Patent application number | Description | Published |
20090025555 | SORBENT FIBER COMPOSITIONS AND METHODS OF TEMPERATURE SWING ADSORPTION - The various embodiments of the present invention relate to compositions, apparatus, and methods comprising sorbent fibers. More particularly, various embodiments of the present invention are directed towards sorbent fiber compositions for temperature swing adsorption processes. Various embodiments of the present invention comprise sorbent fiber compositions, apparatus comprising a plurality of sorbent fibers, and methods of using the same for the capture of at least one component from a medium, for example CO | 01-29-2009 |
20090178561 | Method of making a crosslinked fiber membrane from a high molecular weight, monoesterified polyimide polymer - The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component. | 07-16-2009 |
20090249950 | CROSSLINKED MEMBRANE AND POLYMER FOR MAKING SAME AND METHOD OF USING MEMBRANE - A composition of and a method of making high performances crosslinked membranes are described. The membranes have a high resistance to plasticization by use of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant membrane exhibits a high permeability of CO | 10-08-2009 |
20110011803 | SORBENT FIBER COMPOSITIONS AND METHODS OF USING THE SAME - The various embodiments of the present invention relate generally to sorbent fiber compositions. More particularly, various embodiments of the present invention are directed towards sorbent fibers for pressure swing and temperature swing adsorption processes. Various embodiments of the present invention comprise a sorbent composition, comprising a fiber comprising a plurality of tortuous pathways; and a sorbent material, wherein the sorbent material is in fluid communication with at least a portion of the plurality of tortuous pathways. Aspects of the present invention comprise compositions, devices and methods of using sorbent fiber compositions. | 01-20-2011 |
20110040013 | LAYERED ZEOLITE MATERIALS AND METHODS RELATED THERETO - A novel oxide material (MIN-I) comprising YO | 02-17-2011 |
20120067208 | METHOD OF MAKING A CROSSLINKED FIBER MEMBRANE FROM A HIGH MOLECULAR WEIGHT, MONOESTERIFIED POLYIMIDE POLYMER - The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component. | 03-22-2012 |
20120111191 | CROSSLINKED MEMBRANE AND POLYMER FOR MAKING SAME AND METHOD OF USING MEMBRANE - A composition of and a method of making high performance crosslinked membranes are described. The membranes have a high resistance to plasticization by use of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant membrane exhibits a high permeability of CO | 05-10-2012 |
20120135485 | SORBENT AND PROCESS FOR REMOVING FERMENTATION INHIBITORS - The invention pertains to, for example, an improved sorbent and process for removing fermentation inhibitors such as furfural and/or HMF in microbial processes utilizing fermentable sugars obtained from biomass including, for example, in the production of bioalcohols. The sorbent is capable of separating one or more inhibitors from monosaccharides and is characterized by: (1) a K | 05-31-2012 |
20120152117 | SORBENT FIBER COMPOSITIONS AND METHODS OF TEMPERATURE SWING ADSORPTION - The various embodiments of the present invention relate to compositions, apparatus, and methods comprising sorbent fibers. More particularly, various embodiments of the present invention are directed towards sorbent fiber compositions for temperature swing adsorption processes. Various embodiments of the present invention comprise sorbent fiber compositions, apparatus comprising a plurality of sorbent fibers, and methods of using the same for the capture of at least one component from a medium, for example CO | 06-21-2012 |
20120171752 | Water/Carbonate Stripping For CO2 Capture Adsorber Regeneration And CO2 Delivery To Photoautotrophs - The invention provides systems and methods for the delivery of carbon to photoautotrophs. The invention utilizes low energy regeneration of adsorbent for CO | 07-05-2012 |
20130036905 | SORBENT FIBER COMPOSITIONS AND METHODS OF TEMPERATURE SWING ADSORPTION - The various embodiments of the present invention relate to compositions, apparatus, and methods comprising sorbent fibers. More particularly, various embodiments of the present invention are directed towards sorbent fiber compositions for temperature swing adsorption processes. Various embodiments of the present invention comprise sorbent fiber compositions, apparatus comprising a plurality of sorbent fibers, and methods of using the same for the capture of at least one component from a medium, for example CO | 02-14-2013 |
20130220119 | Crosslinked Membrane And Polymer For Making Same And Method Of Using Membrane - A composition of and a method of making high performance crosslinked membranes are described. The membranes have a high resistance to plasticization by use of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant membrane exhibits a high permeability of CO | 08-29-2013 |
