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Halasa

Adel Farhan Halasa, Bath, OH US

Patent application numberDescriptionPublished
20090156769FUNCTIONALIZED MONOMERS AND FUNCTIONALIZED RUBBERY POLYMERS MADE THEREWITH - Rubbery polymers can be formed having the general formula:06-18-2009
20100043938DENDRIMERS OF RUBBERY POLYMERS - This invention discloses a process for synthesizing a dendrimer of a rubbery polymer comprising: (a) reacting a lithium terminated rubbery polymer with a halogenated silicon containing compound to produce a polymer which is terminated with halogenated silicon moieties, wherein the halogenated silicon contain compound has at least four halogen atoms which are bonded directly to silicon atoms, wherein the ratio of the lithium terminated rubbery polymer to halogen atoms in the halogenated silicon containing compound is within the range of 2:n to (n-1):n, wherein n represents the number of halogen atoms that are bonded directly to silicon atoms in the halogenated silicon containing compound, wherein the halogenated silicon containing compound contains at least three halogen atoms which are bonded directly to a silicon atom; (b) reacting the polymer which is terminated with halogenated silicon moieties with a molar excess of a tertiary alcohol to produce a polymer which is terminated with hydroxy silyl moieties; and (c) allowing the polymer which is terminated with the hydroxy silyl moieties to couple under conditions sufficient to produce a dendrimer containing siloxane linkages. It has also be found that similar dendrimers having improved processability can be make utilizing halogenated tin containing compounds in stead of the halogenated silicon containing compound.02-25-2010
20100063202Methods of Making Siloxy-Amine Functionalized Rubbery Polymers and Uses Thereof in Rubber Compositions for Tires - The invention includes a siloxy-amine functionalized rubbery polymer, which exhibits good reinforcing characteristics and filler dispersing effect, a method for making, and a rubber composition including the same. In one embodiment, a process for manufacturing includes polymerizing a conjugated diene monomer using an organolithium compound as an initiator in a hydrocarbon solvent. Next, an active terminal end of the polymer is reacted with a functionalized terminating agent represented by:03-11-2010
20100093960Potassium Based Catalyst Systems For Synthesizing Rubbery Polymers - The present invention is directed to a catalyst system for synthesizing rubbery polymers, such as styrene-butadiene rubber, that can be utilized in tire tread rubbers. The catalyst system, in one embodiment, includes an organolithium compound and a potassium alkyl borohydride or potassium alkyl aluminum hydride defined by: (R)04-15-2010
20100108230SYNTHESIS OF SOLUBLE FUNCTIONALIZED LITHIUM INITIATORS - This invention discloses a process for making dilithium initiators in high purity. This process can be conducted in the absence of amines which is desirable since amines can act as modifiers for anionic polymerizations. The dilithium compounds made are highly desirable because they are soluble in aromatic solvents. The present invention also discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is a cured the rubber formulation which is comprised of (a) at least one rubbery polymer containing functional groups of the structural formula:05-06-2010
20100206443Heterogeneous Rubbery Polymers Having Random, Tapered, and Block Portions Therein and Methods of Making Same - A heterogeneous rubbery polymer is provided that includes a polymer chain derived from a vinyl aromatic monomer and a conjugated diolefin monomer, wherein from greater than 20 weight percent to about 40 weight percent of units in the rubbery polymer are derived from the vinyl aromatic monomer and from about 60 weight percent to about 80 weight percent of units in the rubbery polymer are derived from the conjugated diolefin monomer. The polymer chain is further characterized by having greater than zero and less than about 30 weight percent of the vinyl aromatic units in sequences containing 1 vinyl aromatic unit, from about 5 weight percent to about 20 weight percent of the vinyl aromatic units in sequences containing 5 to 8 vinyl aromatic units, and greater than zero and less than about 5 weight percent of the vinyl aromatic units in sequences containing 9 or more vinyl aromatic units.08-19-2010
20100288407DENDRIMERS OF RUBBERY POLYMERS - This invention discloses a process for synthesizing a dendrimer of a rubbery polymer comprising: (a) reacting a lithium terminated rubbery polymer with a halogenated tin containing compound to produce a polymer which is terminated with halogenated tin moieties, wherein the halogenated tin containing compound is of the structural formula:11-18-2010

Patent applications by Adel Farhan Halasa, Bath, OH US

Matej Halasa, Lessines BE

Patent application numberDescriptionPublished
20120027667Method for the production of hydrogen peroxide - A process for production of hydrogen peroxide which comprises the following steps: (a) hydrogenation of a working solution comprising at least one non-ionic quinone compound selected from the group consisting of anthraquinone and its derivatives, phenanthrenequinone and its derivatives, naphthoquinone and its derivatives, and benzoquinone and its derivatives, wherein the total molecular weight of optional groups attached to the quinone skeleton is lower than 500, to obtain at least one corresponding hydroquinone compound; (b) oxidation of the at least one hydroquinone compound to obtain hydrogen peroxide; and (c) separation of the hydrogen peroxide, during and/or subsequently to the oxidation step b); wherein the working solution of either step a) and/or b) comprises less than 30% by weight of organic solvent.02-02-2012