Patent application number | Description | Published |
20110009529 | Copolymer Having Polyether Side Chains And Dicarboxylic Acid Derivative Components - The invention relates to a copolymer which can be used as a superplasticizer for hydraulic binders and comprises 30 to 47 mol % of a (meth)allyl alcohol polyether derivative structural unit and 53 to 70 mol % of a maleic acid derivative structural unit. | 01-13-2011 |
20110009575 | Semi Continuous Operational Method For Producing Copolymers - The invention relates to a process for the preparation of a copolymer in a semicontinuous mode of operation in a polymerization apparatus containing a polymerization reactor connected to a metering device, in each case acid monomer being initially introduced into the metering device and polyether macromonomer and water into the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, free radical polymerization initiator being passed into the polymerization reactor before and/or during the metering of the acid monomer into the polymerization reactor, so that an aqueous medium forms in the polymerization reactor, in which aqueous medium acid monomer and polyether macromonomer are reacted by free radical polymerization with formation of the copolymer, at least 70 mol % of the polyether macromonomer initially introduced into the polymerization reactor being converted by the free radical polymerization, the conversion of the acid monomer giving rise in the copolymer to an acid structural until which reduces the pH of the aqueous medium to a lesser extent than the acid monomer as such, the metering of the acid monomer into the polymerization reactor being effected in such a way that first a polymerization pH is established in the aqueous medium and then, until the conversion of 70 mol % of the polyether macromonomer initially introduced into the polymerization reactor, acid monomer is passed into the polymerization reactor in an amount per unit time such that the pH in the aqueous medium deviates by not more than ±0.3 from the initially established polymerization pH. | 01-13-2011 |
20110034592 | Aqueous Solution Containing Copolymers with Polyether Side Chains - The invention relates to a process for the preparation of an aqueous solution comprising 30 to 95% by weight of water and 5 to 70% by weight of a copolymer dissolved in the water by free radical solution polymerizations of an isoprenol polyether derivative with an acrylic acid derivative, so that the copolymer has 20 to 45 mol % of an isoprenol polyether derivative structural unit and 55 to 80 mol % of an acrylic acid derivative structural unit. The aqueous solution is suitable as a superplasticizer for hydraulic binders. | 02-10-2011 |
20110034625 | METHOD FOR INITIATING RADICAL POLYMERIZATIONS - The invention relates to a process for the preparation of polymers by free radical polymerization of monomers in the presence of water, electrochemically produced free radicals being used for initiating the free radical polymerization. | 02-10-2011 |
20110054083 | Copolymer Comprising Polyether Side Chains and Hydroxyalkyl and Acid Structural Units - The invention relates to a copolymer which is suitable as a superplasticizer for hydraulic binders and comprises 5 to 55 mol % of an isoprenol polyether derivative structural unit, 2 to 90 mol % of an acrylic acid derivative structural unit and 2 to 90 mol % of a hydroxyalkyl acrylate structural unit. | 03-03-2011 |
20110203486 | Hardening Accelerator Composition Containing Dispersants - A process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound, said reaction being effected in the presence of a water-soluble dispersant having at least one polyalkyleneglycol structural unit with a functional group at one end of the polyalkyleneglycol, being able to interact as an anchor group with the surface of cement particles, the hardening accelerator composition and its use. | 08-25-2011 |
20110269875 | Plasticizer-Containing Hardening Accelerator Composition - The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and a process for the preparation of a hardening accelerator composition by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction of the water-soluble calcium compound with the water-soluble silicate compound being carried out in the presence of an aqueous solution which contains a water-soluble comb polymer suitable as a plasticizer for hydraulic binders. The invention concerns also a composition of calcium silicate hydrate and comb polymer, its use as hardening accelerator and for the reduction of the permeability of hardened compositions. | 11-03-2011 |
20110294923 | Polymerization Mixture That Can Be Produced Without Water - The invention relates to a process for the preparation of a polymerization mixture suitable as a dispersant and comprising a copolymer. In the process, a vinyloxyalkylpolyether derivative is reacted with an acid monomer derivative with formation of the copolymer in the presence of a free radical polymerization initiator by free radical polymerization, the free radical polymerization taking place in a medium which contains less than 25% by weight of water and in totality more than 60% by weight of copolymer, vinyloxyalkylpolyether derivative and acid monomer derivative. | 12-01-2011 |
20120004350 | Semi Continuously Operated Method for Producing Copolymers - The invention relates to a process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, in each case acid monomer being initially taken in the metering device and polyether macromonomer, acid monomer and water in the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, free radical polymerization initiator being passed into the polymerization reactor before and/or during the metering of the acid monomer into the polymerization reactor so that an aqueous medium in which acid monomer and polyether macromonomer are reacted with formation of the copolymer by free radical polymerization forms in the polymerization reactor, the molar ratio of acid monomer used altogether to polyether macromonomer used altogether being 20:1 to 1:1, the molar ratio of acid monomer initially taken in the polymerization reactor to the acid monomer metered into the polymerization reactor being 10:1 to 1:10 and the metering of the acid monomer being effected with the proviso that at least 70 mol % of the acid monomer metered in altogether are metered in the course of 5 to 19 minutes at a metering rate that is constant or varies to a limited extent. | 01-05-2012 |
20120041106 | Dispersing Agent Containing Copolymer Mixture - The invention relates to a polymer composition containing 5 to 95% by weight of a copolymer H and 2 to 60% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymer H having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymer H varying in such a way that the corresponding frequency distribution diagram, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted along the abscissa and the associated frequency for the copolymer H is plotted along the ordinate, contains at least 2 maxima. | 02-16-2012 |
20120216724 | Sulphonic Acid And Aromatic Groups Containing Hardening Accelerator Compositions - The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction being carried out in the presence of an aqueous solution of a water-soluble polymer, which contains sulphonic acid and/or sulphonate groups and aromatic groups. The invention concerns also the reaction product of said processes and its use as hardening accelerator for building materials. | 08-30-2012 |
20120220696 | Hardening Accelerator Composition Containing Phosphated Polycondensates - The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction being carried out in the presence of a polycondensate containing at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing a polyether side chain and at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing at least one phosphoric acid ester group and/or its salt. The invention concerns a composition of calcium silicate hydrate and the polycondensate, its use as hardening accelerator and for the reduction of the permeability of hardened compositions. | 08-30-2012 |
20130233552 | MACROMOLECULAR, AMPHIPHILIC COMPOUNDS AS WATER RETENTION AGENTS FOR CONSTRUCTION CHEMISTRY SYSTEMS, IN PARTICULAR FOR WELL CEMENTING - The water retention agents according to the invention are outstandingly suitable as additives in construction chemistry systems and in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep wells, their effect being particularly advantageous at increased temperatures and because of their lack of influence on the rheological properties of the well slurries. | 09-12-2013 |