Patent application number | Description | Published |
20090133536 | PROCESS FOR SEPARATING AND RECOVERING BASE METALS FROM USED HYDROPROCESSING CATALYST - A method is disclosed for separating and recovering base metals from a used hydroprocessing catalyst originating from Group VIB and Group VIII metals and containing at least a Group VB metal. In one embodiment, the used catalyst is contacted with an ammonia leaching solution to dissolve and separate the Group VIB and VIII metals from the Group VB metal complex and coke associated with the used catalyst. The resulting Group VIB and VIII metal containing solution is processed through at least two additional precipitation and liquid/solid separation steps to produce, in separate processing streams, a Group VIB metal product solution (such as ammonium molybdate) and a Group VIII metal product solution (such as nickel sulfate). Additionally, two separate filtrate streams are generated from liquid-solid separation steps, which filtrate streams are combined and subjected to hydrolysis and oxidation (oxydrolysis) to generate a purified ammonium sulfate solution for further processing, such as for fertilizer. | 05-28-2009 |
20090136399 | Process for Recovering Base Metals from Spent Hydroprocessing Catalyst - A method for recovering metals from a spent dispersed catalyst originating from a Group VIB metal sulfide catalyst containing at least a Group VB and Group VIII metal for hydrocarbon oil hydroprocessing is disclosed. In one embodiment, the method comprises the steps of: contacting the spent dispersed catalyst with a leaching solution containing ammonia and air to dissolve the group VIB metal and the Group VIII metal into the leaching solution at sufficient temperature and pressure; forming a slurry containing at least a group VIB metal complex and at least a group VIII metal complex, ammonium sulfate and solid residue containing at least a Group VB metal complex and coke; separating and removing the solid residue containing ammonium metavanadate and coke from the pressure leach solution (PLS); precipitating from the PLS at least a portion of the Group VIB metal and at least a portion of the Group VIII metal by controlling the pH at a pre-selected pH to selectively precipitate as metal complexes the Group VIB and Group VIII metals. | 05-28-2009 |
20090136400 | PROCESS FOR SEPARATING AND RECOVERING BASE METALS FROM USED HYDROPROCESSING CATALYST - A method is disclosed for separating and recovering base metals from a used hydroprocessing catalyst originating from Group VIB and Group VIII metals and containing at least a Group VB metal. In one embodiment, the method comprises the steps of: contacting the used catalyst with an ammonia leaching solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution; forming a leached slurry containing at least a group VIB metal complex and at least a group VIII metal complex, ammonium sulfate and a solid residue containing at least a Group VB metal complex and coke; separating and removing from the leached slurry the solid residue and coke; precipitating from the remaining solution at least a portion of the Group VIB metal complex and at least a portion of the Group VIII metal complex by controlling the pH to form a liquid material substantially free of Group VB, Group VIB and Group VIII metals and another solid material comprising substantially Group VIB and Group VIII metal complexes. Said solid material is further processed by dissolution, means of separation, further means of precipitation and oxidative dissolution to produce, separately, a Group VIB metal product solution, a Group VIII metal product solution and a purified ammonium sulfate product solution. | 05-28-2009 |
20100300250 | PROCESS FOR RECOVERING METALS FROM COAL LIQUEFACTION RESIDUE CONTAINING SPENT CATALYSTS - In one embodiment, this invention is directed to a method of recovering metals from a metals bearing material comprising: reducing the particle size of at least a portion of the metals bearing material; mixing the metals bearing material in an acid solution to form a first slurry containing at least alkaline earth metal compounds; separating the at least alkaline earth metal compounds from the first slurry to form a first filtrate and a metals bearing material; leaching metals from the metals bearing material to form a pressure leach solution containing transition metals; precipitating and recovering transition metals from the pressure leach solution. In another aspect, the invention relates to a method for recovering metals from a deoiled and dried coal liquefaction residue that contains spent catalyst originating from a Group VIB metal sulfide catalyst. | 12-02-2010 |
20110017636 | Systems and Methods for Producing a Crude Product - A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. At least an additive material selected from inhibitor additives, anti-foam agents, stabilizers, metal scavengers, metal contaminant removers, metal passivators, and sacrificial materials, in an amount of less than 1 wt. % of the heavy oil feedstock, is added to at least one of the contacting zones. In one embodiment, the additive material is an anti-foam agent. In another embodiment, the additive material is a sacrificial material for trapping heavy metals in the heavy oil feed and/or deposited coke, thus prolonging the life of the slurry catalyst. | 01-27-2011 |
