Patent application number | Description | Published |
20080286159 | Variable Tube Diameter For SMR - A catalyst tube is provided, that includes a bore, wherein said bore is adapted to contain a catalyst bed. The catalyst tube also includes a proximal end, wherein said proximal end has a first inside diameter, a first outside diameter, and a first wall thickness. The catalyst tube also includes a distal end, wherein said distal end has a second inside diameter, a second outside diameter, and a second wall thickness. The catalyst tube may be tapered, with a uniform wall thickness. The catalyst tube may have a uniform outside diameter, with a tapered inside diameter, and a non-uniform wall thickness. The catalyst tube may have a tapered outside diameter, a uniform inside diameter, and non-uniform wall thickness. | 11-20-2008 |
20090165377 | METHOD FOR PRODUCING SYNTHETIC GAS USING AN OXYGEN-CONTAINING GAS PRODUCED BY AT LEAST ONE GAS TURBINE - The invention concerns a method for producing synthetic gas on an industrial site comprising at least one gas turbine wherein the oxygen-containing gas produced by the gas turbine is upgraded in a combustion implemented on the industrial site or in a heat recovery unit of the industrial site. Preferably, the oxygen-containing gas is used as oxidant of the combustion thereby enabling the reaction for forming the syngas. The invention also concerns a method for controlling the introduction of the oxygen-containing required for combustion to enable the syngas to be formed into a syngas reactor and an associated device. | 07-02-2009 |
20090241551 | Cogeneration of Hydrogen and Power - A process for the integration of power generation and an SMR, including introducing a combustion air stream into a compressor, thereby producing a compressed air stream. The compressed air stream is then introduced, along with a combustor feed gas stream into a first combustor, thereby producing a first exhaust gas stream. The first exhaust gas stream is then introduced into the shell-side of an SMR, thereby providing the heat for the reforming reaction, and generating a syngas stream and a second exhaust gas stream. The second exhaust gas stream is introduced, along with a secondary fuel stream, into a second combustor, thereby producing a third exhaust gas stream. The third exhaust gas stream is then introduced into an expander, thereby producing power output and a fourth exhaust gas stream. | 10-01-2009 |
20090265988 | Hydrogenation Of Unsaturated Hydrocarbons For Syngas Production - A method of hydrogenation of unsaturated hydrocarbons for syngas production is presented. A hydrogenation feed reactor stream is introduced into a hydrogenation reactor, thereby producing a reformer feed stream. The reformer feed stream is introduced into a reformer, thereby producing a crude syngas stream. The crude syngas stream is introduced into a water gas shift converter, thereby producing a hydrogen-rich stream. The hydrogen-rich stream is separated in a separation means, thereby producing a carbon dioxide-rich stream and a hydrogen product stream. At least a portion of the hydrogen product stream is combined with a refinery fuel gas stream, and a natural gas stream, to form the hydrogenation reactor feed stream. | 10-29-2009 |
20100037655 | Hydrogen Recovery From A Mixture Of Hydrogen and Hydrocarbons At Low Pressure And Of Low Hydrogen Content - A method for recovering hydrogen from a gas stream is presented. This method includes introducing a feed gas stream comprising hydrogen and methane to a first cold box, thereby producing a first hydrogen-enriched stream, and a first methane-enriched stream; then introducing the first hydrogen-enriched stream to a first feed compressor, thereby producing a compressed first hydrogen-enriched stream. The method includes introducing the compressed first hydrogen-enriched stream to a second cold box, thereby producing a second hydrogen-enriched stream, and a second methane-enriched stream; then introducing the second hydrogen-enriched stream to a second feed compressor, thereby producing a compressed second hydrogen-enriched stream. The method includes introducing the compressed second hydrogen-enriched stream to a third cold box, thereby producing a third hydrogen-enriched stream, and a third methane-enriched stream. This method includes introducing the third hydrogen-enriched stream to a third feed compressor, thereby producing a compressed third hydrogen-enriched stream; then introducing the compressed third hydrogen-enriched stream to a PSA, thereby producing a high pressure, high purity hydrogen stream, and a tail gas stream. This method includes introducing a first part of the tail gas stream to a tail gas compressor, and recycling the compressed tail gas back to the feed gas stream; then combining the first methane-enriched stream, the second methane-enriched stream, the third methane-enriched stream, and a second part of the tail gas stream into a fuel stream. And this method includes introducing the fuel stream to a methane compressor. | 02-18-2010 |
