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TEIJIN ARAMID B.V.

TEIJIN ARAMID B.V. Patent applications
Patent application numberTitlePublished
20120004461METHOD FOR CONVERTING AROMATIC ALDEHYDES TO AROMATIC ACYL HALIDES - A method for converting an aromatic aldehyde or a mixture of aromatic aldehydes to a reaction product in a reaction medium that is free from xylene. The reaction product may be an aromatic acyl halide or a mixture of aromatic acyl halides. The method includes bringing the aromatic aldehyde or mixture of aromatic aldehydes in contact with a halogen to obtain the reaction product.01-05-2012
20110300379METHOD FOR PRODUCING A FILAMENT YARN FROM AN AROMATIC POLYAMIDE - A method for producing a filament yarn from a para-aromatic polyamide, having an optically anisotropic aramid spinning solution filtered within a spinneret arrangement by using a filter having passage openings and extruded within the spinneret arrangement through a plurality of spinning orifices. The extruded anisotropic aramid spinning solution is guided via an air gap, stretched in the process, and collected in an aqueous coagulation bath. The optically anisotropic aramid spinning solution in the spinneret arrangement is fed to the spinning orifices via a flow resistor. The flow resistor is arranged closer to the spinning orifices than the filter, and the flow resistor and the filter are arranged at a distance to one another. The method may also include a para-aromatic polyamide filament yarn.12-08-2011
20110268962ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE COMPRISING REFRACTORY PARTICLES - Ultra-high molecular weight polyethylene including 0.001 to 10 weight % of refractory particles, wherein the refractory particles have an average particle size (D50) below 300 nm. The average particle size is at least 5 nm, in particular at least 10 nm, and/or at most 150 nm, in particular at most 100 nm, more in particular at most 80 nm. The particles are of transformation toughened zirconia.11-03-2011
20110268952POLYETHYLENE FILM WITH HIGH TENSILE STRENGTH AND HIGH TENSILE ENERGY TO BREAK - An UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 6, and a film width of at least 5 mm. The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic shear modulus determined directly after melting at 160° C. of at most 1.4 MPa, and a Mw/Mn ratio of at most 6 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point. The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.11-03-2011
20110268951POLYETHYLENE FILM AND METHOD FOR THE MANUFACTURE THEREOF - The present invention pertains to a polyethylene film and a process for manufacturing such film. The polyethylene film may have a ratio between the strength in a first direction in the film plane and the strength in a second direction in the film plane perpendicular to the first direction in the range of 0.1-10:1, the strength in at least one direction being at least 0.2 Gpa. The process for manufacturing a polyethylene film may have a starting UHMWPE polymer with an average molecular weight of at least 500,000 grams/mole, an elastic shear modulus determined directly after melting at 160° C. of at most 1.4 MPa, and a Mw/Mn ratio of at most 6 to a solvent-free compacting process and a stretching process under such conditions that at no point during the process the temperature of the intermediate polymer film is raised to a value above its melting point.11-03-2011
20110162517BALLISTIC RESISTANT ARTICLES COMPRISING ELONGATE BODIES - A ballistic-resistant moulded article having a compressed stack of sheets including reinforcing elongate bodies, where at least some of the elongate bodies are polyethylene elongate bodies that have a weight average molecular weight of at least 100,000 gram/mole and a Mw/Mn ratio of at most 6. Methods for manufacturing ballistic-resistant moulded articles are also provided.07-07-2011
20110140301PROCESS FOR PRODUCING A PLURALITY OF HIGH-STRENGTH, HIGH MODULUS AROMATIC POLYAMIDE FILAMENTS - A process for producing a plurality of high strength, high modulus aromatic polyamide filaments that includes extruding an acid solution containing at least 15% by weight of an aromatic polyamide through linearly arranged orifices in a spinneret to provide a warp of filaments, passing the warp of filaments through a layer of non-coagulating fluid into a coagulation bath and subsequently passing the warp through a spin tube, the spin tube having an elongated cross section with at least two opposite sides being parallel to the filament warp with the length of these sides being at least as long as the width of the filament warp, jetting additional coagulating liquid at a constant flow rate about the filaments in a downward direction at an angle between 15° and 75° with respect to the filaments, the jetted coagulating liquid moving downward with the warp of filaments through the spin tube at a velocity of about 50% to 100% of the velocity of the filaments, the coagulating liquid being jetted through a jet channel from either one side of the spin tube which is parallel to the filament warp, and the jet channel having at least the same width as the filament warp.06-16-2011
