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Toray Plastics (America) Inc.

Toray Plastics (America) Inc. Patent applications
Patent application numberTitlePublished
20120128974MATTE BIAXIALLY ORIENTED POLYLACTIC ACID FILM - A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and a minority amount of polyolefin with a compatibilizing resin which is biaxially oriented such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.05-24-2012
20120128973METHOD TO PRODUCE MATTE AND OPAQUE BIAXIALLY ORIENTED POLYLACTIC ACID FILM - A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and an inorganic antiblock particle which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the particles such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.05-24-2012
20120094042HEAT SEALABLE MONOAXIALLY ORIENTED PROPYLENE-BASED FILM WITH DIRECTIONAL TEAR - A monoaxially oriented films and methods of making films including a heat sealable layer including propylene homo-polymer or copolymer and 3-15 wt % of at least one elastomer. The oriented films have a refractive index that satisfies the condition 5≦delta n=|n (MD)−n (TD)|×1000≦25, in which n (MD) is a refractive index of the film in a machine direction, and n (TD) is a refractive index of the film in a transverse direction. The films are suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties, particularly for retort pouches04-19-2012
20120088108BARRIER COATING COMPOSITION WITH ORGANIC PARTICLES - A moisture vapor and oxygen transmission resistant flexible film has a polymeric base layer and a barrier layer of discrete particles of a first organic polymer dispersed throughout a matrix of a second organic polymer. Preferably, the first and second polymers are water insoluble and water soluble, respectively. The barrier layer is formed by depositing onto the base layer a coating composition of finely divided insoluble organic polymer particles suspended in an aqueous solution of the water soluble organic polymer, a crosslinking agent and surfactant. The coating composition is heated to crosslink the barrier layer polymers and evaporate solvent to provide a barrier film suitable for packaging applications. Optionally, the film can be metalized to increase barrier properties.04-12-2012
20120028058HIGH BARRIER HEAT SEALABLE FILM WITH LINEAR TEAR PROPERTIES - A monoaxially oriented film including a metallized layer; a gas barrier layer; and a propylene-based random copolymer and at least about 3 wt % of a low density polyethylene which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction and excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature. This film formulation and orientation is suitable for pouch applications requiring high gas and moisture barrier, an “easy-tear” linear tear feature, and excellent hermetic seal properties.02-02-2012
20120028014HEAT SEALABLE FILM WITH LINEAR TEAR PROPERTIES - A monoaxially oriented film including a propylene-based random copolymer and at least about 3 wt % of a low density polyethylene which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction and excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature. This film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties.02-02-2012
20110317269RELEASABLE METALIZED EMBOSSED TRANSFER FILM - A releasable transfer film is suitable to provide a metalized embossed composite onto a paper substrate without a release layer between the composite and a polymeric carrier layer. The transfer film includes a polymeric base layer, an embossing material layer and a metal layer. The transfer film is bonded to the paper substrate with an adhesive layer allowing the polymeric barrier layer to peel away from and to expose the metal-backed, embossing material layer. The substrate covered with the metalized embossed composite can be used to impart holographic style images to packaging, printed media products such as magazines.12-29-2011
20110287200LIGHTER THAN AIR BALLOON MADE FROM A BIAXIALLY ORIENTED POLYESTER FILM - A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 μm to 12 μm. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.11-24-2011
20110287199LIGHTER THAN AIR BALLOON MADE FROM A BIAXIALLY ORIENTED POLYESTER FILM - A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 μm to 12 μm. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.11-24-2011
20110274892BIAXIALLY ORIENTED BIO-BASED POLYOLEFIN FILMS AND LAMINATES - A laminate film including at least one bio-based polyolefin layer including at least 53 pMC of radiocarbon (11-10-2011
