| Fina Technology, Inc. Patent applications |
| Patent application number | Title | Published |
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| 20120124897 | Propellant Compositions and Methods of Making and Using the Same - Formulated propellants and methods of forming the same are described herein including a method of manufacturing a rocket propellant comprising combining at least two hydrocarbon fluids. | 05-24-2012 |
| 20120123068 | NOVEL COMBINATIONS OF SILANE ELECTRON DONORS FOR USE IN CATALYST COMPOSITIONS - Disclosed is a process for preparing an olefinic polymer comprising contacting at least one olefinic C3+ monomer and a catalyst composition comprising a Ziegler-Natta catalyst, dicyclopentyl dimethoxysilane as a first electron donor, and a second electron donor selected from the group consisting of methyl trimethoxysilane, methyl triethoxysilane, dimethyl dimethoxysilane, and mixtures thereof, under reaction conditions suitable to form an olefinic polymer. The polymer prepared using this method may exhibit significantly broadened molecular weight distribution than that achieved using any of the silane compounds alone, and may also exhibit desirable melt flow characteristics and xylene solubles levels. | 05-17-2012 |
| 20120116033 | Catalyst Components, Process for Their Preparation and Their Use as Catalyst Components in Polymerization of Olefins - Catalyst compositions having Cs symmetry and processes utilizing Cs symmetric catalyst components for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Monomers, which are polymerized or copolymerized include ethylene, C | 05-10-2012 |
| 20120108873 | Catalysts Containing Nano-Materials and Methods of Making and Using Same - A method of making a catalyst containing nanosize zeolite particles supported on a support material is disclosed. A process for making styrene or ethylbenzene by reacting toluene with a C | 05-03-2012 |
| 20120108863 | Depolymerizatin of Plastic Materials - A styrene monomer reclamation process and system is disclosed. The styrene monomer reclamation process includes providing a waste plastic. The waste plastic includes styrenic polymers. The waste plastic is formed into polymer particles. At least a portion of the polymer particles are dissolved in a solvent to form a polymer stream. The dissolved polymer particles are depolymerized to form a styrene monomer stream. | 05-03-2012 |
| 20120108771 | SUCCINATE-CONTAINING POLYMERIZATION CATALYST SYSTEM USING BMDS FOR PREPARATION OF POLYPROPYLENE FILM GRADE RESINS - It has been discovered that using n-butylmethyldimethoxysilane (BMDS) as an external electron donor for succinate-containing Ziegler-Natta catalysts can provide a catalyst system that may prepare polypropylene films with improved properties. The catalyst systems of the invention provide for controlled chain defects/defect distribution and thus a regulated microtacticity along with broadened molecular weight distribution. | 05-03-2012 |
| 20120108769 | MULTI-COMPONENT CATALYST SYSTEMS INCLUDING CHROMIUM BASED CATALYSTS AND POLYMERIZATION PROCESSES FOR FORMING POLYOLEFINS - Polymerization processes and polymers formed therefrom are described herein. The polymerization processes generally include contacting ethylene and propylene with a multi-component catalyst composition including a first catalyst component including a chromium oxide based catalyst and a second catalyst component selected from metallocene and Ziegler-Natta catalysts within a polymerization reaction vessel to form a random copolymer, wherein the second catalyst component exhibits a higher comonomer response than the first catalyst component. | 05-03-2012 |
| 20120108747 | Methods of Making High Impact Polystyrene - A process for producing high impact polystyrene including feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture. Polymerizing the reaction mixture in the first linear flow reactor to a point below the point at which phase inversion occurs to produce a first polymerization mixture and feeding the first polymerization mixture from the first linear flow reactor to a second linear flow reactor. Polymerizing the reaction mixture in the second linear flow reactor to at least a phase inversion point of the mixture to produce a second polymerization mixture and feeding the second polymerization mixture from the second linear flow reactor to at least a third linear flow reactor for post-inversion polymerization of the second polymerization mixture. The product stream can have an ESCR value of at least 10% toughness retained with less than 10 wt % rubber content. | 05-03-2012 |
