected pores; and a second layer disposed on the first layer. The second layer has a plurality of unconnected pores. Each of the unconnected pores is in fluid communication with at least one of the interconnected pores of the first layer. A method of making a membrane structure is provided. The method includes the steps of providing a first layer having a plurality of interconnected pores; and disposing a second layer on the first layer. Disposing a second layer includes depositing a conducting layer on the first layer; and anodizing the conducting layer to convert the conducting layer into a porous layer. | 06-24-2010 |
20100247321 | ANTI-FOULING COATINGS AND ARTICLES COATED THEREWITH - An article including a metallic substrate is presented. The article further includes a sacrificial layer disposed on a surface of the substrate and an anti-fouling layer disposed on the sacrificial layer. The anti-fouling layer includes a metal-polymer composite. An article including an anti-fouling layer having a nitride is also presented. | 09-30-2010 |
20110083583 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One embodiment is a material comprising a primary oxide and a secondary oxide. The primary oxide comprises cerium or hafnium. The secondary oxide comprises (i) praseodymium or ytterbium, and (ii) another cation selected from the group consisting of the rare earth elements, yttrium, and scandium. | 04-14-2011 |
20110083736 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One particular embodiment is an article that comprises a coating having a surface connected porosity content of up to about 5 percent by volume. The coating comprises a material that comprises a primary oxide and a secondary oxide, wherein (i) the primary oxide comprises a cerium cation, and (ii) the secondary oxide comprises a cation selected from the group consisting of the praseodymium and neodymium. The material is transparent to electromagnetic radiation of at least one type selected from the group consisting of ultraviolet radiation, visible light, and infrared radiation. | 04-14-2011 |
20110086178 | CERAMIC COATINGS AND METHODS OF MAKING THE SAME - A method for forming a ceramic coating is provided. The method includes providing a slurry comprising a liquid and a plurality of feedstock particles disposed in the liquid, injecting the slurry into the flame of a thermal spray gun, and spraying the slurry on a surface of a substrate using the thermal spray gun to form the ceramic coating such that at least a part of the surface of the substrate is covered by the ceramic coating, wherein a thickness of the ceramic coating is in a range from about 10 nanometers to about 3 micrometers, and wherein a density of the ceramic coating is more than about 90 percent, and wherein the ceramic coating is a continuous coating. | 04-14-2011 |
20110086200 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One particular embodiment is an article that comprises a coating having a surface connected porosity content of up to about 5 percent by volume. The coating comprises a material that comprises a primary oxide and a secondary oxide, wherein (i) the primary oxide comprises a cerium cation, and (ii) the secondary oxide comprises a cation selected from the group consisting of the praseodymium and neodymium. | 04-14-2011 |
20110086754 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials, methods for making these articles and materials, and methods for protecting articles using coatings made from these materials. One embodiment is an article comprising a material that is transparent to electromagnetic radiation of at least one type selected from the group consisting of ultraviolet radiation, visible light, and infrared radiation. The material comprises a primary oxide and a secondary oxide. The primary oxide comprises cerium or hafnium. The secondary oxide comprises (i) praseodymium or ytterbium, and (ii) another cation selected from the group consisting of the rare earth elements, yttrium, and scandium. | 04-14-2011 |
20110210013 | SELECTIVE GAS SENSOR DEVICE AND ASSOCIATED METHOD - A detection system is presented. The detection system includes a sensing component and a data analyzer. The sensing component includes a first sensor and a second sensor in fluid communication with the first sensor. The first sensor is disposed to allow operation at a predetermined temperature T | 09-01-2011 |
20110226154 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials. The oxide materials described herein as a class typically contain europia (Eu | 09-22-2011 |
20110293919 | Combustion Cold Spray - Different types of apparatus for fabricating a deposit, method of deposition and an article are presented. The apparatus include a thermal spray gun comprising a combustion chamber, combustion zone, an air injection port, a fuel injection port, a nozzle and a liquid injection port. The combustion zone exists between the inlet side and outlet side of the combustion chamber. The method includes, among other things, providing a fuel and an oxidizer inside the combustion zone, initiating combustion inside the combustion zone, and directing products of the combustion toward the outlet side to create a combustion product stream. The method also includes introducing a feedstock mixture comprising a feedstock material and a liquid into the combustion product stream to create an entrained feedstock stream, and expelling the entrained feedstock stream from the spray gun through a nozzle to form a deposit on a surface of the article. | 12-01-2011 |
20110305873 | COMPOSITION AND METHOD FOR APPLYING A PROTECTIVE COATING - A coating composition includes a cermet material having metal carbide phase particles with an average size of less than 5 microns. The coating has an average surface roughness of less than approximately 5 microns. A system for applying a coating to a substrate includes a spray gun configured for use with a high velocity oxygen or high velocity air fuel system. The system further includes a cermet material supplied to the spray gun, wherein the cermet material includes at least approximately 34 percent by weight of a metal carbide phase having an average particle size of less than or equal to approximately 5 microns. The metal carbide phase is dispersed in a liquid selected from the group consisting of water, alcohol, an organic combustible liquid, or an organic incombustible liquid. | 12-15-2011 |
