Patent application number | Description | Published |
20100125161 | METHOD OF PREPARING MULTICOMPONENT BISMUTH MOLYBRDATE CATALYSTS WITH CONTROLLING PH AND A METHOD OF PREPARING 1,3-BUTADIENE USING THEREOF - This invention relates to a method of preparing a multicomponent bismuth molybdate catalyst by changing the pH of a coprecipitation solution upon coprecipitation and a method of preparing 1,3-butadiene using the catalyst. The multicomponent bismuth molybdate catalyst, coprecipitated using a solution having an adjusted pH, the preparation method thereof, and the method of preparing 1,3-butadiene through oxidative dehydrogenation using a C4 mixture including n-butene and n-butane as a reactant are provided. The C4 raffinate, containing many impurities, is directly used as a reactant without an additional process for separating n-butane or extracting n-butene, thus obtaining 1,3-butadiene at high yield. The activity of the multicomponent bismuth molybdate catalyst can be simply increased through precise pH adjustment upon coprecipitation, which is not disclosed in the conventional techniques. This method can be applied to the increase in the activity of multicomponent bismuth molybdate catalysts reported in the art. | 05-20-2010 |
20100137664 | PROCESS FOR 1,3-BUTADIENE SEPARATION FROM A CRUDE C4 STREAM WITH ACETYLENE CONVERTER - Disclosed is a method of recovering 1,3-butadiene from a C4 stream containing butane, isobutane, 2-butene, 1-butene, isobutene, butadiene and acetylene. The process of recovering highly pure 1,3-butadiene includes acetylene conversion for selectively converting acetylene through liquid-phase hydrogenation, so that the acetylene content is decreased to 70 wt ppm or less, and 1,3-butadiene extraction using an extractive distillation column, a pre-separator, a solvent stripping column, a solvent recovery column, and a purification column. Through the acetylene conversion, the concentration of vinylacetylene is decreased to 70 wt ppm or less, after which 1,3-butadiene is recovered using only one extractive distillation column, thereby considerably decreasing the degree of utility and the loss of streams in the course of extraction. The number of units necessary for the process is decreased, thus remarkably reducing the time during which impurities can accumulate in a processing unit. | 06-03-2010 |
20100280300 | MIXED MANGANESE FERRITE CATALYSTS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING 1,3-BUTADIENE USING THEREOF - A method of producing a mixed manganese ferrite catalyst, and a method of preparing 1,3-butadiene using the mixed manganese ferrite catalyst. Specifically, a method of producing a mixed manganese ferrite catalyst through a coprecipitation method which is performed at a temperature of 10˜40° C., and a method of preparing 1,3-butadiene using the mixed manganese ferrite catalyst through an oxidative dehydrogenation reaction, in which a C4 mixture containing n-butene, n-butane and other impurities is directly used as reactants without performing additional n-butane separation process or n-butene extraction. 1,3-butadiene can be prepared directly using a C4 mixture including n-butane at a high concentration as a reactant through an oxidative hydrogenation reaction without performing an additional n-butane separation process, and 1,3-butadiene, having high activity, can be also obtained in high yield for a long period of time. | 11-04-2010 |
20110004041 | METHOD OF PRODUCING 1,3-BUTADIENE FROM N-BUTENE USING CONTINUOUS-FLOW DUAL-BED REACTOR - A method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a continuous-flow dual-bed reactor designed such that two kinds of catalysts charged in a fixed-bed reactor are not physically mixed. More particularly, a method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a C4 mixture including n-butene and n-butane as reactants and using a continuous-flow dual-bed reactor in which a multi-component bismuth molybdate catalyst and a zinc ferrite catalyst having different reaction activity in the oxidative dehydrogenation reaction of n-butene isomers (1-butene, trans-2-butene, cis-2-butene). | 01-06-2011 |
20130087095 | SELF-GETTERING DIFFERENTIAL PUMP - A self-gettering differential pump for a molecular beam epitaxy system has a collimator with a length greater than its diameter mounted in front of a source in extended port geometry, wherein the reactant delivered by the source also serves as a gettering agent. | 04-11-2013 |
20130178673 | METHOD OF PRODUCING VALUABLE AROMATICS AND OLEFINS FROM HYDROCARBONACEOUS OILS DERIVED FROM COAL OR WOOD - This invention relates to a method of producing aromatics and olefins from oils derived from coal or wood, including partially saturating and cracking the oils derived from coal or wood in a hydrogenation & reaction area, separating them depending on the number of carbons, recirculating heavy oils having 11 or more carbons to the hydrogenation & reaction area, feeding oils suitable for producing BTX to an aromatic separation process and a transalkylation process to recover aromatics, and feeding hydrocarbonaceous components having 5 or less carbons to a light separation process, thus obtaining olefins. | 07-11-2013 |
20130210611 | HYDROCRACKING CATALYST FOR PREPARING VALUABLE LIGHT AROMATIC HYDROCARBONS FROM POLYCYCLIC AROMATIC HYDROCARBONS - This invention relates to a hydrocracking catalyst for preparing valuable light aromatic hydrocarbons from polycyclic aromatic hydrocarbons derived from oil, which includes (i) beta-zeolite, (ii) pseudo-boehmite, and (iii) one or more metals selected from among metals of Groups VIII and VIB, and which further includes a cocatalyst component, thereby producing a maximum amount of BTX (Benzene, Toluene, Xylene) from LCO (Light Cycle Oil). | 08-15-2013 |