20110124835METHOD FOR MANUFACTURING HIGH MOLECULAR WEIGHT POLYETHYLENE FIBERS - A process for manufacturing high molecular weight polyethylene fibers, including subjecting a polyethylene tape with a weight average molecular weight of at least 500,000 grams/mole, a Mw/Mn ratio of at most 6, and a 200/110 uniplanar orientation parameter of at least 3 to a force in the direction of the thickness of the tape over the entire width of the tape. A polyethylene fiber having a Mw of at least 500 000 gram/mole, a Mw/Mn ratio of at most 6, and a 020 uniplanar orientation value of at most 55°.05-26-2011
20110095447PROCESS FOR MANUFACTURING POLYOLEFIN FILMS - A process for manufacturing a film of ultra-high molecular weight polyolefin comprising: (a) subjecting a starting ultra-high molecular weight polyolefin with a weight average molecular weight of at least 500 000 gram/mole in powder form to a compacting step using an isobaric press: and (b) subjecting the compacted polyolefin to a rolling step and at least one stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point. The process allows for the manufacture of ultra-high molecular weight polyolefin films of high quality.04-28-2011
20110083820PAPER COMPRISING POLYBENZAZOLE OR PRECURSOR THEREOF - The invention relates to a paper comprising at least one of a fiber, pulp, fibril, floc, and fibrid having a polybenzazole structure with a repeating unit of formula (I) and/or (II)04-14-2011
20110041677BALLISTIC-RESISTANT ARTICLES COMPRISING TAPES - Ballistic-resistant moulded article comprising a compressed stack of sheets comprising tapes of a reinforcing material, characterised in that at least one sheet comprises woven tapes as weft and as warp, at least some of the tapes having a width of at least 10 mm. A method for manufacturing the ballistic-resistant moulded article is also claimed.02-24-2011
20110034666CROSSLINKED ARAMID POLYMER - A crosslinked aramid polymer comprising a first aramid backbone which is crosslinked through a poly(meth)acrylic acid with a second aramid backbone. The crosslinked aramid polymer is obtained by polymerizing a monomeric aromatic diamine with a monomeric aromatic diacid, or halide or ester thereof in the presence of poly(meth)acrylic acid, followed by a curing step. The crosslinked aramid polymer is crosslinked through its amide bonds and can be made to a fiber, film or fibrid.02-10-2011
20110020593BALLISTIC RESISTANT ARTICLES COMPRISING ELONGATE BODIES - A ballistic-resistant moulded article comprising a compressed stack of sheets comprising reinforcing elongate bodies and an organic matrix material, the direction of the elongate bodies within the compressed stack being not unidirectionally, wherein the elongate bodies are tapes with a width of at least 2 mm and a thickness to width ratio of at least 10:1 with the stack comprising 0.2-8 wt. % of an organic matrix material.01-27-2011
20100319139Method for Spinning and Washing Aramid Fiber and Recovering Sulfuric Acid - A method for spinning and washing aramid fiber and for recovering sulfuric acid by (a) spinning an aramid polymer from a sulfuric acid spin dope to a yarn and coagulating the yarn in a coagulation bath having an inlet for water or diluted sulfuric acid and an outlet for sulfuric acid enriched water; (b) washing the yarn with water to obtain a washed yarn and a washing water containing sulfuric acid; (c) recycling the sulfuric acid enriched water and optionally the washing water to a sulfuric acid recovery unit; (d) increasing the sulfuric acid content of the recycled sulfuric acid enriched water, and optionally the washing water, by evaporation to obtain 20 to 98% sulfuric acid and water; (e) mixing the 20 to 98% sulfuric acid with oleum to obtain 98-105% sulfuric acid; and (f) recycling the 98-105% sulfuric acid to the spinning unit for use as sulfuric acid spin dope.12-23-2010
20100292398ARAMID PARTICLES CONTAINING PEROXIDE RADICAL INTIATOR - An aramid particle containing a peroxide radical initiator wherein the particle contains 3-40 wt % peroxide radical initiator based on the weight of the aramid particle. Also, disclosed is a particle-elastomer composition having 100 parts by weight of at least one natural or synthetic elastomer, such as rubber; 0.1 to 20 parts by weight of a peroxide or 0.1 to 25 parts by weight of sulfur, an amount of a sulfur donor providing the equivalent of 0.1 to 25 parts by weight of sulfur, or a mixture of sulfur and a sulfur donor to an equivalent total of 0.1 to 25 parts by weight of sulfur; and 0.1 to 20 parts by weight of the aramid particle.11-18-2010
