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Shanghai HuaYi Acrylic Acid Co. Ltd.

Shanghai HuaYi Acrylic Acid Co. Ltd. Patent applications
Patent application numberTitlePublished
20120135856PROCESS FOR REGENERATING A DEACTIVATED HETEROPOLYMOLYBDOPHOSPHORIC ACID CATALYST - The present invention provides a process for regenerating a deactivated heteropolymolybdophosphoric acid catalyst, comprising the steps of grinding the deactivated catalyst into particles having a particle size of 40 mesh or less, mixing the particles with a mixture comprising aqua ammonia, which is an aqueous solution containing ammonium ions and organic auxiliaries, kneading the mixture of particles and aqua ammonia in a kneader to obtain a paste, drying the paste, molding the paste into cylindrical particles with a through hole in its longitudinal axis, and heating the paste in atmosphere at 350˜450° C. for 1˜10 hours to produce the generated catalyst.05-31-2012
20110295041CATALYST FOR PRODUCING UNSATURATED ALDEHYDE BY OXIDATION OF LOWER OLEFIN AT HIGH SPACE VELOCITY - A method of preparing a catalyst for producing acrolein by oxidation of propylene at high space velocity, said catalyst is a Mo—Bi—Fe—Co based composite metal oxide. Producing unsaturated aldehyde via partial oxidation of lower unsaturated olefin at high space velocity using said catalyst is suitable for process with or without off-gas recirculating. Said catalyst is prepared by co-precipitation, the reaction conditions for using said catalyst to produce unsaturated aldehyde are, the space velocity of unsaturated lower olefin relative to catalyst being 120˜200 h-1(STP), reaction temperature being 300˜420° C. and absolute pressure being 0.1˜0.5 MPa; a single-stage unsaturated lower olefin conversion ratio of greater than 98.0% and carbon oxide yield of less than 3.3% with an overall yield of unsaturated lower aldehyde and acid of greater than 94.0% are obtained. The process to prepare the said catalyst is simple, easy to be repeated, and capable of industrial scale-up.12-01-2011