Patent application number | Description | Published |
20090123810 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and fuel cell systems, methods of using same, and methods of making same are provided. In certain embodiments, the fuel cell devices may include one or more active layers containing active cells that are connected electrically in parallel and/or series. In certain embodiments, the fuel cell devices include an elongate ceramic support structure the length of which is the greatest dimension such that the coefficient of thermal expansion has only one dominant axis coextensive with the length. In certain embodiments, a reaction zone is positioned along a first portion of the length for heating to a reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating below the reaction temperature. There are one or more gas passages, each having an associated anode or cathode. In some embodiments, ceramic end tubes are permanently attached to the ceramic support structure to supply gases to the passages. In certain embodiments, a multilayer active structure is attached upon a flat tube having a plurality of channels therein for feeding gases into the passages of the multilayer active structure. In other embodiments, multilayer active structures are provided in which the electrodes contain pluralities of microtubular or nanotubular passages for feeding gases thereto. In yet other embodiments, the multilayer active structure is contained within a ceramic support structure that includes two elongate members that extend outwardly from one edge for feeding gases into the multilayer active structure. | 05-14-2009 |
20090226781 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness. A reaction zone positioned along a portion of the length is configured to be heated to an operating reaction temperature, and has at least one active layer therein comprising an electrolyte separating first and second opposing electrodes, and active first and second gas passages adjacent the respective first and second electrodes. At least one cold zone positioned from the first end along another portion of the length is configured to remain below the operating reaction temperature. An artery flow passage extends from the first end along the length through the cold zone and into the reaction zone and is fluidicly coupled to the active first gas passage, which extends from the artery flow passage toward at least one side. The thickness of the artery flow passage is greater than the thickness of the active first gas passage. In other embodiments, fuel cell devices include an electrolyte having at least a portion thereof comprising a ceramic material sintered from a nano-sized powder. In yet other embodiments, cold zones are provided at each end of the device with the reaction zone therebetween having at least two discrete power sections, each having one or more active layers, the power sections fed by discrete fuel passages to provide a device and system capable of operating at more than one power level. | 09-10-2009 |
20090324999 | FUEL CELL DEVICE AND SYSTEM - The present invention relates to fuel cell devices and fuel cell systems, methods of using fuel cell devices and systems, and methods of making fuel cell devices. According to certain embodiments, the fuel cell devices may include an elongate substrate, such as a rectangular or tubular substrate, the length of which is the greatest dimension such that the coefficient of thermal expansion has only one dominant axis that is coextensive with the length. In addition, or in accordance with other certain embodiments, a reaction zone is positioned along a first portion of the length for heating to an operating reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating at a temperature below the operating reaction temperature. There are one or more fuel passages in the elongate substrate, each having an associate anode, and one or more oxidizer passages in the elongate substrate, each having an associate cathode. In some embodiments, the passages are formed by sacrificial organic materials that are melted or baked out of the structure and/or by removable structures that are pulled out after lamination. Bake-out paths may also be used to facilitate removal of the sacrificial organic materials, which paths are later sealed. Embodiments of the invention further include methods and devices in which a current collector is recessed into the electrode. | 12-31-2009 |
20100053842 | STACKED MULTILAYER CAPACITOR - A capacitor device mountable on a plane of a substrate includes an electrically conductive bottom plate adapted to be mounted substantially parallel to, and in electrical contact at the plane of the substrate and a first multilayer capacitor having substantially parallel first and second electrode plates oriented substantially perpendicular to the bottom plate with the first electrode plates being electrically connected to the bottom plate. An electrically conductive top lead frame overlaps with, and is electrically isolated from, the bottom plate. The top lead frame electrically connected to the second electrode plates and adapted to be electrically connected at the plane of the substrate. The bottom lead frame may have a corrugated shape, where the corrugated shape provides compliance between the first multilayer capacitor and the substrate. A portion of the top lead frame may contact at least a portion of a side of the first multilayer capacitor. | 03-04-2010 |