20100266247FLEXIBLE CONTINUOUS TAPE FROM MULTIFILAMENT YARN AND METHOD FOR MAKING THESE - A method for making a flexible fibrous continuous tape containing 60 to 98 wt % fiber based on the weight of the tape, from multifilament yarn selected from aramid, glass, aromatic polyester, and rigid rod polymer, comprising the steps: a1) spreading the filaments of the yarn to obtain a filament layer having a cross sectional aspect ratio (w/h) of 2 to 2000; and b1) treating the spread filaments with a curable resin, or a liquid thermoplastic resin or wax; or a2) treating the yarn with the curable resin, or the liquid thermoplastic resin or wax; and b2) spreading the filaments of the yarn to obtain a filament layer having a cross sectional aspect ratio (w/h) of 2 to 2000; followed by c) fixating the filaments by curing or solidifying the resin to obtain the tape, wherein steps a1-b1, respectively a2-b2, and c are performed in-line.10-21-2010
20100234496NON-FIBROUS POLYMER SOLUTION OF PARA-ARAMID WITH HIGH RELATIVE VISCOSITY - The invention relates to a non-fibrous polymer solution essentially consisting of 1 to 8 wt. % para-aramid, at least 50 mole % of the aromatic moieties thereof being unsubstituted, in a mixture of a) a polar amide solvent selected from N-methyl-2-pyrrolidone, N,N′-dimethyl-formamide, N,N′-dimethylacetamide, tetramethylurea, and mixtures thereof; b) between 0.7 mole of an alkali or earth alkali chloride per mole amide groups of the para-aramid and 7.5 wt. % of the alkali or earth alkali chloride, and c) water; and wherein at least 50 wt. % of the formed hydrochloric acid has been neutralized to obtain a solution having a dynamic viscosity which is at least a factor three smaller than the dynamic viscosity of the polymer solution without neutralization. The invention further pertains to a process making the same and para-aramid pulp-like fiber, paper and film made from said polymer solution.09-16-2010
20100154378METHOD FOR PREVENTING YARN BREAKAGE - The invention pertains to the use of a multifilament yarn spinning process comprising individually washing each filament of a multifilament yarn and, if neutralized, individually neutralizing each filament of the multifilament yarn, for preventing yarn breakage during the spinning process, the spinning process comprising spinning of a polymer through a spinneret to obtain the multifilament yarn, washing the yarn, and optionally neutralizing and/or drying the yarn and winding the yarn onto a bobbin Preferably the yarn is washed with jet washers.06-24-2010
20100144224POLYETHYLENE FILM WITH HIGH TENSILE STRENGTH AND HIGH TENSILE ENERGY TO BREAK - The present invention pertains to a UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 6. The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic shear modulus determined directly after melting at 160° C. of at most 0.9 MPa, and a Mw/Mn ratio of at most 6 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point. The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.06-10-2010
20100089018METHOD FOR PREVENTING DEPOSIT FORMING ON GUIDE ROLLERS - The invention relates to a method for preventing or reducing deposit forming of superabsorbent material and/or oil onto guide rollers during the process of applying a superabsorbent water-in-oil emulsion onto a yarn wherein the oil is a mixture comprising saturated hydrocarbons, characterized in that the at least 70 wt % of the hydrocarbons have 20 to 32 carbon atoms.04-15-2010
20100076151PARTICLE COMPRISING A MATRIX AND A RADICAL INITIATOR - The invention pertains to a particle comprising a composition containing a matrix and a peroxide or azo radical initiator, wherein the particle is a fiber or fibrid selected from aramid, polyester, polyimide, cellulose, and glass. The invention further relates to particle-elastomers comprising said composition, and skim products, tires, tire treads, and belts comprising these particle-elastomers.03-25-2010
20100063205METHOD FOR DISSOLVING ARAMID POLYMER IN SULFURIC ACID USING A DOUBLE SHAFT KNEADER - A method for dissolving an aramid polymer in sulfuric acid using a double shaft kneader, comprising the steps: dosing the polymer and the solvent into the kneader, mixing the polymer and the solvent to dissolve the polymer in the solvent for obtaining a solution, degassing the solution to obtain a spin dope, and transporting the spin dope out of the kneader, wherein the polymer is an aramid polymer and the solvent is sulfuric acid, and whereby the aramid polymer is dosed into the kneader prior to dosing the sulfuric acid into the kneader.03-11-2010