20130280151 | IONIC LIQUID-FUNCTIONALIZED MESOPOROUS SORBENTS AND THEIR USE IN THE CAPTURE OF POLLUTING GASES - A composite structure for capturing a gaseous electrophilic species, the composite structure comprising mesoporous refractory sorbent particles on which an ionic liquid is covalently attached, wherein said ionic liquid includes an accessible functional group that is capable of binding to said gaseous electrophilic species. In particular embodiments, the mesoporous sorbent particles are contained within refractory hollow fibers. Also described is a method for capturing a gaseous electrophilic species by use of the above-described composite structure, wherein the gaseous electrophilic species is contacted with the composite structure. In particular embodiments thereof, cooling water is passed through the refractory hollow fibers containing the IL-functionalized sorbent particles in order to facilitate capture of the gaseous electrophilic species, and then steam is passed through the refractory hollow fibers to facilitate release of the gaseous electrophilic species such that the composite structure can be re-used to capture additional gas. | 10-24-2013 |
20130333562 | POLYIMIDE-BASED CARBON MOLECULAR SIEVE MEMBRANE FOR ETHYLENE/ETHANE SEPARATIONS - Carbon molecular sieve membranes having desirable selectivity for ethylene/ethane separations are prepared from a 3,3′,4,4′-benzophenonetetracarboxylic acid dianhydride 5(6)-amino-1-(4′-aminophenyl)-1,3,3-trimethylindane 4,4-bismaleimidodiphenyl-methane (BTDA-DAPI) precursor solution that is then formed into films or hollow fibers which are pyrolyzed under vacuum or an inert atmosphere to form carbon molecular sieve membranes. Pyrolysis condition variables, including ramp rate, thermal soak time and temperature, are used to optimize the membrane's separation performance. | 12-19-2013 |
20150053079 | HOLLOW FIBER CARBON MOLECULAR SIEVE MEMBRANE AND PREPARATION AND USE THEREOF - A hollow fiber carbon molecular sieve membrane, a process for preparing the hollow fiber carbon molecular sieve membrane, and a process for effecting separation of an olefin from a gaseous mixture that comprises the olefin in admixture with its corresponding paraffin and optionally one or more gaseous components selected from hydrogen, an olefin other than the olefin and a paraffin other than the corresponding paraffin. The process and membrane may also be used to effect separation of the olefin(s) from remaining feedstream components subsequent to an olefin-paraffin separation. | 02-26-2015 |
Patent application number | Description | Published |
20080200696 | SEPARATION PROCESS USING AROMATIC-SELECTIVE POLYMERIC MEMBRANES - Processes are disclosed for production of value-added products from fluid admixtures of hydrocarbon compounds at least one of which is an aromatic hydrocarbon compound, by means of one or more devices using perm-selective polymeric membranes. More particularly, processes of the invention comprise separations using aromatic-selective polymeric materials comprising long-chain polymeric molecules in which recurring amide and imide linkages are part of the main polymer chain. Processes of the invention advantageously employ aromatic-selective membranes to separate an aromatic enriched stream from gaseous and/or liquid mixtures comprising one or more aromatic hydrocarbon compounds thereby producing a stream comprising the remaining compounds which may include alkenes and/or alkanes containing 3 or more carbon atoms, and/or alicyclic hydrocarbons. Processes of the invention are particularly useful for recovery of meta-xylene and para-xylene products from liquid mixtures even containing ethylbenzene as well as the three xylene isomers. | 08-21-2008 |
20080223785 | Ionic Polymer Membranes - Compositions and processes are disclosed for economical separation of fluid mixtures. Broadly, the present invention discloses ionic polymer compositions that are useful for perm-selective membrane separations. More particularly, ionic polymers of the invention comprise a plurality of repeating structural units having as a constituent part thereof organic ionic moieties consisting of nitrogen containing anions and/or cations. In the form of non-porous membranes, ionic polymers of the invention facilitate recovery of purified organic and inorganic products from fluid mixtures by means of perm-selective membrane separations. The present invention also provides methods for forming the ionic polymers, for example by treating selected nitrogen-containing organic polymers with acids, or treating a polymeric material comprising a plurality of carboxylate groups with an amine. Ionic polymer compositions of the invention are particularly useful for simultaneous recovery of a permeate product of an increased concentration, and a desired non-permeate stream, from a fluid mixture containing at least two compounds of different boiling point temperatures. | 09-18-2008 |
20100313755 | FIBER SORBENTS - The present invention relates to new fibers, new processes of using said fibers, and new sheath dope compositions for multi-layer spinning processes. The fibers comprise a porous core and a sheath surrounding said porous core. The fibers may be useful in, for example, processes for removing low level contaminants like sulfur compounds from a gas stream like natural gas. | 12-16-2010 |