| 20120107199 | Processes for Reduction of Alkylation Catalyst Deactivation Utilizing Stacked Catalyst Bed - Alkylation systems and methods of minimizing alkylation catalyst regeneration are discussed herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a first preliminary alkylation catalyst disposed therein to form a first output stream. The first preliminary alkylation catalyst generally includes a Y zeolite. The systems further include a first alkylation system adapted to receive the first output stream and contact the first output stream with a first alkylation catalyst disposed therein and an alkylating agent to form a second output stream. | 05-03-2012 |
| 20120095250 | CATALYST WITH AN ION-MODIFIED BINDER - A solid catalyst, such as a molecular sieve catalyst or solid acid catalyst, is supported by a binder, such as amorphous silica or alumina, wherein the binder is charged with metal ions to form an ion-modified binder. The ion-modified binder is capable of attachment to polar contaminants and inhibit their contact with the catalyst. The catalyst can be a zeolite and can be the catalyst for an alkylation reaction, such as the alkylation of benzene with ethylene. | 04-19-2012 |
| 20120095175 | PREPARATION AND USE OF TETRASUBSTITUTED FLUORENYL CATALYSTS FOR POLYMERIZATION OF OLEFINS - Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. The polymerization catalyst characterized by the formula B(FluL)MQ | 04-19-2012 |
| 20120095174 | Fluorinated Catalyst Systems and Methods of Forming the Same - Supported catalyst systems and methods of forming the same are described herein. In one specific embodiment, the methods generally include providing an inorganic support material and contacting the inorganic support material with an aluminum fluoride compound represented by the formula AlF | 04-19-2012 |
| 20120095155 | MODIFIED RESINS FOR BLOWN FILM - Processes for enhancing blown film processability and the blown films formed thereby are described herein. One embodiment of the processes generally includes providing a first propylene based heterophasic copolymer having a first melt flow rate, modifying the first propylene based heterophasic copolymer to form a second heterophasic polymer having a second melt flow rate, wherein the second melt flow rate is greater than the first melt flow rate, contacting the first heterophasic polymer, the second heterophasic copolymer or a combination thereof with a plurality of additives, wherein the plurality of additives include a nucleator, polyethylene and mineral oil to form a modified heterophasic copolymer and blowing the modified heterophasic polymer into a film. | 04-19-2012 |
| 20120091621 | BIMODAL PIPE RESIN AND PRODUCTS MADE THEREFROM - Disclosed is a bimodal Ziegler-Natta catalyzed polyethylene, having a density of from 0.930 glee to 0.960 glee, and a molecular weight distribution of from 10 to 25, wherein an article formed therefrom has a PENT of at least 1500. Also disclosed is a method of preparing a tubular article including obtaining a bimodal polyethylene having a density of from 0.930 glee to 0.960 Wee and a molecular weight distribution of from 10 to 25, and processing the polyethylene under conditions where a specific energy input (SET) is less than 300 kW.h/ton, and wherein the article has a PENT of at least 1500. Further disclosed is a method for controlling the degradation of polyethylene including polymerizing ethylene monomer, recovering polyethylene, extruding the polyethylene, and controlling the degradation of polyethylene by measuring the SEI to the extruder and adjusting throughput and/or gear suction pressure keep SEI less than 300 kW.h/ton, and forming an article. | 04-19-2012 |
| 20120083405 | Ziegler-Natta Catalyst Systems and Polymers Formed Therefrom - Processes of forming catalyst systems, catalyst systems and polymers formed therefrom are described herein. The processes generally include providing a first compound including a magnesium dialkoxide, contacting the first compound with a second compound to form a solution of reaction product “A”, wherein the second compound is generally represented by the formula: | 04-05-2012 |