20100056731PARTICLES COMPRISING COMPOSITE OF PARA-ARAMID AND ADDITIVE MATERIAL - The invention pertains to a method for making a polymer-additive composite particle from a dope by jet spinning the dope to obtain a pulp, fibril or fibrid, wherein the solvent of the dope is selected from N-methyl-2-pyrrolidone, N,N′-dimethylformamide, N,N′-dimethylacetamide, tetramethylurea, and 4 to 75 wt % of a composition consisting of 2 to 95 wt % of a para-aramid polymer and 5-98 wt % of a solid additive material, to a total of 100 wt %, and wherein the aramid polymer is dissolved in the solvent; or coagulating the dope by means of a rotor-stator apparatus in which the polymer solution is applied through the stator on the rotor so that the precipitating polymer-additive composite particle is subjected to shear forces while they are in a plastic deformable stage.03-04-2010
20100041793PARTICLE-MATRIX COMPOSITION COATED WITH MIXTURE COMPRISING POLYSULFIDE POLYMER - The invention pertains to a composition comprising a particle and a matrix, wherein the particle is at least partially coated with a compound or a mixture of compounds a cured polysulfide polymer obtained from a polysulfide polymer having at least two epoxy end groups.02-18-2010
20100036007FOAM OF POLYMERS - The disclosure pertains to foam of polymers, which can be made by a method for making a polymer foam comprising vacuum or gas-filled compartments by making a solution of 1 to 20% by weight of a polymer in a solvent; adding particles to the a polymer solution; solidifying the polymer wherein the particles are contained by heating, cooling, ageing, or coagulating to obtain a polymer foam or matrix comprising the particles, and obtaining from the polymer matrix the polymer foam containing the compartments; and optionally washing, drying, and/or heating the polymer foam.02-11-2010
20100001433Method for obtaining high-tenacity aramid yarn - The invention relates to a method for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising DAPBI, an aromatic para-diamine, and an aromatic para-diacid, wherein the yarn is heated in at least two process steps, characterized in that in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex. The invention further pertains to a multifilament aramid yarn spun from a sulfuric acid spin dope and having a tenacity of at least 2500 mN/tex.01-07-2010
20090318660CROSSLINKABLE ARAMID COPOLYMERS - The invention pertains to an aramid copolymer composition comprising an aramid copolymer having at least one arylene carboxylic acid moiety and at least one hydroxyarylene moiety, or comprising an aramid copolymer having at least one arylene carboxylic acid moiety or having at least one hydroxyarylene moiety, and a crosslinker agent. The invention further relates to crosslinked copolymers derived thereof and shaped articles comprising said crosslinked copolymers.12-24-2009
20090285537Antitracking Aramid Yarn - The invention pertains to an aramid filament yarn provided with a finish composition comprising an organic substance, the amount of organic substance in the finish being selected so that the finish has a conductivity from 0.2 mS/cm to 200 mS/cm, measured as a 50 wt % finish composition in water at 20° C., and the amount of the finish on the yarn being selected so that the yarn has a specific electric resistance from 4×104 to 1.2×107 Ohm.cm. The invention further pertains to an ADSS cable reinforced with bundles of said aramid filament yarn, and to a method for making the ADSS cable.11-19-2009
20090258988Composition Comprising Sulfurized Particles - The invention pertains to a composition comprising a particle and a matrix, the particle being at least partially coated with a composition comprising: a) a Bunte salt (A); b) a polysulfide (B) comprising the moiety —[S]10-15-2009
20090252960Composite materials comprising PPTA and nanotubes - Disclosed is a composite material comprising PPTA (poly-p-phenyleneterephthalamide) and nanotubes having an aspect ratio of at least 100 and a cross-sectional diameter of 5 nm or less, the composite material containing up to 12 wt. % of nanotubes, obtainable by adding the nanotubes to sulfuric acid, decreasing the temperature to solidify the mixture, adding PPTA to the solid mixture, heating to above the solidifying point and mixing the mixture, and spinning, casting, or molding the mixture to the composite material.10-08-2009
20090166453Process for Yarn or Sliver Refining - The invention discloses a process for refining yarn or sliver having a length of at least 1 meter, comprising the step of feeding the yarn or sliver and a liquid into a refiner, which comprises refiner fillings having a body surrounding a central hole (07-02-2009
20080251965Method for Improving Filament Cohesiveness of Chopped Aramid Fiber - The invention pertains to a method for improving filament cohesiveness of chopped aramid fiber including the steps of impregnating a film-forming binding agent into the fiber, drying the fiber, optionally applying a finish to the fiber, and chopping the fiber to pieces of 1 to 16 mm length, characterized in that the fiber prior to applying the binding agent is subjected to a twisting process to obtain a fiber having a twisting level of 10 to 150 tpm and that the chopping of the fiber is performed in a rotary chopper.10-16-2008

Patent applications by TEIJIN ARAMID B.V.