20120189817 | ARTICLES FOR HIGH TEMPERATURE SERVICE - Articles coated via a plasma spray process, and methods for making such articles, are presented. For example, one embodiment is an article comprising a substrate comprising a top surface and a channel disposed in the substrate. The channel is defined by an internal channel surface disposed beneath the top surface and having a terminal end at an orifice at the top surface. A coating is disposed on the top surface and on at least a portion of the internal channel surface. A coating thickness at any point on the internal channel surface is less than a nominal coating thickness on the top surface, and the coating comprises a plurality of at least partially melted and solidified particles. | 07-26-2012 |
20120251774 | WETTING RESISTANT MATERIALS AND ARTICLES MADE THEREWITH - Ceramic materials with relatively high resistance to wetting by various liquids, such as water, are presented, along with articles made with these materials. The oxide materials described herein as a class typically contain one or more of ytterbia (Yb | 10-04-2012 |
20130108810 | METHOD OF COATING A SURFACE AND ARTICLE INCORPORATING COATED SURFACE | 05-02-2013 |
20130126773 | COATING METHODS AND COATED ARTICLES - One aspect of the present invention includes a method. The method includes combusting a fuel and an oxidant in a combustion chamber of a thermal spray gun to form a combustion stream. The method further includes injecting a liquid and a feedstock material into the combustion stream in the combustion chamber to form an entrained feedstock stream, wherein the feedstock material includes a plurality of cermet particles having a median particle size of less than about 5 microns. The method further includes directing the entrained feedstock stream on a surface of a substrate to form a coating, wherein a temperature of the plurality of cermet particles in the entrained feedstock stream is less than a melting temperature of the plurality of cermet particles. Coated articles are also presented. | 05-23-2013 |
20140037903 | PROTECTIVE COATING WITH HIGH ADHESION AND ARTICLES MADE THEREWITH - Coatings and articles suitable for use in high temperature environments, for example, are presented. One embodiment is a coating that comprises a plurality of elongate material growth domains defined between domain boundaries. The domains have an intra-domain density of at least about 75% of theoretical density, have a substantially equiaxed grain morphology, and comprise a plurality of at least partially melted and solidified particles. Another embodiment is a coating that comprises a matrix comprising a substantially equiaxed grain morphology and a plurality of vertically oriented cracks disposed in the matrix. Further embodiments include articles comprising one or more of the coatings described above. | 02-06-2014 |
20140065361 | THERMAL BARRIER COATING SYSTEMS AND METHODS OF MAKING AND USING THE SAME - A coating comprising a first surface and a second surface is provided. The coating includes a plurality of growth domains. An orientation of at least one growth domain of the plurality of growth domains is non-vertical with respect to the first surface of the coating. One or more growth domains of the plurality of growth domains comprise a plurality of at least partially melted and solidified particles. | 03-06-2014 |
20140175318 | COATING METHODS AND COATED ARTICLES - One aspect of the present invention includes an article. The article includes a substrate and a coating disposed on the substrate, wherein the coating includes a plurality of cermet particles bonded along their prior particle boundaries. The plurality of cermet particles have a median particle size less than about 5 microns and less than 25 percent of the plurality of cermet particles include melted and re-solidified particles. Gate valves are also presented. | 06-26-2014 |
20140178641 | METHODS OF COATING A SURFACE AND ARTICLES WITH COATED SURFACE - A method of coating a surface is provided. The method comprises feeding a feedstock to a thermal spray torch, the feedstock comprising a liquid, disposing the feedstock on a substrate by thermal spray under conditions selected to produce a textured surface comprising a hierarchical structure, wherein the hierarchical structure comprises agglomerations of at least partially melted and solidified particles derived from the feedstock with individual at least partially melted and solidified particles derived from the feedstock disposed on a surface of the agglomerations; and applying a surface energy modification material over the textured surface. An article comprising a component having a coated surface is also provided. | 06-26-2014 |
20140308479 | ARCHITECTURES FOR HIGH TEMPERATURE TBCs WITH ULTRA LOW THERMAL CONDUCTIVITY AND ABRADABILITY AND METHOD OF MAKING - A method for fabricating thermal barrier coatings. The thermal barrier coatings are produced with a fine grain size by reverse co-precipitation of fine powders. The powders are then sprayed by a solution plasma spray that partially melts the fine powders while producing a fine grain size with dense vertical cracking. The coatings comprise at least one of 45%-65% Yb | 10-16-2014 |
20150060403 | METHODS FOR MANUFACTURING AN ADDITIVELY MANUFACTURED FUEL CONTACTING COMPONENT TO FACILITATE REDUCING COKE FORMATION - A method for manufacturing a fuel contacting component that facilitates reducing coke formation on at least one surface of the fuel contacting component is disclosed herein. The method includes applying a slurry composition including a powder including aluminum to the component surface, wherein the fuel contacting component is formed by an additive manufacturing process. The slurry composition is heat treated to diffuse the aluminum into the component surface. The heat treatment comprises forming a diffusion aluminide coating on the component surface, wherein the diffusion coating comprises a diffusion sublayer formed on the component surface and an additive sublayer formed on the diffusion sublayer. The method further comprises removing the additive sublayer of the diffusion aluminide coating with at least one aqueous solution such that the diffusion sublayer and the component surface are substantially unaffected, wherein the diffusion layer facilitates preventing coke formation on component surface. | 03-05-2015 |