20100104910 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness with the length direction being the dominant direction of thermal expansion. A reaction zone having at least one active layer therein is spaced from the first end and includes first and second opposing electrodes, associated active first and second gas passages, and electrolyte. The active first gas passage includes sub-passages extending in the y direction and spaced apart in the x direction. An artery flow passage extends from the first end along the length and into the reaction zone and is fluidicly coupled to the sub-passages of the active first gas passage. The thickness of the artery flow passage is greater than the thickness of the sub-passages. In other embodiments, fuel cell devices include second sub-passages for the active second gas passage and a second artery flow passage coupled thereto, and extending from either the first end or the second end into the reaction zone. In yet other embodiments, one or both electrodes of a fuel cell device are segmented. | 04-29-2010 |
20110117471 | FUEL CELL DEVICE - A fuel cell device is provided in which the gas input passages are separate from the exhaust gas passages to provide better flow of reactants through the pores of the electrodes. First and second porous electrodes are separated by an electrolyte layer that is monolithic with a solid ceramic support structure for the device. First and second input passages extend within the respective electrodes, within the electrolyte layer, and/or at the surfaces that form the interface between the respective electrodes and the electrolyte layer. First and second exhaust passages are spaced apart from the input passages, and extend within the respective electrodes and/or at a surface thereof opposite the interface surface with the electrolyte layer. Gases are adapted to flow through the respective input passages, then through the pores of the porous electrodes, and then through the respective exhaust passages. | 05-19-2011 |
20110272081 | METHOD OF MAKING A FUEL CELL DEVICE - A method of making a fuel cell device comprises forming a green stacked structure to provide an internal active section of intervening green layers of ceramic material separating anode layers from cathode layers and sacrificial layers of organic material adjacent each of the anode and cathode layers opposite the intervening green layers, and a non-active section of the green layers substantially surrounding the active section. The sacrificial layers are sized to provide internal gas passages in the active section for feeding gases to the internal anodes and cathodes, and the sacrificial layers are coupled to edges of the structure to couple each of the internal gas passages to an inlet and an outlet of the device. The green stacked structure is heated to bake out the organic material to form the passages and to sinter together the green layers in the active and non-active sections. | 11-10-2011 |
20120003556 | FUEL CELL DEVICE AND SYSTEM - The invention relates to fuel cell devices and systems, and methods of using and making fuel cell devices and systems. The fuel cell devices include an elongate ceramic substrate, such as a rectangular or tubular substrate, the length of which is the greatest dimension such that thermal expansion is exhibited along a dominant axis that is coextensive with the length. A reaction zone is positioned along a first portion of the length for heating to an operating reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating at a temperature below the operating reaction temperature. There are one or more fuel passages and one or more oxidizer passages extending within an interior solid support structure of the elongate substrate, each having an associated anode and cathode, respectively, which are separated by an electrolyte. The passages include a neck-down point. | 01-05-2012 |
20120003558 | FUEL CELL DEVICE AND SYSTEM - The present invention relates to a fuel cell system. A hot zone chamber has a wall thickness T and a heat source coupled thereto. An elongate fuel cell device is positioned with a first lengthwise portion within the hot zone chamber, a second lengthwise portion outside the hot zone chamber, and a third lengthwise portion of length T within the chamber wall. The third portion has a maximum dimension L in a plane transverse to the length where T≧½ L. | 01-05-2012 |
20120003570 | METHOD OF MAKING A FUEL CELL DEVICE - The present invention relates to a method of making fuel cell devices. A stack structure is formed having plural ceramic layers, anode layers, cathode layers, and sacrificial layers, where the sacrificial layers are sized to provide internal gas passages. Removable structures are placed in contact with the sacrificial layers and extend to an edge. After laminating the stacked structure, the removable structures are pulled out to form bake-out paths that facilitate removal of the sacrificial material during a heating step, which paths are later sealed. | 01-05-2012 |
20120003571 | METHOD OF MAKING A FUEL CELL DEVICE - The invention relates to a method of making fuel cell devices. Anode and cathode layers are applied on respective first and opposing second sides of a first portion of a first green ceramic layer, and a second green ceramic layer of thickness approximately equal to that of the anode and cathode layers is applied on a second portion of each of the first and second sides of the first green ceramic layer. A sacrificial layer is applied over each of the anode, cathode and second green ceramic layers, and a third green ceramic layer is applied over the sacrificial layers. The layered structure is heated to sinter all the layers and burn out the sacrificial layers. A pair of gas passages is thus formed with a thick sintered ceramic therebetween as a passive supporting portion and an anode, thin electrolyte and cathode therebetween as an active portion of the device. | 01-05-2012 |