| 20120080822 | Compatibilized Polypropylene and Polylactic Acid Blends and Methods of Making and Using Same - A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %. | 04-05-2012 |
| 20120078025 | USE OF A DIRECT HEATING DEVICE WITH A REHEATER IN A DEHYDROGENATION UNIT - Methods and processes for increasing the efficiency and/or expanding the capacity of a dehydrogenation unit by use of at least one direct heating unit are described. | 03-29-2012 |
| 20120078024 | Removal of Hydrogen From Dehydrogenation Processes - A process and system for dehydrogenating certain hydrocarbons is disclosed. The process includes contacting a dehydrogenatable hydrocarbon with steam in the presence of a dehydrogenation catalyst to form hydrogen and a dehydrogenated hydrocarbon. Some of the hydrogen is then removed and some of the remaining dehydrogenatable hydrocarbon is dehydrogenated. | 03-29-2012 |
| 20120071317 | TOLUENE DISPROPORTIONATION USING Nb/MORDENITE CATALYST - A molecular sieve catalyst useful in the conversion of hydrocarbons containing niobium is disclosed, along with a process for the disproportionation of toluene to benzene and xylene using such catalyst. | 03-22-2012 |
| 20120065334 | POLYMERIC BLENDS FOR SLIT FILM APPLICATIONS AND METHODS OF MAKING THE SAME - Films and processes of forming the same are described herein. The processes generally include providing a propylene-based polymer; contacting the propylene-based polymer with polylactic acid in the presence of a modifier to form a polymeric blend, wherein the modifier is selected from epoxy-functionalized polyolefins, maleic anhydride modified polyolefins, ethylene-methacrylate copolymers, styrene-ethylene-butadiene-styrene (SIBS) polymers, and combinations thereof; forming the polymeric blend into a film; and monoaxially orienting the film. | 03-15-2012 |
| 20120065333 | CROSSLINKABLE HIGH MELT STRENGTH POLYPROPYLENE RESINS - Crosslinkable silane-grafted polypropylene compositions and processes of forming the same are described herein. The processes generally include contacting a polyolefin, a multifunctional monomer and a silane compound in the presence of a radical initiator, wherein the polyolefin is selected from polypropylene, polyethylene, combinations thereof and copolymers thereof. | 03-15-2012 |
| 20120064268 | Process for Controlling Morphology of Ziegler-Natta Catalysts - Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. The process enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. | 03-15-2012 |
| 20120059206 | PROCESS FOR PRODUCTION OF ETHYLBENZENE FROM TOLUENE AND METHANE - A process for making ethylbenzene and/or styrene by reacting toluene with methane is disclosed. In one embodiment the process can include reacting toluene with methane to form a product stream comprising ethylbenzene and further processing the ethylbenzene to form styrene in an existing styrene production facility. | 03-08-2012 |
| 20120059077 | LOW MELT FLOW BRANCHED IONOMERS - Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: | 03-08-2012 |
| 20120046508 | PROCESS FOR TOLUENE AND METHANE COUPLING IN A MICROREACTOR - A process for making ethylbenzene and/or styrene by reacting toluene with methane in one or more microreactors is disclosed. In one embodiment a method of revamping an existing styrene production facility by adding one or more microreactors capable of reacting toluene with methane to produce a product stream comprising ethylbenzene and/or styrene is disclosed. | 02-23-2012 |
| 20120046429 | Sequential Formation of Ziegler-Natta Catalyst Using Non-blended Components - Catalyst compositions, methods of forming the same and polymers formed therefrom are described herein. The methods of forming the catalysts generally include contacting an alkyl magnesium compound with a viscosity modifier prior to contact with an alcohol to form a magnesium dialkoxide compound; contacting the magnesium dialkoxide compound with a first titanium alkoxide and a first agent to form a first solution reaction product “A”, wherein the titanium alkoxide and the first agent are non-blended individual components prior to contacting the magnesium dialkoxide; contacting the first solution reaction product “A” with a second titanium alkoxide to form a second solution reaction product “B”; contacting the second solution reaction product “B” with a second agent to form a first solid reaction product “C”; contacting the first solid reaction product “C” with a third agent to form a second solid reaction product “D”; and contacting the second solid reaction product “D” with a reducing agent to limn a catalyst component. | 02-23-2012 |