20100104499 | Zero Steam Export With CO2 Recovery In A High Thermal Efficiency Hydrogen Plant - A high thermal efficiency process for hydrogen recovery is provided. The present invention includes combusting a first fuel stream to a reforming furnace, producing reforming heat and a hot exhaust stream. Then exchanging heat indirectly between the hot exhaust stream and a first feed water stream, producing a first steam stream. Then providing a hydrocarbon containing stream and a feed steam stream to the reforming furnace, utilizing the reforming heat and producing a hot raw syngas stream. Then exchanging heat indirectly between the hot raw syngas stream and second feedwater stream, producing a second steam stream and a cooled, raw syngas stream. Then introducing the cooled, raw syngas stream to a CO shift converter, producing a shifted syngas stream. Then introducing the shifted syngas stream into a pressure swing adsorption unit, producing a hydrogen product stream and a tail gas stream. Then introducing the tail gas stream to a CO2 removal unit, producing a CO2 stream and a recycle stream; compressing the recycle stream, producing a compressed recycle stream. Then combining the compressed recycle stream with at least one stream selected from the group consisting of the hydrocarbon containing stream, the cooled raw syngas stream, the shifted syngas stream, and the tail gas stream. Then combining the first steam stream and the second steam stream, producing the feed steam stream. | 04-29-2010 |
20100224061 | Process and Apparatus For CO2 Recovery From Flue Gas With Thermocompression - A process for the recovery of CO | 09-09-2010 |
20100284892 | Process For The Purification Of A Carbon Dioxide Stream With Heating Value And Use Of This Process In Hydrogen Producing Processes - The present invention relates to a process for purifying a CO | 11-11-2010 |
20110011128 | Process For The Production Of Carbon Dioxide Utilizing A Co-Purge Pressure Swing Adsorption Unit - The present invention provides a process for recovering gaseous hydrogen and gaseous carbon dioxide from a mixture of hydrocarbons by utilizing a system that includes a reformer unit, an optional water gas shift reactor, and a pressure swing adsorption unit in conjunction with a carbon dioxide purification unit such as a cryogenic purification unit or a catalytic oxidizer. In this process, purified CO | 01-20-2011 |
20110085966 | High Hydrogen Recovery From Residual Fuels And Biomass - A method of high hydrogen recovery from syngas from a gasifier is provided. This method includes providing a syngas stream from the gasifier to first hydrogen separation device, wherein the first hydrogen separation device is a pressure swing adsorption device, thereby producing a first high purity hydrogen stream and a tailgas stream. This method also includes increasing the pressure of the tailgas stream in a first compressor; thereby producing a pressurized tailgas stream. This method also includes providing the pressurized tailgas stream to a second hydrogen separation device, thereby producing a second high purity hydrogen stream and a residue stream. This method also includes directing the residue stream to an auxiliary boiler, and combining the first high purity hydrogen product stream and the second high purity hydrogen product stream, thereby producing a high purity hydrogen product stream. | 04-14-2011 |
20110097260 | Hydrogen Recovery And Methane Production From Residual Fuels and Biomass - A method of hydrogen and methane recovery from syngas from a gasifier is provided. Then directing a raw syngas stream from an acid gas removal system to a CO and methane removal system. Then returning the CO and methane stream to the gasifier, and exporting the hydrogen stream as a product. | 04-28-2011 |
20110100214 | PSA Tail Gas Preheating - A process for improving the thermodynamic efficiency of a hydrogen generation system is provided. This includes producing a syngas stream in a reformer, wherein the reformer has a combustion zone. This also includes introducing a syngas stream into a pressure swing adsorption unit, thereby producing a product hydrogen stream and a tail gas stream. This also includes heating the tail gas stream by indirect heat exchange with a heat source, thereby producing a heated tail gas stream; and introducing the heated tail gas stream into the combustion zone. | 05-05-2011 |