20120196200 | SOLID OXIDE FUEL CELL DEVICE - A fuel cell device including an elongate ceramic substrate having an exterior surface defining an interior ceramic support structure having non-active end regions and an active zone therebetween that includes electrodes in opposing relation with an electrolyte therebetween for undergoing a fuel cell reaction when supplied with heat, fuel and oxidizer. The electrolyte is a ceramic co-fired with the interior ceramic support structure. The end regions lack opposing electrodes and extend away from the active zone to dissipate heat. Gas inlets are positioned in the end regions with respective outlets in either the active zone or opposite end region, and elongate passages are coupled therebetween at least partially extending in opposing relation through the active zone. The electrodes are positioned adjacent the gas passages in the active zone and are electrically connected to exterior contact surfaces on the exterior surface of the end regions for external connection to voltage nodes. | 08-02-2012 |
20120288779 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and fuel cell systems are provided. In certain embodiments, the fuel cell devices may include one or more active layers containing active cells that are connected electrically in series. In certain embodiments, the fuel cell devices include an elongate ceramic support structure the length of which is the greatest dimension such that the coefficient of thermal expansion has only one dominant axis coextensive with the length. In certain embodiments, a reaction zone is positioned along a first portion of the length for heating to a reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating below the reaction temperature. There are one or more gas passages, each having an associated anode or cathode. | 11-15-2012 |
20130017466 | SOLID OXIDE FUEL CELL DEVICE AND SYSTEM - The invention provides tubular solid oxide fuel cell devices and a fuel cell system incorporating a plurality of the fuel devices, each device including an elongate tube having a reaction zone for heating to an operating reaction temperature, and at least one cold zone that remains at a low temperature below the operating reaction temperature when the reaction zone is heated. An electrolyte is disposed between anodes and cathodes in the reaction zone, and the anode and cathode each have an electrical pathway extending to an exterior surface in a cold zone for electrical connection at low temperature. In one embodiment, the tubular device is a spiral rolled structure, and in another embodiment, the tubular device is a concentrically arranged device. The system further includes the devices positioned with their reaction zones in a hot zone chamber and their cold zones extending outside the hot zone chamber. A heat source is coupled to the hot zone chamber to heat the reaction zones to the operating reaction temperature, and fuel and air supplies are coupled to the tubes in the cold zones. | 01-17-2013 |
20130045433 | SOLID OXIDE FUEL CELL DEVICE - A fuel cell device including an elongate ceramic substrate having an exterior surface defining an interior ceramic support structure and having a length that is at least 5 times greater than the width and the thickness so as to exhibit thermal expansion along a dominant axis coextensive with the length. The substrate has an active zone and at least one non-active end region. The active zone has an anode and a cathode in opposing relation with an electrolyte therebetween and the non-active end region lacks the anode and cathode in opposing relation and extends away from the active zone to dissipate heat. The electrolyte, anode and cathode extend within the interior ceramic support structure, the anode and cathode each have an electrical pathway extending from within the interior ceramic support structure to the exterior surface in the non-active end region, and the electrolyte is a ceramic co-fired with the interior ceramic support structure. | 02-21-2013 |
20130063858 | NANOSTRUCTURED DIELECTRIC MATERIALS FOR HIGH ENERGY DENSITY MULTILAYER CERAMIC CAPACITORS - A multilayer ceramic capacitor, having a plurality of electrode layers and a plurality of substantially titanium dioxide dielectric layers, wherein each respective titanium dioxide dielectric layer is substantially free of porosity, wherein each respective substantially titanium dioxide dielectric layer is positioned between two respective electrode layers, wherein each respective substantially titanium dioxide dielectric layer has an average grain size of between about 200 and about 400 nanometers, wherein each respective substantially titanium dioxide dielectric layer has maximum particle size of less than about 500 nanometers. Typically, each respective substantially titanium dioxide dielectric layer further includes at least one dopant selected from the group including P, V, Nb, Ta, Mo, W, and combinations thereof, and the included dopant is typically present in amounts of less than about 0.01 atomic percent. | 03-14-2013 |
20130130149 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness. A reaction zone positioned along a portion of the length is configured to be heated to an operating reaction temperature, and has at least one active layer therein comprising an electrolyte separating first and second opposing electrodes, and active first and second gas passages adjacent the respective first and second electrodes. At least one cold zone positioned from the first end along another portion of the length is configured to remain below the operating reaction temperature. An artery flow passage extends from the first end along the length through the cold zone and into the reaction zone and is fluidicly coupled to the active first gas passage, which extends from the artery flow passage toward at least one side. The thickness of the artery flow passage is greater than the thickness of the active first gas passage. In other embodiments, fuel cell devices include an electrolyte having at least a portion thereof comprising a ceramic material sintered from a nano-sized powder. In yet other embodiments, cold zones are provided at each end of the device with the reaction zone therebetween having at least two discrete power sections, each having one or more active layers, the power sections fed by discrete fuel passages to provide a device and system capable of operating at more than one power level. | 05-23-2013 |