| 20120046427 | "GREEN" PLASTIC MATERIALS AND METHODS OF MANUFACTURING THE SAME - A process is disclosed for producing plastic materials by providing a biology based feedstock and reacting the biology based feedstock to form a feedstock capable of reaction to form the plastic material, wherein the plastic material is selected from polystyrene and polyethylene terephthalate (PET). | 02-23-2012 |
| 20120034838 | Polymeric Blends for Fiber Applications and Methods of Making the Same - Processes of forming a fiber article and articles formed therefrom are described herein. The processes generally include providing a propylene-based polymer; contacting the propylene-based polymer with polylactic acid in the presence of a reactive modifier, a non-reactive modifier or a combination thereof to form a polymeric blend, wherein the reactive modifier is selected from epoxy-functionalized polyolefins and the non-reactive modifier comprises an elastomer; and forming the polymeric blend into a fiber article. | 02-09-2012 |
| 20120010376 | Multi-Component Catalyst Systems and Polymerization Processes for Forming Broad Composition Distribution Polymers - Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst. | 01-12-2012 |
| 20110319687 | Method for Production of Styrene from Toluene and Syngas - A method for the production of styrene comprising reacting toluene and syngas in one or more reactors is disclosed. | 12-29-2011 |
| 20110313118 | FLUORINATED IMPREGNATED CATALYST SYSTEMS AND METHODS OF FORMING THE SAME - Methods of forming supported catalyst systems, supported catalyst systems and polymerization processes utilizing the supported catalyst systems are described herein. The methods generally include providing an inorganic support material and contacting the inorganic support material with a support solvent to form a support solution. The methods further include contacting the support solution with a fluorine containing compound represented by the formula AlF | 12-22-2011 |
| 20110313116 | Polymerization Process Utilizing Hydrogen - Ethylene polymerization processes and polymers formed from the same are discussed herein. The ethylene polymerization processes generally include introducing ethylene monomer into a polymerization reaction zone; introducing a chromium oxide based catalyst into the polymerization reaction zone; introducing a quantity of hydrogen into the polymerization reaction zone; and contacting the ethylene monomer with the chromium oxide based catalyst in the polymerization reaction zone in the presence of hydrogen to form polyethylene, wherein the polyethylene formed in the presence of hydrogen exhibits an MI | 12-22-2011 |
| 20110313104 | Polypropylene Compositions for Oriented Films - Oriented films and methods of forming the same are discussed herein. The oriented films generally include a propylene based polymer and an additive selected from fluoropolymers, fluoroelastomers and combinations thereof, wherein the additive is present in an amount of from about 50 ppm to about 20,000 ppm. | 12-22-2011 |
| 20110306813 | Dilute Ethylene Alkylation of Benzene - Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a reaction zone containing a gaseous phase and recovering ethylbenzene from the reaction zone. | 12-15-2011 |
| 20110306689 | Expandable Polystyrene and Methods of Forming the Same - Expanded polystyrene, foamed articles and methods of making the same are described herein. The expanded polystyrene generally includes polystyrene selected from expandable polystyrene and extrusion polystyrene, the polystyrene exhibiting a molecular weight of from about 130,000 Daltons to about 220,000 Daltons; a melt flow index of from about 20 to about 30 and a density of from about 0.1 lb/ft | 12-15-2011 |