Patent application number | Description | Published |
20120039777 | PROCESS FOR SEPARATING AND RECOVERING METALS - A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals. | 02-16-2012 |
20120172202 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - A process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a pressure leach solution obtained from a metal recovery process as part of the metal precursor feed. In one embodiment, the process comprises: sulfiding a pressure leach solution having at least a Group VIB metal precursor compound in solution forming a catalyst precursor, and mixing the sulfided catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In another embodiment, the pressure leach solution is mixed with a hydrocarbon diluent under high shear mixing conditions to form an emulsion, which emulsion can be sulfided in-situ upon contact with a heavy oil feedstock in the heavy oil upgrade process. | 07-05-2012 |
20120193295 | METHOD FOR TREATING EFFLUENT WATERS - A process for treating waste water, effluent streams, e.g., acid mine drainage, containing heavy metals and soluble contaminants is provided. In one embodiment, at least a metal cation is added to the effluent water at a pre-selected pH to form insoluble heavy metal complexes. In one embodiment, the metal cation is a trivalent metal ion, e.g., ferric iron such as in ferric sulfate. In another embodiment, a divalent metal ion such as ferrous sulfate is used. After the removal of the heavy metal complexes, the effluent water is treated with an aluminum salt such as calcium aluminate to remove remaining soluble contaminants, thus producing a treated water stream with reduced levels of contaminants. | 08-02-2012 |
20120193296 | Method for Treating Acid Mine Drainage - A process for treating acid mine drainage containing heavy metals and soluble contaminants is provided. In one embodiment, at least a metal cation is added to the acid mine drainage at a pre-select pH to form insoluble heavy metal complexes. In one embodiment, the metal cation is a trivalent metal ion, e.g., ferric iron such as in ferric sulfate. In another embodiment, a divalent metal ion such as in ferrous sulfate is used. After the removal of the heavy metal complexes, the effluent water is treated with at least a phosphate additive to remove remaining soluble contaminants, thus producing a treated water stream with reduced levels of contaminants. | 08-02-2012 |
20140248199 | RECOVERY OF VANADIUM FROM PETROLEUM COKE SLURRY CONTAINING SOLUBILIZED BASE METALS - A method for recovering vanadium from a spent slurry catalyst for hydrocarbon oil hydroprocessing is disclosed. In one embodiment after de-oiling, the spent catalyst is treated with ammonia and air, forming a leach slurry. The leach slurry is subsequently treated with a flocculant. After solid-liquid separation to recover the solid residue containing coke and ammonium metavanadate, the solid residue is washed with an ammonium sulfate solution and leached with hot water. After solid-liquid separation to recover a solution containing ammonium metavanadate, the ammonium metavanadate is crystallized and purified from the leach solution. | 09-04-2014 |
20140251914 | METHOD FOR TREATING ACID MINE DRAINAGE - A process for treating acid mine drainage containing heavy and base metals and soluble contaminants is provided. In one embodiment, at least a metal cation is added to the acid mine drainage at a pre-select pH to form insoluble heavy and base metal complexes. After the removal of the heavy and base metal complexes, the pH is raised to the alkaline range. Following removal of base metal hydroxides and gypsum, membrane filtration is employed to generate a treated membrane permeate having a reduced concentration of heavy and base metals and soluble contaminants, and a membrane reject stream containing a concentrated brine. The concentrated brine is further treated with additional lime and at least an aluminum salt to remove remaining soluble contaminants, thus producing a treated water stream with reduced levels of contaminants. Carbonation with CO | 09-11-2014 |
20140348729 | PROCESS FOR SEPARATING AND RECOVERING METALS - A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals. | 11-27-2014 |
Patent application number | Description | Published |
20150083397 | METHOD OF INHIBITING FOULING ON A METALLIC SURFACE USING A SURFACE MODIFYING TREATMENT AGENT - Fouling caused by contaminants onto a metallic tubular, flow conduit or vessel in an underground reservoir or extending from or to an underground reservoir may be inhibited by applying onto the surface of the metallic tubular, flow conduit or vessel a treatment agent comprising a hydrophobic tail and an anchor. The anchor attaches the treatment agent onto the surface of the metallic tubular, flow conduit or vessel. | 03-26-2015 |