20130136953 | FUEL CELL DEVICE - Fuel cell devices are provided having improved shrinkage properties between the active and non-active structures by modifying the material composition of the non-active structure, having a non-conductive, insulating barrier layer between the active structure and surface conductors that extend over the inactive surrounding support structure, having the width of one or both electrodes progressively change along the length, or having a porous ceramic layer between the anode and fuel passage and between the cathode and air passage. Another fuel cell device is provided having an internal multilayer active structure with electrodes alternating in polarity from top to bottom and external conductors on the top and/or bottom surface with sympathetic polarity to the respective top and bottom electrodes. A fuel cell system is provided with a fuel cell device having an enlarged attachment surface at one or both ends, which resides outside the system's heat source, insulated therefrom. | 05-30-2013 |
20130252126 | FUEL CELL DEVICE AND SYSTEM - The present invention relates to a fuel cell system. A hot zone chamber has a wall thickness T and a heat source coupled thereto. An elongate fuel cell device is positioned with a first lengthwise portion within the hot zone chamber, a second lengthwise portion outside the hot zone chamber, and a third lengthwise portion of length T within the chamber wall. The third portion has a maximum dimension L in a plane transverse to the length where T≧½L. | 09-26-2013 |
20130273462 | METHOD OF MAKING A FUEL CELL DEVICE - A monolithic fuel cell device is provided by forming anode and cathode layers by dispensing paste of anode or cathode material around pluralities of spaced-apart removable physical structures to at least partially surround the structures with the anode or cathode material and then drying the paste. An electrolyte layer is provided in a multi-layer stack between the cathode layer and the anode layer thereby forming an active cell portion. The multi-layer stack is laminated, and then the physical structures are pulled out to reveal spaced-apart active passages formed through each of the anode layer and cathode layer. Finally, the laminated stack is sintered to form an active cell comprising the spaced apart active passages embedded in and supported by the sintered anode material and sintered cathode material. | 10-17-2013 |
20140065504 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness with the length direction being the dominant direction of thermal expansion. A reaction zone having at least one active layer therein is spaced from the first end and includes first and second opposing electrodes, associated active first and second gas passages, and electrolyte. The active first gas passage includes sub-passages extending in the y direction and spaced apart in the x direction. An artery flow passage extends from the first end along the length and into the reaction zone and is fluidicly coupled to the sub-passages of the active first gas passage. The thickness of the artery flow passage is greater than the thickness of the sub-passages. In other embodiments, fuel cell devices include second sub-passages for the active second gas passage and a second artery flow passage coupled thereto, and extending from either the first end or the second end into the reaction zone. In yet other embodiments, one or both electrodes of a fuel cell device are segmented. | 03-06-2014 |
20140106252 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and fuel cell systems are provided. The fuel cell devices may include one or more active layers containing active cells that are connected electrically in series. The active cells include anodes and cathodes spaced apart along the length, with each including a porous portion and a non-porous conductor portion. The active cells reside between opposing porous anode and cathode portions. The electrical series connections between active cells are made between the non-porous conductor portions. In certain embodiments, the electrical series connections are made by direct contact between the non-porous conductor portions. In certain embodiments, the electrical series connections are made by non-porous conductive vias or elements that extend through an intervening support structure that separates the non-porous anode conductor portions from the non-porous cathode conductor portions. | 04-17-2014 |
20140141349 | SOLID OXIDE FUEL CELL DEVICE - A fuel cell device having an exterior surface defining an interior ceramic support structure. An active zone is along an intermediate portion of the length for undergoing a fuel cell reaction, and opposing non-active end regions are along end portions extending away from the active zone without being heated. Fuel and oxidizer passages extend within the interior support structure from respective first and second inlets in respective ones of the opposing non-active end regions. The active zone has an anode associated with each of the fuel passages and a cathode associated with each of the oxidizer passages in opposing relation to a respective one of the anodes with an electrolyte therebetween. The opposing non-active end regions lack the anode and cathode in opposing relation so as to be incapable of undergoing a fuel cell reaction. | 05-22-2014 |