20110274796BARRIER FILM WITH RECLAIMED METALIZED POLYESTER - A method reclaims metalized polymer film or mixtures containing metal and/or metal alloys into a metal-containing, polymeric film. The resulting film structure has better oxygen and moisture barrier properties when metalized than plain metalized polymer films. The polymer to be reclaimed, originates in sheet form, and is densified, as by shredding, pelletizing and/or re-extruding into fine particulate form such as chips or pellets. The reclaimed polymeric film can be used, in a range of concentrations, to produce biaxially oriented polyester film for metalizing.11-10-2011
20110244257METHOD TO REPROCESS POLYLACTIC ACID RESIN AND ARTICLES - Films and formulations that include recycled polylactic acid resin are described. The films and formulations include, for example, 1-10 wt % of an ethylene-acrylate copolymer. The use of the ethylene-acrylate compolymer in the polylactic acid formulations allows for recycling of PLA-based films and articles with minimum degradation, as exhibited by changes in intrinsic viscosity and color properties.10-06-2011
20110244186BIAXIALLY ORIENTED POLYLACTIC ACID FILM WITH REDUCED NOISE LEVEL AND IMPROVED MOISTURE BARRIER - Described are metallized biaxially oriented polylactic acid (BOPLA) films with a novel formulation that exhibits a softer feel and quieter sound, without jeopardizing film making stability. It has been found that when these films are metallized, moisture barrier properties are surprisingly improved compared to conventional metallized BOPLA films. Specifically, the moisture barrier of the films may be 2.0 g/m10-06-2011
20110244185BIAXIALLY ORIENTED POLYLACTIC ACID FILM WITH REDUCED NOISE LEVEL - Described are biaxially oriented polylactic acid (BOPLA) films with a novel formulation that exhibits a softer feel and quieter sound, without jeopardizing film making stability. The films can be used, for example, in packaging applications. The films can be metallized, or combined with barrier coatings or layers, for improved gas barrier properties particularly for moisture vapor transmission barrier desired in packaging applications. The films can also be printing films for packaging applications and may be transparent or matte in appearance. The films have characteristics that are beneficial to converting processes, are economical, and maintain bio-compostability similar to typical BOPLA films.10-06-2011
20110171489MULTI-LAYER HIGH MOISTURE BARRIER POLYLACTIC ACID FILM - A laminate film including a first polylactic acid layer; a second metal-receiving layer including PVOH, EVOH, or a blend thereof on a side of the first polylactic acid layer; and a metal layer deposited on a side of the metal-receiving layer opposite the polylactic acid layer. The metal-receiving layer may be coextruded with the polylactic acid first layer or may be a coating applied to one side of the polylactic acid first layer. This laminate film exhibits excellent gas and moisture barrier properties, appearance, and metal adhesion. It may also include a heat sealable or winding improving layer on the side opposite the metal receiving-layer of the first polylactic acid layer.07-14-2011
20110107933POLYESTER FILM WITH ADHESIVE PROPERTIES - A multilayer composite film for sublimation type dye transfer imaging includes a polyester base layer and an adhesive layer onto which an ink layer of the sublimation dye can be placed. The adhesive layer includes an acrylic resin, an epoxy resin monomer and a crosslinking agent. The components of the adhesive layer preferably are water soluble or water dispersible.05-12-2011
20110081543BIODEGRADABLE COMPOSITE BARRIER FILM - The present invention is directed to a multilayer film having, as its main component, a hydroxy acid polymer with improved gas barrier and optional heat sealability. The oriented film of predominately hydroxy acid polymer having controlled shrink can be produced by melting and coextruding a hydroxy acid polymer with a much thinner layer of an amorphous aromatic copolyester to form a multilayer film that is quench cooled, then biaxially stretched at a process temperature above the glass transition and below the cold crystallization temperature of the hydroxy acid polymer. A heat-setting treatment with a controlled relaxation of the film above the hydroxy acid polymer glass transition temperature and below its melt temperature may be used to control shrinkage. The films thus obtained are vacuum metallized on the aromatic copolyester surface to produce environmentally friendly packaging from predominately renewable resources having improved gas barrier properties.04-07-2011
