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The Dow Chemical Company

Midland, MI US

The Dow Chemical Company Patent applications
Patent application numberTitlePublished
20120065413PROCESS FOR PRODUCING PROPYLENE OXIDE - A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.03-15-2012
20110130579PROCESS FOR THE PREPARATION OF A TITANIUM ZEOLITE CATALYST - A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.06-02-2011
20110120309ADVANCED INTERCOOLING AND RECYCLING IN CO2 ABSORPTION - The present invention relates processes of removal of acidic gases from a gas stream, comprising the steps of 05-26-2011
20110065939METHOD FOR THE SEPARATION OF ACETONITRILE FROM WATER - A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile:water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene:propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile:water in L2 is less than 1; (iv) separating L1 from L2.03-17-2011
20100305369PROCESS FOR THE PREPARATION OF AN OLEFIN OXIDE - The present invention relates to a continuous process for the preparation of an olefin oxide wherein an olefin is reacted with a hydroperoxidein the presence of a catalyst, and wherein the reaction which is carried out in at least three reactors operated in parallel is controlled by specifically adjusting the catalyst loads in the reactors.12-02-2010
20100298128Catalysts Having Enhanced Stability, Efficiency and/or Activity For Alkylene Oxide Production - A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.11-25-2010
20100234518Branched Polyglycols And Branched Polyether Functional Organopolysiloxanes And Coatings Containing Same - Branched polyglycols and branched polyether functional organopolysiloxanes are disclosed as is a process for making branched polyether functional organopolysiloxanes by reacting an organohydrogensiloxane and a branched polyglycol having an unsaturated group via a hydrosilylation reaction, as well as coating compositions containing branched polyether functional organopolysiloxanes and a binder are disclosed. Coatings resulting from these compositions were more hydrophilic and had improved dirt release properties as compared to coatings containing similar, but un-branched, polyether functional organopolysiloxanes.09-16-2010
20100121113PROCESS FOR PRODUCING LOW COLOR GLYCOLS - The present invention provides a process for producing low color glycols that comprises altering at least one condition of a reaction component and/or process stream within the process to be unfavorable for the formation of at least one color-producing contaminant intermediate. As such, such intermediates may be reduced in concentration, or even eliminated entirely, from glycols produced by the process. Since they are not present, or are present in reduced number, the intermediates cannot form color-producing contaminants in the glycols, and low color glycols are provided to the customer. Any condition that can discourage the formation of color forming contaminant intermediates can be adjusted, although conditions that can be adjusted by materials or equipment already utilized in the process, e.g., temperature, pressure, pH, concentration of a color-forming contaminant precursor, the presence of one or more solvents or catalysts favorable for the production of the color-producing contaminant or contaminant intermediate, and the like, are preferred.05-13-2010
20100029960PROCESS FOR PRODUCING EPOXIDES - A process for producing epoxide, the process including contacting an organic phase including at least one halohydrin(s) with at least one aqueous phase including a base in a plug-flow mixer/reactor system to disperse the organic phase in the aqueous phase via a mixing device imparting a power-to-mass ratio of at least 0.2 W/kg to convert at least a portion of the at least one halohydrin to an epoxide.02-04-2010
20090291847Catalysts Having Enhanced Stability, Efficiency and/or Activity For Alkylene Oxide Production - A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.11-26-2009
20090214395Raw Material Efficiency Method and Process - A method and apparatus are disclosed for controlling product discharge from a fluidized bed reactor and for minimizing the loss of the unreacted monomer in the fluidizing gas upon removing the solid polymer product from the reactor. The method and apparatus utilize at least one detector in the product tank or its vent line and a control system in communication with the detector and the product tank fill valve, along with certain algorithms, to adjust by an iterative process, the product discharge time, thereby maximizing resin fill in the product tank and minimizing the lost reactor gas volume.08-27-2009
20090133834Radial Block Copolymers and Adhesives Based Thereon With Improved Die-Cutting Performance - Improved adhesives are provided through the use of styrenic radial block copolymers, containing at least 40 wt % diblock copolymers, the adhesives have improved adhesive properties and a reduced elastic behavior under die-cutting conditions. Compared to conventional linear block copolymers of similar molecular weight, radial copolymers offer higher holding power and lower melt viscosity for the adhesive. They therefore contribute to an improved balance between processability and end-use properties.05-28-2009
20090118523Separation of Propylene Oxide from a Mixture Comprising Propylene Oxide and Methanol - A method of separating propylene oxide from a mixture (M) comprising propylene oxide and methanol, said method comprising: (i) introducing said mixture (M) into an extractive distillation column; (ii) additionally introducing an extracting solvent into said extractive distillation column; (iii) distilling propylene oxide overhead from said extractive distillation column as top stream; (iv) withdrawing a bottoms stream from said extractive distillation column; (v) compressing the top stream obtained overhead in (iii) by means of at least one compressor to give a compressed vapor.05-07-2009
20080306290Process for Epoxidizing Propene - The present invention provides a process for the epoxidation of propene which comprises reacting propene with hydrogen peroxide in the presence of methanol as solvent and a titanium zeolite catalyst, the process further comprising separating propylene oxide from the reaction mixture to obtain a mixture comprising methanol, water, at least one carboxylic acid and at least one carbonyl compound, wherein the at least one carboxylic acid is at least partially neutralized, said process optionally comprising a hydrogenation stage.12-11-2008
20080289948Process for Separating Propylene Glycol From Aqueous Compositions - The present invention relates to a process for separating at least one propylene glycol from a mixture (M) comprising water and said propylene glycol, said process comprising (I) evaporating the mixture in at least two evaporation and/or distillation stages at decreasing operating pressures of the evaporators and/or distillation columns obtaining mixture (M′) and mixture (M″); (II) separating the mixture (M′) obtained in (I) in at least one further distillation step, obtaining a mixture (M-I) comprising at least 70 wt.-% of water and a mixture (M-II) comprising less than 30 wt.-% of water.11-27-2008
20080289758Reactive Hot Melt Adhesive - A reactive hot melt composition, having a softening point of at least 50° C., and being curable on heating to a temperature of 150° C. The composition comprises a blend of (a) a macrocyclic oligomer having a softening point of at least 50° C., containing at least one ring having eight or more atoms, and being able to undergo decyclization at a temperature of 150° C. or more, to produce a polymerizable species, wherein each cyclic oligomer molecule provides two or more structural repeat units of the same or different formula for the resulting polymer, and (b) a thermoplastic resin, its use as an adhesive and methods of its application.11-27-2008

Patent applications by The Dow Chemical Company