20140295319 | FUEL CELL DEVICE AND SYSTEM - A fuel cell device is provided having an active central portion with an anode, a cathode, and an electrolyte therebetween. At least three elongate portions extend from the active central portion, each having a length substantially greater than a width transverse thereto such that the elongate portions each have a coefficient of thermal expansion having a dominant axis that is coextensive with its length. A fuel passage extends from a fuel inlet in a first elongate portion into the active central portion in association with the anode, and an oxidizer passage extends from an oxidizer inlet in a second elongate portion into the active central portion in association with the cathode. A gas passage extends between an opening in the third elongate portion and the active central portion. For example, the passage in the third elongate portion may be an exhaust passage for the spent fuel and/or oxidizer gasses. | 10-02-2014 |
Patent application number | Description | Published |
20090123810 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and fuel cell systems, methods of using same, and methods of making same are provided. In certain embodiments, the fuel cell devices may include one or more active layers containing active cells that are connected electrically in parallel and/or series. In certain embodiments, the fuel cell devices include an elongate ceramic support structure the length of which is the greatest dimension such that the coefficient of thermal expansion has only one dominant axis coextensive with the length. In certain embodiments, a reaction zone is positioned along a first portion of the length for heating to a reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating below the reaction temperature. There are one or more gas passages, each having an associated anode or cathode. In some embodiments, ceramic end tubes are permanently attached to the ceramic support structure to supply gases to the passages. In certain embodiments, a multilayer active structure is attached upon a flat tube having a plurality of channels therein for feeding gases into the passages of the multilayer active structure. In other embodiments, multilayer active structures are provided in which the electrodes contain pluralities of microtubular or nanotubular passages for feeding gases thereto. In yet other embodiments, the multilayer active structure is contained within a ceramic support structure that includes two elongate members that extend outwardly from one edge for feeding gases into the multilayer active structure. | 05-14-2009 |
20090226781 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness. A reaction zone positioned along a portion of the length is configured to be heated to an operating reaction temperature, and has at least one active layer therein comprising an electrolyte separating first and second opposing electrodes, and active first and second gas passages adjacent the respective first and second electrodes. At least one cold zone positioned from the first end along another portion of the length is configured to remain below the operating reaction temperature. An artery flow passage extends from the first end along the length through the cold zone and into the reaction zone and is fluidicly coupled to the active first gas passage, which extends from the artery flow passage toward at least one side. The thickness of the artery flow passage is greater than the thickness of the active first gas passage. In other embodiments, fuel cell devices include an electrolyte having at least a portion thereof comprising a ceramic material sintered from a nano-sized powder. In yet other embodiments, cold zones are provided at each end of the device with the reaction zone therebetween having at least two discrete power sections, each having one or more active layers, the power sections fed by discrete fuel passages to provide a device and system capable of operating at more than one power level. | 09-10-2009 |
20090324999 | FUEL CELL DEVICE AND SYSTEM - The present invention relates to fuel cell devices and fuel cell systems, methods of using fuel cell devices and systems, and methods of making fuel cell devices. According to certain embodiments, the fuel cell devices may include an elongate substrate, such as a rectangular or tubular substrate, the length of which is the greatest dimension such that the coefficient of thermal expansion has only one dominant axis that is coextensive with the length. In addition, or in accordance with other certain embodiments, a reaction zone is positioned along a first portion of the length for heating to an operating reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating at a temperature below the operating reaction temperature. There are one or more fuel passages in the elongate substrate, each having an associate anode, and one or more oxidizer passages in the elongate substrate, each having an associate cathode. In some embodiments, the passages are formed by sacrificial organic materials that are melted or baked out of the structure and/or by removable structures that are pulled out after lamination. Bake-out paths may also be used to facilitate removal of the sacrificial organic materials, which paths are later sealed. Embodiments of the invention further include methods and devices in which a current collector is recessed into the electrode. | 12-31-2009 |
20100053842 | STACKED MULTILAYER CAPACITOR - A capacitor device mountable on a plane of a substrate includes an electrically conductive bottom plate adapted to be mounted substantially parallel to, and in electrical contact at the plane of the substrate and a first multilayer capacitor having substantially parallel first and second electrode plates oriented substantially perpendicular to the bottom plate with the first electrode plates being electrically connected to the bottom plate. An electrically conductive top lead frame overlaps with, and is electrically isolated from, the bottom plate. The top lead frame electrically connected to the second electrode plates and adapted to be electrically connected at the plane of the substrate. The bottom lead frame may have a corrugated shape, where the corrugated shape provides compliance between the first multilayer capacitor and the substrate. A portion of the top lead frame may contact at least a portion of a side of the first multilayer capacitor. | 03-04-2010 |