20110076511MULTI-LAYER HIGH MOISTURE BARRIER POLYLACTIC ACID FILM - A laminate film including a first core polylactic acid layer, a coating receiving-layer of polylactic acid, and coated on one side of the coating receiving-layer with PVOH, EVOH, a blend of crosslinked EVOH/PVOH, vinyl alcohol-vinylamine (PVAm) copolymer, anionic carboxylated styrene-butadiene copolymer (SBR) emulsion, or blends thereof. This coating may be applied after the machine-direction orientation step and dried and oriented in a transverse direction orientation oven if in-line coating is desired; or applied to the film in an off-line coating method and dried in an air flotation oven. The dried coating layer can be metallized. This laminate film exhibits excellent gas and moisture barrier properties, appearance, and metal adhesion. It may also optionally include a heat sealable or winding improving layer on the side opposite the coating receiving-layer of the core layer.03-31-2011
20110014835CROSSLINKED POLYOLEFIN FOAM SHEET WITH EXCEPTIONAL SOFTNESS, HAPTICS, MOLDABILITY, THERMAL STABILITY AND SHEAR STRENGTH - A crosslinked, closed cell polyolefin foam sheet has exceptional softness, haptics, moldability, thermal stability and shear strength as well as a laminate and uses thereof.01-20-2011
20100330382BIAXIALLY ORIENTED POLYLACTIC ACID FILM WITH IMPROVED MOISTURE BARRIER - A biaxially oriented multilayer film comprising a skin layer of polyhydroxyalkanoate, a core layer of polylactic acid polymer and a sealant layer with a metal deposited upon one surface of the skin layer of polyhydroxyalkanoate polymer. This metallized, polyhydroxyalkanoate-coextruded polylactic acid film exhibits improved moisture barrier property versus a metallized, non-polyhydroxyalkanoate-coextruded polylactic acid film.12-30-2010
20100323196BIAXIALLY ORIENTED POLYLACTIC ACID FILM WITH IMPROVED HEAT SEAL PROPERTIES - Multi-layer biaxially oriented polylactic acid (BOPLA) film with a novel formulation improves the heat seal initiation temperature and heat seal performance of BOPLA films while maintaining good optical clarity. The film may include a core layer including polylactic acid base polymer resin, and a heat sealable layer including amorphous polylactic acid base polymer and a modifier comprising polycaprolactone or poly(butylene-adipate-co-butylene terephthalate).12-23-2010
20100247886BIAXIALLY ORIENTED METALLIZED POLYLACTIC ACID FILM WITH HIGH METAL ADHESION AND HIGH BARRIER PROPERTIES - Metallized multi-layer biaxially oriented polylactic acid base polymer (BOPLA) films that exhibits improved barrier properties and metal adhesion. The films include a core layer including crystalline polylactic acid base polymer, a first skin layer consisting essentially of amorphous polylactic acid base polymer, and a metal layer on the first skin layer. The films may include a second skin layer consisting essentially of amorphous polylactic acid base polymer.09-30-2010
20100055429HEAT SEALABLE MONOAXIALLY ORIENTED PROPYLENE-BASED FILM WITH DIRECTIONAL TEAR - A monoaxially oriented film including heat sealable layer including an ethylene-propylene impact copolymer and a metallocene-catalyzed propylene-butene elastomer. The heat sealable layer may include a metallocene-catalyzed ethylene-butene elastomer. The film is oriented at least 4 times in the machine direction and exhibits excellent linear directional tear properties in the machine direction and excellent heat seal performance. This film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties, particularly for retort pouches.03-04-2010
20100040904BIAXIALLY ORIENTED POLYLACTIC ACID FILM WITH HIGH BARRIER - A multilayer film including a first layer including a polylactic acid polymer, a second layer of a metal primer, deposited upon one surface of the first polylactic acid polymer layer, and a third metal layer deposited on the second metal primer layer. This metal-primed and metallized polylactic acid film exhibits improved moisture barrier properties versus a non-metal-primed and metallized polylactic acid film and can be used as part of a lamination structure for food packaging applications.02-18-2010
20100009208MATTE BIAXIALLY ORIENTED POLYLACTIC ACID FILM - A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and a minority amount of polyolefin with a compatibilizing resin which is biaxially oriented such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.01-14-2010