20150083414 | ORGANOPHOSPHORUS CONTAINING COMPOSITES FOR USE IN WELL TREATMENT OPERATIONS - A composite having a solid particulate and a surface modifying treatment agent on the solid particulate wherein the surface modifying treatment agent has a hydrophobic tail and an anchor for adhering the hydrophobic tail onto the solid particulate. The anchor is an organophosphorus acid derivative. The composite may be used as a proppant in a hydraulic fracturing operation as well as a sand control particulate in a gravel packing operation. The presence of the surface modifying treatment agent on the surface of the solid particulate reduces the generation of fines and dust as well as the migration of sand during a hydraulic fracturing operation or a sand control operation. The presence of the surface modifying treatment agent on the surface of the solid particulate further enhances the crush resistance of the solid particulate. | 03-26-2015 |
20150083415 | COMPOSITES FOR USE IN STIMULATION AND SAND CONTROL OPERATIONS - A composite having a solid particulate and a surface modifying treatment agent on the solid particulate wherein the surface modifying treatment agent has a hydrophobic tail and an anchor for adhering the hydrophobic tail onto the solid particulate. The anchor may be metal and the hydrophobic tail may be an organo-silicon material, a fluorinated hydrocarbon or both an organo-silicon material and a fluorinated hydrocarbon. The composite may be used as a proppant in a hydraulic fracturing operation as well as a sand control particulate in a gravel packing operation. The presence of the surface modifying treatment agent on the surface of the solid particulate reduces the generation of fines and dust as well as the migration of sand during a hydraulic fracturing operation or a sand control operation. The presence of the surface modifying treatment agent on the surface of the solid particulate further enhances the crush resistance of the solid particulate. | 03-26-2015 |
20150083416 | METHOD OF USING SURFACE MODIFYING TREATMENT AGENTS TO TREAT SUBTERRANEAN FORMATIONS - A well treatment fluid contains a surface modifying treatment agent having an anchor and a hydrophobic tail. The surface modifying treatment agent is an organophosphorus acid derivative. After the well treatment fluid is pumped into a well penetrating the subterranean formation, the anchor binds to the surface of the formation. The subterranean formation is a siliceous formation or a metal oxide-containing subterranean formation. The anchor bonds to a Si atom when the formation is a siliceous formation and to the metal of the metal oxide when the formation is a metal oxide-containing formation. After being bound to the surface of the formation, frictional drag within the well is reduced. This allows for faster recovery of formation fluids. The bonding of the surface modifying treatment agent onto the formation may further be enhanced by first pre-treating the formation with a non-aqueous fluid. By increasing the number of sites for the surface modifying treatment agent to bind onto the surface of the subterranean formation, productivity is improved. | 03-26-2015 |
20150083417 | METHOD OF USING SURFACE MODIFYING METALLIC TREATMENT AGENTS TO TREAT SUBTERRANEAN FORMATIONS - A method of treating a subterranean formation comprises pumping into a well penetrating the formation a surface modifying treatment agent having a metallic anchor and at least one hydrophobic tail attached to the metal of the anchor. The surface modifying treatment agent is covalently bound to the surface of the subterranean formation through the metal of the anchor. | 03-26-2015 |
20150129216 | COMPOSITION AND METHOD FOR TREATING SUBTERRANEAN FORMATIONS USING INORGANIC FIBERS IN INJECTED FLUIDS - A method of plugging an opening in a subterranean formation such as a fracture system is provided. A gel composition can be provided which includes an aqueous fluid, a cross-linkable polymer soluble in the aqueous fluid and a cross-linking agent. Inorganic fibers can be added to the gel composition. The gel composition can be injected into the opening in the subterranean formation. The gel composition can be cross-linked, and the opening can be plugged with the gel composition. In certain illustrative embodiments, the inorganic fibers can be mineral wool fibers. | 05-14-2015 |
20150299561 | METHOD OF PUMPING AQUEOUS FLUID CONTAINING SURFACE MODIFYING TREATMENT AGENT INTO A WELL - A well treatment fluid contains a surface modifying treatment agent having an anchor and a hydrophobic tail. The surface modifying treatment agent is an organophosphorus acid derivative. After the well treatment fluid is pumped into a well penetrating the subterranean formation, the anchor binds to the surface of the formation. The subterranean formation is a siliceous formation or a metal oxide-containing subterranean formation. The anchor bonds to a Si atom when the formation is a siliceous formation and to the metal of the metal oxide when the formation is a metal oxide-containing formation. After being bound to the surface of the formation, frictional drag within the well is reduced. This allows for faster recovery of formation fluids. The bonding of the surface modifying treatment agent onto the formation may further be enhanced by first pre-treating the formation with an aqueous fluid. By increasing the number of sites for the surface modifying treatment agent to bind onto the surface of the subterranean formation, productivity is improved. | 10-22-2015 |