20100104910 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness with the length direction being the dominant direction of thermal expansion. A reaction zone having at least one active layer therein is spaced from the first end and includes first and second opposing electrodes, associated active first and second gas passages, and electrolyte. The active first gas passage includes sub-passages extending in the y direction and spaced apart in the x direction. An artery flow passage extends from the first end along the length and into the reaction zone and is fluidicly coupled to the sub-passages of the active first gas passage. The thickness of the artery flow passage is greater than the thickness of the sub-passages. In other embodiments, fuel cell devices include second sub-passages for the active second gas passage and a second artery flow passage coupled thereto, and extending from either the first end or the second end into the reaction zone. In yet other embodiments, one or both electrodes of a fuel cell device are segmented. | 04-29-2010 |
20110117471 | FUEL CELL DEVICE - A fuel cell device is provided in which the gas input passages are separate from the exhaust gas passages to provide better flow of reactants through the pores of the electrodes. First and second porous electrodes are separated by an electrolyte layer that is monolithic with a solid ceramic support structure for the device. First and second input passages extend within the respective electrodes, within the electrolyte layer, and/or at the surfaces that form the interface between the respective electrodes and the electrolyte layer. First and second exhaust passages are spaced apart from the input passages, and extend within the respective electrodes and/or at a surface thereof opposite the interface surface with the electrolyte layer. Gases are adapted to flow through the respective input passages, then through the pores of the porous electrodes, and then through the respective exhaust passages. | 05-19-2011 |
20110272081 | METHOD OF MAKING A FUEL CELL DEVICE - A method of making a fuel cell device comprises forming a green stacked structure to provide an internal active section of intervening green layers of ceramic material separating anode layers from cathode layers and sacrificial layers of organic material adjacent each of the anode and cathode layers opposite the intervening green layers, and a non-active section of the green layers substantially surrounding the active section. The sacrificial layers are sized to provide internal gas passages in the active section for feeding gases to the internal anodes and cathodes, and the sacrificial layers are coupled to edges of the structure to couple each of the internal gas passages to an inlet and an outlet of the device. The green stacked structure is heated to bake out the organic material to form the passages and to sinter together the green layers in the active and non-active sections. | 11-10-2011 |
20120003556 | FUEL CELL DEVICE AND SYSTEM - The invention relates to fuel cell devices and systems, and methods of using and making fuel cell devices and systems. The fuel cell devices include an elongate ceramic substrate, such as a rectangular or tubular substrate, the length of which is the greatest dimension such that thermal expansion is exhibited along a dominant axis that is coextensive with the length. A reaction zone is positioned along a first portion of the length for heating to an operating reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating at a temperature below the operating reaction temperature. There are one or more fuel passages and one or more oxidizer passages extending within an interior solid support structure of the elongate substrate, each having an associated anode and cathode, respectively, which are separated by an electrolyte. The passages include a neck-down point. | 01-05-2012 |
20120003558 | FUEL CELL DEVICE AND SYSTEM - The present invention relates to a fuel cell system. A hot zone chamber has a wall thickness T and a heat source coupled thereto. An elongate fuel cell device is positioned with a first lengthwise portion within the hot zone chamber, a second lengthwise portion outside the hot zone chamber, and a third lengthwise portion of length T within the chamber wall. The third portion has a maximum dimension L in a plane transverse to the length where T≧½ L. | 01-05-2012 |
20120003570 | METHOD OF MAKING A FUEL CELL DEVICE - The present invention relates to a method of making fuel cell devices. A stack structure is formed having plural ceramic layers, anode layers, cathode layers, and sacrificial layers, where the sacrificial layers are sized to provide internal gas passages. Removable structures are placed in contact with the sacrificial layers and extend to an edge. After laminating the stacked structure, the removable structures are pulled out to form bake-out paths that facilitate removal of the sacrificial material during a heating step, which paths are later sealed. | 01-05-2012 |
20120003571 | METHOD OF MAKING A FUEL CELL DEVICE - The invention relates to a method of making fuel cell devices. Anode and cathode layers are applied on respective first and opposing second sides of a first portion of a first green ceramic layer, and a second green ceramic layer of thickness approximately equal to that of the anode and cathode layers is applied on a second portion of each of the first and second sides of the first green ceramic layer. A sacrificial layer is applied over each of the anode, cathode and second green ceramic layers, and a third green ceramic layer is applied over the sacrificial layers. The layered structure is heated to sinter all the layers and burn out the sacrificial layers. A pair of gas passages is thus formed with a thick sintered ceramic therebetween as a passive supporting portion and an anode, thin electrolyte and cathode therebetween as an active portion of the device. | 01-05-2012 |