20130253242 | METHOD FOR PRODUCING HIGH-ADDED-VALUE AROMATIC PRODUCTS AND OLEFINIC PRODUCTS FROM AN AROMATIC-COMPOUND-CONTAINING OIL FRACTION - The present invention relates to a method for manufacturing aromatic products (benzene/toluene/xylene) and olefinic products from an aromatic-compound-containing oil fraction, whereby it is possible to substitute naphtha as a feedstock for aromatic production and so make stable supply and demand, and it is possible to substantially increase the yield of high-added-value olefinic and high-added-value aromatic components, by providing a method for manufacturing olefinic and aromatic products from light cycle oil comprising a hydrogen-processing reaction step, a catalytic cracking step, an separation step and a transalkylation step, and optionally also comprising a recirculation step. | 09-26-2013 |
20130267744 | THE METHOD FOR PRODUCING VALUABLE AROMATICS AND LIGHT PARAFFINS FROM HYDROCARBONACEOUS OILS DERIVED FROM OIL, COAL OR WOOD - This invention relates to a method of producing aromatics and light paraffins from hydrocarbonaceous oils derived from oil, coal or wood, including partially saturating and hydrocracking the oils derived from oil in a hydrogenation and reaction area, separating them depending on the number of carbons, recirculating heavy oils having 11 or more carbons to the hydrogenation and reaction area, feeding oils suitable for producing BTX to an aromatic separation process and a transalkylation process to recover aromatics, and feeding hydrocarbonaceous components having 5 or fewer carbons to a light separation process, thus obtaining light paraffins. | 10-10-2013 |
20140179967 | METHOD OF PRODUCING AROMATIC HYDROCARBONS FROM BYPRODUCTS OF AROMATIC CARBOXYLIC ACID AND/OR AROMATIC CARBOXYLIC ACID ALKYLESTER PREPARATION PROCESSES - This invention relates to a method of producing an aromatic hydrocarbon compound from byproducts of aromatic carboxylic acid and/or aromatic carboxylic acid alkylester preparation processes using hydroprocessing under conditions of high temperature and high hydrogen pressure in the presence of a catalyst, and to a hydroprocessing catalyst used therein. | 06-26-2014 |
20140213431 | CATALYST FOR CATALYTIC CRACKING OF HYDROCARBON, WHICH IS USED IN PRODUCTION OF LIGHT OLEFIN AND PRODUCTION METHOD THEROF - Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01˜5.0 wt % of MnO | 07-31-2014 |
20140275671 | METHOD OF PRODUCING AROMATIC HYDROCARBONS AND OLEFIN FROM HYDROCARBONACEOUS OILS COMPRISING LARGE AMOUNTS OF POLYCYCLIC AROMATIC COMPOUNDS - This invention relates to a method of producing aromatic hydrocarbons and olefin from hydrocarbonaceous oils including large amounts of polycyclic aromatic compounds having two or more rings via partial hydrogenation in the presence of a hydrogenation catalyst and catalytic cracking in the presence of a catalytic cracking catalyst. | 09-18-2014 |
Patent application number | Description | Published |
20090012339 | Catalytic Cracking Process Using Fast Fluidization for the Production of Light Olefins from Hydrocarbon Feedstock - Disclosed is a catalytic cracking process for the production of light olefins from a hydrocarbon feedstock using fast fluidization, which is a preferred process for more efficiently increasing the production of light olefin hydrocarbons. According to this invention, a fast fluidization regime is applied to a fluidized bed catalytic cracking process of producing light olefins using zeolite, such that a volume fraction and distribution of the catalyst sufficient to induce the catalytic cracking reaction can be provided, thus effectively enhancing the production of light olefin hydrocarbons, in particular, ethylene and propylene, at high selectivity. | 01-08-2009 |
20100121123 | ZINC FERRITE CATALYSTS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING 1,3-BUTADIENE USING THEREOF - The present invention relates to a zinc ferrite catalyst, a method of producing the same, and a method of preparing 1,3-butadiene using the same. Specifically, the present invention relates to a zinc ferrite catalyst which is produced in a pH-adjusted solution using a coprecipitation method, a method of producing the same, and a method of preparing 1,3-butadiene using the same, in which the 1,3-butadiene can be prepared directly using a C4 mixture including n-butene and n-butane through an oxidative dehydrogenation reaction. The present invention is advantageous in that 1,3-butadiene can be obtained at a high yield directly using a C4 fraction without performing an additional process for separating n-butene, as a reactant, from a C4 fraction containing impurities. | 05-13-2010 |
20100249482 | METHOD OF PREPARING MULTICOMPONENT BISMUTH MOLYBDATE CATALYSTS COMPRISING FOUR METAL COMPONENTS AND METHOD OF PREPARING 1,3-BUTADIENE USING SAID CATALYSTS - This invention relates to a method of preparing multicomponent bismuth molybdate catalysts composed of four metal components and a method of preparing 1,3-butadiene using the catalyst, and particularly, to multicomponent bismuth molybdate catalysts composed of a divalent cationic metal, a trivalent cationic metal, bismuth and molybdenum, a preparation method thereof, and a method of preparing 1,3-butadiene from a C4 mixture including n-butene and n-butane using oxidative dehydrogenation. According to this invention, it is possible to prepare catalysts having high activity for the preparation process of 1,3-butadiene only using four metal components as shown through systematic investigation of types and ratios of metal components, unlike conventional multicomponent metal oxide catalysts having a complicated composition of metal components. | 09-30-2010 |
20110288354 | PROCESS FOR THE PREPARATION OF CLEAN FUEL AND AROMATICS FROM HYDROCARBON MIXTURES CATALYTIC CRACKED ON FLUID BED - This invention relates to a petroleum refining method for producing high value-added clean petroleum products and aromatics (Benzene/Toluene/Xylene) together, by which low pollution petroleum products including liquefied petroleum gas or low-sulfur gas oil and aromatics can be efficiently produced together from a fluid catalytic cracked oil fraction. | 11-24-2011 |