Patent application number | Description | Published |
20120142865 | NANOSTRUCTURED POLYMER MEMBRANES FOR SELECTIVE ALCOHOL TRANSPORT - The present invention relates to copolymer compositions for alcohol-selective membranes and methods of selectively separating an alcohol such as ethanol from an aqueous solution using such membranes. The copolymer compositions may be block copolymers of polystyrene-polybutadiene-polystyrene (hereafter “SBS”) having cylindrical morphologies; graft diblock copolymers synthesized by ring-opening metathesis polymerization of two cycloalkene monomers, wherein at least one of the cycloalkene monomers is substituted with one or more polydialkylsiloxane groups; or triblock copolymers comprising a middle block comprising a polymerized cycloalkene monomer and two end groups. The synthesized graft and triblock copolymer compositions may have a spherical, lamellar, cylindrical, double diamond, or gyroid morphologies. The copolymer compositions may contain a structural block that imparts essential mechanical properties to the membrane (e.g., polystyrene) and may also contain an alcohol transporting block (e.g., polydimethylsiloxane or polybutadiene). The copolymer compositions may have a domain spacing and a flux, where the flux increases as the domain spacing increases. The copolymer compositions may also have an alcohol separation factor that increases as the domain spacing increases. The separation method may be carried out using pervaporation or vapor permeation techniques. | 06-07-2012 |
20140045074 | SOLID LITHIUM ELECTROLYTE VIA ADDITION OF LITHIUM SALTS TO METAL-ORGANIC FRAMEWORKS - Various embodiments of the invention disclose that the uptake of LiO | 02-13-2014 |
20140364567 | STYRENE-SILOXANE TRIBLOCK COPOLYMERS AS MEMBRANES FOR SELECTIVE TRANSPORT OF ALCOHOLS AND OTHER ORGANIC COMPOUNDS IN AQUEOUS MIXTURES - The present disclosure relates to high molecular weight polystyrene-polydialkylsiloxane-polystyrene (“SDS”) triblock copolymer compositions and methods of separating one or more organic compounds from an aqueous solution using membranes derived from SDS triblock copolymers. The methods may be used to separate the one or more organic compounds from an aqueous solution produced in a fermentation process. In some embodiments, the one or more organic compounds include an alcohol, such as, for example, ethanol. In other embodiments, the one or more organic compounds include acetone. In other embodiments, the one or more organic compounds include acetone, ethanol, and n-butanol produced in an acetone-ethanol-n-butanol (ABE) fermentation process. In other embodiments, the one or more organic compounds include one or more byproducts produced in a fermentation process. | 12-11-2014 |
Patent application number | Description | Published |
20090075176 | Solid Electrolyte Material Manufacturable by Polymer Processing Methods - The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that is ionically conductive, mechanically robust, and can be formed into desirable shapes using conventional polymer processing methods. An exemplary polymer electrolyte material has an elastic modulus in excess of 1×10 | 03-19-2009 |
20090104523 | High elastic modulus polymer electrolytes suitable for preventing thermal runaway in lithium batteries - A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1×10 | 04-23-2009 |
20090263725 | High Elastic Modulus Polymer Electrolytes - A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1×10 | 10-22-2009 |
20110003211 | ELECTRODES WITH SOLID POLYMER ELECTROLYTES - An electrode assembly that includes an electrode film and a current collector is provided. The electrode film includes electrode active material, electronically conductive particles, and a solid polymer electrolyte. In some embodiments, no additional binder is used as the solid polymer electrolyte also acts as a binder to hold together the active material and electronically conductive particles, thus creating a freestanding electrode film. Such a freestanding film makes it possible to deposit a very thin current collector layer, thus increasing specific energy and specific power for electrochemical cells in which these electrode assemblies are used. | 01-06-2011 |
20110033755 | PROTECTED LITHIUM METAL ELECTRODES FOR RECHARGEABLE BATTERIES - It has long been recognized that replacing the Li intercalated graphitic anode with a lithium foil can dramatically improve energy density due to the dramatically higher capacity of metallic lithium. However, lithium foil is not electrochemically stable in the presence of typical lithium ion battery electrolytes and thus a simple replacement of graphitic anodes with lithium foils is not possible. It was found that diblock or triblock polymers that provide both ionic conduction and structural support can be used as a stable passivating layer on a lithium foil. This passivation scheme results in improved manufacture processing for batteries that use Li electrodes and in improved safety for lithium batteries during use. | 02-10-2011 |
20110053043 | NANOSTRUCTURED POLYMER MEMBRANES FOR PROTON CONDUCTION - Polymers having an improved ability to entrain water are characterized, in some embodiments, by unusual humidity-induced phase transitions. The described polymers (e.g., hydrophilically functionalized block copolymers) have a disordered state and one or more ordered states (e.g., a lamellar state, a gyroid state, etc.). In one aspect, the polymers are capable of under-going a disorder-to-order transition while the polymer is exposed to an increasing temperature at a constant relative humidity. In some aspects the polymer includes a plurality of portions, wherein a first portion forms proton-conductive channels within the membrane and wherein the channels have a width of less than about 6 nm. The described polymers are capable of entraining and preserving water at high temperature and low humidity. Surprisingly, in some embodiments, the polymers are capable of entraining greater amounts of water with the increase of temperature. The polymers can be used in Polymer Electrolyte Membranes in fuel cells. | 03-03-2011 |