| 20110306684 | CHEMICAL PRODUCTION PROCESSES UTILIZING SYNGAS FROM PLASMA PYROLYSIS - Chemical production processes are described herein. The chemical production processes generally include providing municipal solid waste; subjecting the municipal solid waste to plasma pyrolysis to form an intermediate for chemical production, wherein the intermediate includes carbon monoxide and hydrogen; and transferring the intermediate from the plasma pyrolysis to a chemical or liquid fuel production process. | 12-15-2011 |
| 20110305857 | MODIFIED POLYPROPYLENE FOR PACKAGING APPLICATIONS - Methods of forming a clear packaging container, polymers for use therein and packaging containers are described herein. The methods generally include providing a propylene based polymer formed from a metallocene catalyst; blending the propylene based polymer with a nonitol-based clarifying agent to form clarified polypropylene; and forming the clarified polypropylene into a packaging container, wherein the packaging container exhibits a gloss that is at least 6% greater than a container formed from a Ziegler-Natta formed propylene based polymer blended with the clarifying agent. | 12-15-2011 |
| 20110301396 | PROCESSES FOR THE REDUCTION OF ALKYLATION CATALYST DEACTIVATION UTILIZING LOW SILICA TO ALUMINA RATIO CATALYST - Alkylation systems and methods of minimizing alkylation catalyst regeneration are described herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a preliminary alkylation catalyst disposed therein to form a first output stream. The preliminary alkylation catalyst generally includes a zeolite catalyst having a SiO | 12-08-2011 |
| 20110295048 | Rhenium Promoted Catalyst - A group V metal/rhenium-modified molecular sieve catalyst can be used in hydrocarbon conversion reactions. Embodiments can provide a toluene conversion of at least 30 wt % with selectivity to benzene above 40 wt % and to xylenes above 40 wt % and non-aromatics selectivity of less than 2.0 wt %. | 12-01-2011 |
| 20110278201 | Stacked Bed Hydrotreating Reactor System - Methods and systems for diesel formation are described herein. The diesel hydrotreating systems generally include a hydrodesulfurization unit having a catalyst system disposed therein and adapted to contact an input stream with the catalyst system therein to form diesel. The catalyst system generally includes a plurality of catalysts including a first catalyst including a hydrodesulfurization catalyst having a first pore diameter and a second catalyst having a second pore diameter, wherein the second pore diameter is larger than the first pore diameter. | 11-17-2011 |
| 20110275771 | LOOP REACTOR DESIGN - Loop reactors are described herein. The loop reactors generally include a lower horizontal segment, an upper horizontal segment and a vertical segment in operable communication and an in-line pump incorporated within the loop reactor. | 11-10-2011 |
| 20110275509 | ZIEGLER-NATTA CATALYST - The present invention relates generally to catalysts, to methods of making catalysts, to methods of using catalysts, to methods of polymerizing, and to polymers made with such catalysts. More particularly, the present invention relates to polyolefin catalysts and to Ziegler-Natta catalysts, to methods of making such catalysts, to methods of using such catalysts, to polyolefin polymerization, and to polyolefins. | 11-10-2011 |
| 20110270007 | Catalyst with an Ion-Modified Binder - An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst. | 11-03-2011 |
| 20110270006 | Use of an Additive in the Coupling of Toluene with a Carbon Source - A method is disclosed of preparing a catalyst, including contacting a substrate with at least one solution including a first promoter being Cs and at least one solution including a second promoter. The contact subjects the substrate to the addition of the first and second promoters, thereby forming the catalyst comprising the first and second promoters. In the method disclosed, the second promoter is capable of undergoing a redox reaction. | 11-03-2011 |
| 20110269923 | MULTI-COMPONENT CATALYST SYSTEMS AND POLYMERIZATION PROCESSES FOR FORMING IN-SITU HETEROPHASIC COPOLYMERS AND/OR VARYING THE XYLENE SOLUBLES CONTENT OF POLYOLEFINS - Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCp | 11-03-2011 |
| 20110269877 | ASPHALT COMPOSITIONS AND THE PREPARATION THEREOF - Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications. | 11-03-2011 |