20110100211 | METHOD FOR PRODUCING CARBON MOLECULAR SIEVE MEMBRANES IN CONTROLLED ATMOSPHERES - The invention concerns carbon molecular sieve membranes (“CMS membranes”), and more particularly the use of such membranes in gas separation. In particular, the present disclosure concerns an advantageous method for producing CMS membranes with desired selectivity and permeability properties. By controlling and selecting the oxygen concentration in the pyrolysis atmosphere used to produce CMS membranes, membrane selectivity and permeability can be adjusted. Additionally, oxygen concentration can be used in conjunction with pyrolysis temperature to further produce tuned or optimized CMS membranes. | 05-05-2011 |
20110210073 | POLYMERIC SORBENTS FOR REMOVING LOW LEVEL CONTAMINANTS - The present invention relates to functionalized polymeric sorbents and processes of employing them to remove low level contaminants from fluid streams. Poly(glycidyl methacrylate-co-trimethylolpropane trimethacrylate) functionalized with a compound having the structure NH | 09-01-2011 |
20110269915 | THERMALLY CROSSLINKED POLYMERIC COMPOSITIONS AND METHODS OF MAKING THE SAME - The various embodiments of the present disclosure relate generally to thermally crosslinked polymeric compositions and methods of making thermally crosslinked polymeric compositions. An embodiment of the present invention comprises a composition comprising: a first polymer comprising a first repeat unit, the first repeat unit comprising a carboxyl group, wherein the first polymer crosslinks to a second polymer formed from a second repeat unit, and wherein the first polymer crosslinks to the second polymer without formation of an ester group. | 11-03-2011 |
20120042780 | TREATMENT OF MOLECULAR SIEVE PARTICLES FOR MIXED MATRIX MEMBRANES - The present invention relates to a method for treating molecular sieve particles for use in a mixed matrix membrane useful in, for example, gas separations. Membranes employing treated molecular sieve particles may exhibit enhanced permeabilities and selectivities in regard to, for example, the separation of carbon dioxide and methane. | 02-23-2012 |
20120324890 | ADSORBING HEAT EXCHANGERS - The present invention generally relates to power generation systems configured to absorb and capture a component, such as carbon dioxide, in a flue gas for later sequestration or utilization, wherein heat generated in the sorption process is captured for use in the power generation system. In some examples, the heat of sorption is used to preheat fluids in one or more systems of the power generation system to reduce the heating load on the subsystem. By using the heat of sorption, the carbon dioxide capture and sequestration process not only reduces or eliminates the concentration of carbon dioxide in the flue gas, but reduces or eliminates the parasitic effect of carbon dioxide capture and sequestration on power generation. | 12-27-2012 |
20130152793 | Stabilization of Porous Morphologies for High Performance Carbon Molecular Sieve Hollow Fiber Membranes - Carbon molecular sieves (CMS) membranes having improved thermal and/or mechanical properties are disclosed herein. In one embodiment, a carbon molecular sieve membrane for separating a first and one or more second gases from a feed mixture of the first gas and one or more second gases comprises a hollow filamentary carbon core and a thermally stabilized polymer precursor disposed on at least an outer portion of the core. In some embodiments, the thermally stabilized polymer precursor is created by the process of placing in a reaction vessel the carbon molecular sieve membrane comprising an unmodified aromatic imide polymer, filling the reaction vessel with a modifying agent, and changing the temperature of the reaction vessel at a temperature ramp up rate and ramp down rate for a period of time so that the modifying agent alters the unmodified aromatic imide polymer to form a thermally stabilized polymer precursor. | 06-20-2013 |
20130305921 | METHOD FOR PRODUCING CARBON MOLECULAR SIEVE MEMBRANES IN CONTROLLED ATMOSPHERES - The invention concerns carbon molecular sieve membranes (“CMS membranes”), and more particularly the use of such membranes in gas separation. In particular, the present disclosure concerns an advantageous method for producing CMS membranes with desired selectivity and permeability properties. By controlling and selecting the oxygen concentration in the pyrolysis atmosphere used to produce CMS membranes, membrane selectivity and permeability can be adjusted. Additionally, oxygen concentration can be used in conjunction with pyrolysis temperature to further produce tuned or optimized CMS membranes. | 11-21-2013 |
20140000454 | Carbon Molecular Sieve Membrane (CMSM) Performance Tuning By Dual Temperature Secondary Oxygen Doping (DTSOD) | 01-02-2014 |
20150011815 | COMPOSITE HOLLOW FIBER MEMBRANES USEFUL FOR CO2 REMOVAL FROM NATURAL GAS - Disclosed herein is a composite hollow fiber polymer membrane including a porous core layer and a selective sheath layer. The porous core layer includes a polyamide-imide polymer, or a polyetherimide polymer, and the selective sheath layer includes a polyimide polymer, which is prepared from monomers A, B, and C. The monomer A is a dianhydride of the formula | 01-08-2015 |