20120196200 | SOLID OXIDE FUEL CELL DEVICE - A fuel cell device including an elongate ceramic substrate having an exterior surface defining an interior ceramic support structure having non-active end regions and an active zone therebetween that includes electrodes in opposing relation with an electrolyte therebetween for undergoing a fuel cell reaction when supplied with heat, fuel and oxidizer. The electrolyte is a ceramic co-fired with the interior ceramic support structure. The end regions lack opposing electrodes and extend away from the active zone to dissipate heat. Gas inlets are positioned in the end regions with respective outlets in either the active zone or opposite end region, and elongate passages are coupled therebetween at least partially extending in opposing relation through the active zone. The electrodes are positioned adjacent the gas passages in the active zone and are electrically connected to exterior contact surfaces on the exterior surface of the end regions for external connection to voltage nodes. | 08-02-2012 |
20120288779 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and fuel cell systems are provided. In certain embodiments, the fuel cell devices may include one or more active layers containing active cells that are connected electrically in series. In certain embodiments, the fuel cell devices include an elongate ceramic support structure the length of which is the greatest dimension such that the coefficient of thermal expansion has only one dominant axis coextensive with the length. In certain embodiments, a reaction zone is positioned along a first portion of the length for heating to a reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating below the reaction temperature. There are one or more gas passages, each having an associated anode or cathode. | 11-15-2012 |
20130017466 | SOLID OXIDE FUEL CELL DEVICE AND SYSTEM - The invention provides tubular solid oxide fuel cell devices and a fuel cell system incorporating a plurality of the fuel devices, each device including an elongate tube having a reaction zone for heating to an operating reaction temperature, and at least one cold zone that remains at a low temperature below the operating reaction temperature when the reaction zone is heated. An electrolyte is disposed between anodes and cathodes in the reaction zone, and the anode and cathode each have an electrical pathway extending to an exterior surface in a cold zone for electrical connection at low temperature. In one embodiment, the tubular device is a spiral rolled structure, and in another embodiment, the tubular device is a concentrically arranged device. The system further includes the devices positioned with their reaction zones in a hot zone chamber and their cold zones extending outside the hot zone chamber. A heat source is coupled to the hot zone chamber to heat the reaction zones to the operating reaction temperature, and fuel and air supplies are coupled to the tubes in the cold zones. | 01-17-2013 |
20130045433 | SOLID OXIDE FUEL CELL DEVICE - A fuel cell device including an elongate ceramic substrate having an exterior surface defining an interior ceramic support structure and having a length that is at least 5 times greater than the width and the thickness so as to exhibit thermal expansion along a dominant axis coextensive with the length. The substrate has an active zone and at least one non-active end region. The active zone has an anode and a cathode in opposing relation with an electrolyte therebetween and the non-active end region lacks the anode and cathode in opposing relation and extends away from the active zone to dissipate heat. The electrolyte, anode and cathode extend within the interior ceramic support structure, the anode and cathode each have an electrical pathway extending from within the interior ceramic support structure to the exterior surface in the non-active end region, and the electrolyte is a ceramic co-fired with the interior ceramic support structure. | 02-21-2013 |
20130130149 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness. A reaction zone positioned along a portion of the length is configured to be heated to an operating reaction temperature, and has at least one active layer therein comprising an electrolyte separating first and second opposing electrodes, and active first and second gas passages adjacent the respective first and second electrodes. At least one cold zone positioned from the first end along another portion of the length is configured to remain below the operating reaction temperature. An artery flow passage extends from the first end along the length through the cold zone and into the reaction zone and is fluidicly coupled to the active first gas passage, which extends from the artery flow passage toward at least one side. The thickness of the artery flow passage is greater than the thickness of the active first gas passage. In other embodiments, fuel cell devices include an electrolyte having at least a portion thereof comprising a ceramic material sintered from a nano-sized powder. In yet other embodiments, cold zones are provided at each end of the device with the reaction zone therebetween having at least two discrete power sections, each having one or more active layers, the power sections fed by discrete fuel passages to provide a device and system capable of operating at more than one power level. | 05-23-2013 |