20110281173 | MULTIPLE ELECTROLYTE ELECTROCHEMICAL CELLS - Electrode assemblies for use in electrochemical cells are provided. The negative electrode assembly comprises negative electrode active material and an electrolyte chosen specifically for its useful properties in the negative electrode. These properties include reductive stability and ability to accommodate expansion and contraction of the negative electrode active material. Similarly, the positive electrode assembly comprises positive electrode active material and an electrolyte chosen specifically for its useful properties in the positive electrode. These properties include oxidative stability and the ability to prevent dissolution of transition metals used in the positive electrode active material. A third electrolyte can be used as separator between the negative electrode and the positive electrode. | 11-17-2011 |
20120264880 | Block Copolymer with Simultaneous Electric and Ionic Conduction for Use in Lithium ION Batteries - Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction, A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO | 10-18-2012 |
20130130069 | HIGH ELASTIC MODULUS POLYMER ELECTROLYTES SUITABLE FOR PREVENTING THERMAL RUNAWAY IN LITHIUM BATTERIES - A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1×10 | 05-23-2013 |
20140212766 | BLOCK COPOLYMER BATTERY SEPARATOR - The invention herein described is the use of a block copolymer/homopolymer blend for creating nanoporous materials for transport applications. Specifically, this is demonstrated by using the block copolymer poly(styrene-block-ethylene-block-styrene) (SES) and blending it with homopolymer polystyrene (PS). After blending the polymers, a film is cast, and the film is submerged in tetrahydrofuran, which removes the PS. This creates a nanoporous polymer film, whereby the holes are lined with PS. Control of morphology of the system is achieved by manipulating the amount of PS added and the relative size of the PS added. The porous nature of these films was demonstrated by measuring the ionic conductivity in a traditional battery electrolyte, 1M LiPF | 07-31-2014 |
Patent application number | Description | Published |
20100144333 | SYSTEM, METHOD AND APPARATUS FOR PROVIDING COMMUNICATIONS THAT CONFORM TO A CELLULAR COMMUNICATION STANDARD AND A NON-CELLULAR COMMUNICATION STANDARD - The present invention provides a software defined radio transceiver that includes a programmable cellular radio front end and a programmable baseband processor. The programmable cellular radio front end is typically a digital radio frequency processor configured to support a cellular communication standard. The programmable baseband processor is connected to the digital radio frequency processor. The programmable baseband processor (a) selectively reconfigures the cellular configured digital radio frequency processor to support a non-cellular communication standard by bypassing one or more cellular communication standard specific function, and modifying one or more operating parameters to conform to the non-cellular communication standard, (b) processes input data in accordance with the non-cellular communication standard and provides the processed input data to the digital radio frequency processor for transmission, and (c) receives output data from the digital radio frequency processor and processes the received output data to obtain transmitted data. | 06-10-2010 |
20120139509 | System, apparatus and methods for controlling multiple output converters - An apparatus and method is presented for implementing and controlling a voltage converter with one input voltage and multiple output voltages. In the case of boost and buck-boost converters, a converter circuit with one inductor and a switched group of parallel connection capacitors is realized, one parallel connection for each output voltage. A duty ratio is monitored for the inductor and the switched group of capacitors to provide a set of duty ratios. The duty ratios form a control vector which describes the control inputs. The output voltages are the control outputs describing a MIMO system. A generalized Cuk-Middlebrook modeling approach is applied to the voltage converter, along with linearization and MIMO control methods to regulate all output voltages to desired levels. | 06-07-2012 |
20140361754 | ANALOG INPUT OUTPUT LINEARIZATION CONTROL - A voltage converter for converting an input voltage to an output voltage is disclosed. The voltage converter includes a voltage converter circuit having a set of switches, a switch driver connected to the voltage converter circuit, a controller connected to the switch driver and the output voltage, a target output voltage connected to the controller, a control signal generated by the controller for the switch driver that includes a duty ratio based on the target output voltage and the output voltage. The switch driver is configured to apply the control signal to the set of switches and the voltage converter circuit generates the output voltage based on the duty ratio to match the target output voltage. | 12-11-2014 |