20120003145 | Process For Recovering Hydrogen And Carbon Dioxide From A Syngas Stream - The present invention provides a process for recovering high purity gaseous hydrogen and high purity gaseous carbon dioxide from a syngas stream by utilizing a hydrogen selective membrane unit and a primary water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor or by utilizing a hydrogen membrane/water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor. Each of these embodiments may further include a sulfur recovery unit. | 01-05-2012 |
20120118011 | Process For The Production Of Hydrogen And Carbon Dioxide - The present invention provides a method to more efficiently recover hydrogen and carbon dioxide as well as a design for carbon dioxide capture from syngas that allows for the simultaneous production of medium to high amounts of hydrogen and the capture of at least 90% of the carbon dioxide in the syngas as a part of the production of hydrogen in a hydrogen generation plant. Through the use of a combination of hydrogen selective membranes and carbon dioxide selective membranes together with a carbon dioxide separation unit it is possible to increase recovery of hydrogen and carbon dioxide and improved process efficiency of the hydrogen generation plant. | 05-17-2012 |
20120121497 | Process For Recovering Hydrogen And Carbon Dioxide - The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream ( | 05-17-2012 |
20120151962 | Ethylene Recovery From Off-Gas - A method for the recovery of ethylene from an off-gas is provided. This method includes providing an ethylene containing feed gas stream, introducing the ethylene containing gas stream into a first cryogenic separation device, thereby producing a first condensed stream and a first ethylene poor stream, and introducing the ethylene poor stream into a first feed compressor, thereby producing a pressurized first ethylene poor stream. This is repeated three times, resulting in a pressurized third ethylene poor stream, which is introduced into a pressure swing adsorber, thereby producing a high purity hydrogen stream and a PSA tail gas stream. The PSA tail gas stream is into a PSA tail gas compressor, thereby producing a pressurized PSA tail gas stream, which is then combined with an ethylene containing gas stream to produce the ethylene containing feed gas stream. The first condensed stream, the second condensed stream and the third condensed stream are combined to produce a combined condensed stream, which is introduced into an ethylene separation column thereby producing an ethylene rich stream and a methane rich stream. The methane rich stream is introduced into a methane compressor thereby producing a methane fuel stream. | 06-21-2012 |
20120157731 | Multistage Prereforming - A pre-reforming process is provided. This process includes heating a first stream containing heavy hydrocarbons to a first temperature, then introducing the heated first stream into a first pre-reforming chamber, thereby producing a first pre-reformed stream. This process also includes heating the first pre-reformed stream to a second temperature, then introducing the heated first pre-reformed stream into a second pre-reforming chamber, thereby producing a second pre-reformed stream. This process also includes heating the second pre-reformed stream to a third temperature, then introducing the heated second pre-reformed stream into a third pre-reforming chamber, thereby producing a third pre-reformed stream. | 06-21-2012 |
20120227583 | METHOD FOR PURIFYING A GAS FLOW IMPLEMENTING A CONTACTOR HAVING PARALLEL PASSAGES WHILE MAINTAINING THE PERFORMANCE THEREOF - The invention relates to a method for purifying a gas flow including at least a first compound selected from the compounds of a first group including water, ammonia, aromatics, alkane-, alkene-, or alkyne-type hydrocarbons containing at least 5 carbon atoms, aldehydes, ketones, halogen hydrocarbons, hydrogen sulfide, hydrogen chloride, and at least second and third compounds selected from the compounds of a second group including helium, hydrogen, nitrogen, oxygen, argon, carbon monoxide, carbon dioxide, hydrocarbons lower than C5, wherein said method comprises a variable-pressure adsorption implementing at least one main adsorber comprising at least one contactor having parallel passages, characterized in that said first compound is at least partially stopped upstream from said main adsorber. | 09-13-2012 |
20120291481 | Process For Recovering Hydrogen And Carbon Dioxide - The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized. | 11-22-2012 |
