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Geoffrey W. Coates

Geoffrey W. Coates, Lansing, NY US

Patent application numberDescriptionPublished
20100144969ISOSELECTIVE POLYMERIZATION OF EPOXIDES - The present invention provides novel bimetallic complexes and methods of using the same in the isoselective polymerization of epoxides. The invention also provides methods of kinetic resolution of epoxides. The invention further provides polyethers with high enantiomeric excess that are useful in applications ranging from consumer goods to materials.06-10-2010
20100145046Substituted 3-hydroxy-delta-lactones from epoxides - Catalysts and methods for the carbonylation of epoxides to substituted 3-hydroxy-δ-lactones and β-lactones are disclosed.06-10-2010
20100204437POLYCARBONATES MADE USING HIGHLY SELECTIVE CATALYSTS - Poly(propylene carbonates) are prepared from propylene oxide and CO08-12-2010
20100311941COPOLYMERIZATION OF EPOXIDES AND CYCLIC ANHYDRIDES - The present invention provides novel polymers and methods of preparing the same.12-09-2010
20110087001POLYMERS OF ETHYLENE OXIDE AND CARBON DIOXIDE - The present disclosure is directed, in part, to methods of synthesizing a poly(ethylene carbonate) polymer from the reaction of ethylene oxide (EO) and carbon dioxide (CO04-14-2011

Geoffrey W. Coates, Ithaca, NY US

Patent application numberDescriptionPublished
20080214854Production of isotactic and regiorandom polypropylene based polymer and block copolymers - One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF09-04-2008
20080262164Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide) - (Salph or methoxy salph) Co (initiating ligand) catalyze homopolymerizing rac-PO to produce pure highly isotactic PPO and rac-1-butylene oxide to produce pure isotactic poly(butylene oxide). A product is unfractionated isotactic PPO of m-dyad content >81%, normally at least 99%.10-23-2008
20090192278Alkene polymerization using beta-ketoiminato metal complexes - Group (IV) and (X) metal complexes with ketoiminate ligands are prepared by deprotonation of a ketoimine ligand followed by reaction with the appropriate metal halide. In preferred cases, the compounds are titanium (IV), zirconium (IV) and hafnium (IV), preferred cases, the compounds are titanium (IV), zirconium (IV) and hafnium (IV) complexes with (arylimino-alkyl)-spiro[4,5]decan-6-one ligands. The compounds are useful as catalysts for polymerizing ethylene, C07-30-2009
20090287000LOW PRESSURE CARBONYLATION OF HETEROCYCLES - Heterocycles, e.g., epoxides, are carbonylated at low pressure with high percentage conversion to cyclic, ring expanded products using the catalyst11-19-2009
20100029882Production of isotactic and regiorandom polypropylene based polymer and block copolymers - One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF02-04-2010
20100036077Regioregular polymerization of alpha-olefins to produce polyethylene with a predominance of methyl substituents - Regioregular polymers of C02-11-2010
20100063213GEL-PROCESSED POLYOLEFIN COMPOSITIONS - Semicrystalline polyolefins with narrow molecular weight distributions characterized by a low polydispersity index (PDI) and selected from the families of homopolymers, statistical copolymers, block copolymers, and graft copolymers, can be blended with a low molecular weight fluid diluent to create gel fiber and film compositions. These gel compositions, when subjected to mechanical or thermomechanical processing, either before or after removal of the diluent, result in fiber or film compositions that combine high tensile strength with other desirable physical properties, such as high rigidity, large extension at break, and/or high recoverable elasticity. These desirable combinations of properties are superior to those obtained from gel-processed semicrystalline polyolefins that are substantially similar in composition and molecular weight, but that have large PDIs.03-11-2010
20110152497CATALYSTS AND METHODS FOR POLYMER SYNTHESIS - The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.06-23-2011

Patent applications by Geoffrey W. Coates, Ithaca, NY US