20130136953 | FUEL CELL DEVICE - Fuel cell devices are provided having improved shrinkage properties between the active and non-active structures by modifying the material composition of the non-active structure, having a non-conductive, insulating barrier layer between the active structure and surface conductors that extend over the inactive surrounding support structure, having the width of one or both electrodes progressively change along the length, or having a porous ceramic layer between the anode and fuel passage and between the cathode and air passage. Another fuel cell device is provided having an internal multilayer active structure with electrodes alternating in polarity from top to bottom and external conductors on the top and/or bottom surface with sympathetic polarity to the respective top and bottom electrodes. A fuel cell system is provided with a fuel cell device having an enlarged attachment surface at one or both ends, which resides outside the system's heat source, insulated therefrom. | 05-30-2013 |
20130252126 | FUEL CELL DEVICE AND SYSTEM - The present invention relates to a fuel cell system. A hot zone chamber has a wall thickness T and a heat source coupled thereto. An elongate fuel cell device is positioned with a first lengthwise portion within the hot zone chamber, a second lengthwise portion outside the hot zone chamber, and a third lengthwise portion of length T within the chamber wall. The third portion has a maximum dimension L in a plane transverse to the length where T≧½L. | 09-26-2013 |
20130273462 | METHOD OF MAKING A FUEL CELL DEVICE - A monolithic fuel cell device is provided by forming anode and cathode layers by dispensing paste of anode or cathode material around pluralities of spaced-apart removable physical structures to at least partially surround the structures with the anode or cathode material and then drying the paste. An electrolyte layer is provided in a multi-layer stack between the cathode layer and the anode layer thereby forming an active cell portion. The multi-layer stack is laminated, and then the physical structures are pulled out to reveal spaced-apart active passages formed through each of the anode layer and cathode layer. Finally, the laminated stack is sintered to form an active cell comprising the spaced apart active passages embedded in and supported by the sintered anode material and sintered cathode material. | 10-17-2013 |
20140065504 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness with the length direction being the dominant direction of thermal expansion. A reaction zone having at least one active layer therein is spaced from the first end and includes first and second opposing electrodes, associated active first and second gas passages, and electrolyte. The active first gas passage includes sub-passages extending in the y direction and spaced apart in the x direction. An artery flow passage extends from the first end along the length and into the reaction zone and is fluidicly coupled to the sub-passages of the active first gas passage. The thickness of the artery flow passage is greater than the thickness of the sub-passages. In other embodiments, fuel cell devices include second sub-passages for the active second gas passage and a second artery flow passage coupled thereto, and extending from either the first end or the second end into the reaction zone. In yet other embodiments, one or both electrodes of a fuel cell device are segmented. | 03-06-2014 |
20140106252 | FUEL CELL DEVICE AND SYSTEM - Fuel cell devices and fuel cell systems are provided. The fuel cell devices may include one or more active layers containing active cells that are connected electrically in series. The active cells include anodes and cathodes spaced apart along the length, with each including a porous portion and a non-porous conductor portion. The active cells reside between opposing porous anode and cathode portions. The electrical series connections between active cells are made between the non-porous conductor portions. In certain embodiments, the electrical series connections are made by direct contact between the non-porous conductor portions. In certain embodiments, the electrical series connections are made by non-porous conductive vias or elements that extend through an intervening support structure that separates the non-porous anode conductor portions from the non-porous cathode conductor portions. | 04-17-2014 |
20140141349 | SOLID OXIDE FUEL CELL DEVICE - A fuel cell device having an exterior surface defining an interior ceramic support structure. An active zone is along an intermediate portion of the length for undergoing a fuel cell reaction, and opposing non-active end regions are along end portions extending away from the active zone without being heated. Fuel and oxidizer passages extend within the interior support structure from respective first and second inlets in respective ones of the opposing non-active end regions. The active zone has an anode associated with each of the fuel passages and a cathode associated with each of the oxidizer passages in opposing relation to a respective one of the anodes with an electrolyte therebetween. The opposing non-active end regions lack the anode and cathode in opposing relation so as to be incapable of undergoing a fuel cell reaction. | 05-22-2014 |
20140295319 | FUEL CELL DEVICE AND SYSTEM - A fuel cell device is provided having an active central portion with an anode, a cathode, and an electrolyte therebetween. At least three elongate portions extend from the active central portion, each having a length substantially greater than a width transverse thereto such that the elongate portions each have a coefficient of thermal expansion having a dominant axis that is coextensive with its length. A fuel passage extends from a fuel inlet in a first elongate portion into the active central portion in association with the anode, and an oxidizer passage extends from an oxidizer inlet in a second elongate portion into the active central portion in association with the cathode. A gas passage extends between an opening in the third elongate portion and the active central portion. For example, the passage in the third elongate portion may be an exhaust passage for the spent fuel and/or oxidizer gasses. | 10-02-2014 |