20120291482 | Process For Recovering Hydrogen And Carbon Dioxide - The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized. | 11-22-2012 |
20120291483 | Process For Recovering Hydrogen And Carbon Dioxide - The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized. | 11-22-2012 |
20120291484 | Process For The Production Of Hydrogen And Carbon Dioxide - This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized. | 11-22-2012 |
20120291485 | Process For The Production Of Hydrogen And Carbon Dioxide - This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized. | 11-22-2012 |
20120292574 | Process For The Production Of Hydrogen And Carbon Dioxide - This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized. | 11-22-2012 |
20130009099 | Process For The Production Of Hydrogen/Carbon Monoxide - The present invention provides for an energy efficient process of producing hydrogen/carbon monoxide gas mixtures from one or more hydrocarbon gas streams treated in a syngas producing unit by utilizing a carbon dioxide removal unit that contains sorbent beds in which a magnesium based sorbent is transported and cycled between different beds for sorption and desorption of carbon dioxide. The carbon dioxide recovered during the process is recovered at high temperature and high pressure therefore allowing for at least a portion of the carbon dioxide stream to be recycled for further treatment with little or no compression of the stream. | 01-10-2013 |
20130011323 | Process For The Production Of Hydrogen And Carbon Dioxide Utilizing Magnesium Based Sorbents In A Fixed Bed - The present invention relates to a process for recovering hydrogen along with high temperature high pressure carbon dioxide from one or more hydrocarbon gas streams by incorporating a carbon dioxide recovery unit which utilizes a magnesium based sorbent into a process that includes a reformer unit, a water gas shift reactor and a hydrogen pressure swing adsorption unit. | 01-10-2013 |
20130011324 | Process For The Production Of Hydrogen And Carbon Dioxide Utilizing Magnesium Based Sorbents In A Fluidized Bed - The present invention provides a process for recovering hydrogen and high pressure high purity carbon dioxide from one or more hydrocarbon feed streams utilizing a carbon dioxide removal unit that contains sorbent beds of a magnesium based sorbent in a fluidized form. | 01-10-2013 |
20130011325 | Process For The Production Of Hydrogen And Carbon Dioxide Utilizing Dry Magnesium Based Sorbents In A Fixed Bed - The present invention relates to a process for recovering hydrogen along with high temperature high pressure carbon dioxide from one or more hydrocarbon gas streams by incorporating a carbon dioxide recovery unit which utilizes a magnesium based sorbent into a process that includes a gasification unit, an optional sulfur removal unit, a water gas shift reactor and a hydrogen pressure swing adsorption unit. | 01-10-2013 |
20130011326 | Process For The Production Of Hydrogen And Carbon Dioxide Utilizing Magnesium Based Sorbents - The present invention relates to a process for recovering hydrogen along with high temperature high pressure carbon dioxide from one or more hydrocarbon gas streams by incorporating a carbon dioxide recovery unit which utilizes a fluidized magnesium based sorbent into a process that includes a gasification unit, an optional sulfur removal unit, a water gas shift reactor and a hydrogen pressure swing adsorption unit. | 01-10-2013 |
20130156685 | HYDROGEN PRODUCTION WITH REDUCED CARBON DIOXIDE GENERATION AND COMPLETE CAPTURE - The present invention is a method of reducing the carbon dioxide balance from a reformer furnace flue gas to the high pressure syngas exit water gas shift reaction unit. Introducing a heated gas mixture into at least one pre-reforming chamber. The heating being provided by indirect heat exchange with one or more of an SMR furnace flue gas or an SMR furnace syngas introducing the gas mixture into a standard H2 PSA unit, wherein the gas mixture is separated into a hydrogen enriched stream and a PSA tail gas stream; introducing the PSA tail gas stream into a CPU system, wherein the PSA tail gas stream is separated into a carbon dioxide enriched stream, a hydrogen rich stream, and a residual stream, and introducing the residual stream as fuel into the reformer furnace along with natural gas. | 06-20-2013 |