20090311544METHOD TO PRODUCE MATTE AND OPAQUE BIAXIALLY ORIENTED POLYLACTIC ACID FILM - A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and an inorganic antiblock particle which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the particles such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.12-17-2009
20090148715PROCESS TO PRODUCE BIAXIALLY ORIENTED POLYLACTIC ACID FILM AT HIGH TRANSVERSE ORIENTATION RATES - A biaxially oriented laminate film including a first amorphous polylactic acid polymer heat sealable resin layer and a second core layer including a blend of crystalline polylactic acid polymer and 2-10 wt % of the core layer of an ethylene-acrylate copolymer. The laminate film, exhibiting the property to be transverse oriented in excess of 6 times its original width, typically 8 to 10 times its original width with excellent operability and relatively low haze, is disclosed. The laminate film may further have additional layers such as a third polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.06-11-2009
20090148713BIAXIALLY ORIENTED POLYLACTIC ACID FILM WITH HIGH BARRIER - A metallized laminate film exhibiting improved moisture barrier property as well as maintaining a high bio-polymer content and degradability property is disclosed. The laminate film includes a first core layer of polylactic acid polymer and a second skin layer comprising a polyolefin metal receiving layer. The metal receiving layer or the core layer, or both, may be blended with an amount of polar-modified tie-resin to improve bonding. Alternatively, a discrete tie-resin layer may be interposed between the polyolefin metal receiving layer and the crystalline polylactic acid polymer core layer. The polyolefin metal receiving layer may be discharge-treated on the side opposite the core layer and metallized.06-11-2009
20090087648BIAXIALLY ORIENTED POLYPROPYLENE FILM WITH HIGH HEAT SEAL STRENGTH - A laminate film including a first polyolefin heat sealable resin layer and a second core layer including of a blend of 5-15 wt % of a metallocene-catalyzed butene-propylene or ethylene-propylene thermoplastic elastomer or ethylene-propylene plastomer or blends thereof which exhibit an isothermal crystallization temperature of 60° C. or less and 95-85 wt % of a crystalline propylene homopolymer is disclosed. The laminate film may include additional layers such as a third polyolefin resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.04-02-2009
20090045543METHOD OF MAKING BIAXIALLY ORIENTED POLYOLEFIN FILM FOR COLD SEAL APPLICATIONS - The present invention relates to methods of manufacturing multi-layered polyolefin films that provide excellent adhesion to cold seal cohesive formulations. A surface of the film is discharge-treated. It has been found that when the discharge-treated surface has at least 0.3% nitrogen functional groups, it provides an excellent cold seal receptive surface. A biaxially oriented polypropylene film made according the invention may also have a second skin layer, opposite the first layer, which may be used for metallizing, laminating, or printing.02-19-2009
20090022919LIGHTER THAN AIR BALLOON MADE FROM A BIAXIALLY ORIENTED POLYESTER FILM - A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 μm to 12 μm. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.01-22-2009
20080220226BIAXIALLY ORIENTED POLYPROPYLENE FILM WITH HEAT SEALABLE MATTE LAYER - A laminate film including a first polyolefin heat sealable matte resin layer including a blend of 15-30 wt % metallocene-catalyzed butene-propylene elastomer and 85-70 wt % of a matte resin including ethylene homopolymer and propylene homopolymer or copolymer is disclosed. The laminate film could further have additional layers such as a second polyolefin resin-containing layer, a metal layer, or combinations thereof.09-11-2008
20080205800TRANSPARENT BIAXIALLY ORIENTED POLYPROPYLENE FILM WITH LOW MOISTURE VAPOR AND OXYGEN TRANSMISSION RATE - A laminate film comprising a polyetheramine resin-containing layer, an adhesion-promoting tie-layer, and a core layer comprising of high crystalline propylene homopolymer and crystalline Fischer-Tropsch wax with an optional amount of hydrocarbon resin which exhibits excellent transparency and oxygen and moisture barrier properties. The laminate film could further have additional layers such as a second polyolefin resin-containing layer, or combinations thereof.08-28-2008

Patent applications by Toray Plastics (America) Inc.