20130156686 | HYDROGEN PRODUCTION WITH REDUCED CARBON DIOXIDE GENERATION AND COMPLETE CAPTURE - The present invention is a method of minimizing the emissions of carbon dioxide from a reformer furnace flue gas to the high pressure syngas exit water gas shift reaction unit. Including heating a first gas mixture by indirect heat exchange with one or more of an SMR furnace flue gas or an SMR furnace syngas, further heating the pre-reformed mixture in a primary reformer, thereby generating a second gas mixture comprising hydrogen, carbon monoxide, carbon dioxide, and a flue gas. Introducing the gas mixture into a standard H2 PSA unit, wherein the gas is separated into a hydrogen enriched stream and a PSA tail gas stream, and introducing PSA feed or tail gas stream into a carbon dioxide removal system, wherein the flue gas is separated into a residual flue gas stream and a carbon dioxide enriched stream. | 06-20-2013 |
20130227961 | OXY-COMBUSTION TURBOEXPANDER SYSTEM - An integrated oxy-combustion turboexpander process including producing an enriched carbon dioxide product stream, by combusting a compressed synthetic air stream, including an oxygen-enriched stream and a carbon dioxide recycle stream, with a fuel stream and expanding the combustion stream thereby producing the carbon dioxide recycle stream and an enriched carbon dioxide product stream; producing an essentially pure carbon dioxide product stream, by processing the enriched carbon dioxide product stream into a deoxo methane combustor. | 09-05-2013 |
20130341839 | USE OF OXYGEN FROM ION TRANSPORT MEMBRANES IN BLAST FURNACE - The present invention is a method of integrating oxygen production with blast furnace operation. A heated air stream is introduced to an ion transfer membrane separator, producing a permeate and a retentate. The permeate and the motive stream are introduced into an ejector jet pump producing an oxygen enriched stream. The oxygen enriched stream is introduced into blast furnace. In another embodiment of the present invention, the permeate and a steam motive stream are introduced into an ejector jet pump. Heated air inlet stream is introduced into a cascading series of ion transfer membrane separators, producing a series of permeate streams and a series of retentate streams wherein each retentate stream acts as the input stream for the subsequent ion transfer membrane separator. Thereby producing a series of oxygen enriched streams which are combined and introduced into blast furnace. | 12-26-2013 |
20130344450 | SYNGAS GENERATOR FOR BLAST FURNACE - A method for producing a syngas stream for use in a blast furnace, including providing a hot air stream to an ion transport membrane, thereby producing a hot nitrogen rich stream and a hot oxygen rich stream, providing a methane stream to the ion transport membrane, wherein the methane reacts with the hot oxygen rich stream thereby producing a syngas containing stream, introducing the syngas containing stream into a CO2 removal unit, thereby producing a carbon dioxide rich stream, and a hydrogen rich stream, and introducing the hydrogen rich stream into a blast furnace, thereby replacing at least a portion of the natural gas fuel required therein. | 12-26-2013 |
20140167336 | INTEGRATION OF OXYGEN TRANSPORT MEMBRANE WITH COAL BASED DRI PROCESS - A process for the integration of oxygen transport membrane with a coal based DRI process is provided. The process includes introducing a heated, compressed air stream into an oxygen transport membrane separator, thereby producing a permeate stream and a retentate stream, introducing at least a portion of the retentate stream into a fired heater along with a combustion air stream, and introducing at least a portion of the permeate stream into a DRI shaft furnace. | 06-19-2014 |
20140170061 | STAGED MEMBRANE PROCESS FOR HIGH PRESSURE HYDROGEN PRODUCTION - “A hydrogen purification process is provided. This process includes separating hydrogen from a hydrogen containing stream in at least two sequential palladium membrane purification zones, wherein each purification zone has a permeate side, wherein the permeate side pressure of purification zones are not the same.” | 06-19-2014 |
20140171714 | PROCESS TO INCREASE HYDROGEN PRODUCTION WITHOUT LOSS OF STEAM PRODUCTION IN A STEAM METHANE REFORMER - A process for pre-reforming a hydrocarbon containing stream prior to admission into a steam methane reformer is provided. This process includes a system with two pre-reformer reactors in series, wherein an oxygen stream is combined with the partially reformed outlet stream of the first pre-reformer reactor, then the combined stream is introduced into the second pre-reformer reactor. | 06-19-2014 |
20140182336 | ION TRANSPORT MEMBRANES IN FLOAT GLASS MANUFACTURING - Ion transport membranes are integrated with a glass melting furnace and a float glass bath. Only feeds of air, steam and hydrocarbon are necessary for producing hot oxygen for the melting furnace and a mixture of nitrogen, carbon dioxide, and hydrogen for the float glass bath. | 07-03-2014 |