| 20110267920 | Method and Apparatus for Controlling Residence Time Distribution in Continuous Stirred-Tank Reactors - The present invention includes an apparatus and method for narrowing the residence time distribution of a continuous stirred-tank reactor, or CSTR, which includes the optional procedures of: decreasing the vertical cross-sectional area of the reactor's agitator blades; decreasing the RPM of the agitator blades; and increasing the reactor's L/D ratio. The CSTR can be used in the production of monovinylidene aromatic polymers, such as high impact polystyrene. | 11-03-2011 |
| 20110263802 | Formation of Ziegler-Natta Catalyst Using Non-blended Components - Methods of forming a catalyst, catalysts, polymerization processes and polymers formed therefrom are described herein. The method of forming a catalyst generally includes contacting an alkyl magnesium compound with an alcohol to form a magnesium alkoxide compound; contacting the magnesium alkoxide compound with a first titanium alkoxide and a first agent to form a reaction product “A”, wherein the titanium alkoxide and the first agent are nonblended individual components prior to contacting the magnesium alkoxide; and sequentially contacting the reaction product “A” with a second agent, followed by a third agent, and subsequently a first reducing agent to form a catalyst component. | 10-27-2011 |
| 20110257454 | Use of an Additive in the Coupling of Toluene with a Carbon Source - A method is disclosed of preparing a catalyst including providing a substrate and a first solution containing at least one promoter, contacting the substrate with the solution to obtain a catalyst containing at least one promoter, wherein the contacting of the substrate with the solution subjects the substrate to the addition of at least one promoter. | 10-20-2011 |
| 20110257453 | Reactors and Processes for the Oxidative Coupling of Hydrocarbons - A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst. | 10-20-2011 |
| 20110257452 | Regenerable Composite Catalysts for Hydrocarbon Aromatization - A composite catalyst for aromatization of hydrocarbons includes a molecular sieve catalyst and metal dehydrogenation catalyst present as discrete catalysts in a physical admixture. The molecular sieve catalyst can be a zeolite and the metal dehydrogenation catalyst can be in the form of a nanostructure, such as zinc oxide nanopowder. The catalyst can convert hydrocarbon feedstocks, such as alkanes and alkenes, to aromatics and can be regenerated in-situ. | 10-20-2011 |
| 20110257451 | Alkylation of Toluene to Form Styrene and Ethylbenzene - A process is disclosed for making styrene and/or ethylbenzene by reacting toluene with a C1 source over a catalyst in one or more reactors to form a product stream comprising styrene and/or ethylbenzene where the catalyst time on stream prior to regeneration is less than 1 hour. | 10-20-2011 |
| 20110257450 | Method of Coupling a Carbon Source with Toluene to Form a Styrene Ethylbenzene - A process is disclosed for making styrene or ethylbenzene by reacting toluene with a C1 source that is selected from the group consisting of methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, methylal, and combinations thereof. | 10-20-2011 |
| 20110253596 | Regenerable Composite Catalysts for Paraffin Aromatization - A composite catalyst for aromatization of paraffins includes a molecular sieve catalyst and metal dehydrogenation catalyst present as discrete catalysts in a physical admixture. The molecular sieve catalyst can be a zeolite and the metal dehydrogenation catalyst can be in the form of a nanoctructure, such as zinc oxide nanopowder. The catalyst can convert feedstocks such as LPG to aromatics and can be regenerated in-situ. | 10-20-2011 |
| 20110251346 | Biodegradable Polymeric Compositions and Methods of Making and Using the Same - Biodegradable polymeric compositions and processes for making such are described herein. The processes generally include providing an olefin based polymer selected from polypropylene, polyethylene, combinations thereof and copolymers thereof and contacting the olefin based polymer with polylactic acid in the presence of a reactive modifier to form the biodegradable polymeric composition, wherein the reactive modifier is selected from oxazoline-grafted polyolefins, maleated polyolefin-based ionomers, isocyanate-functionalized polyolefins and combinations thereof. | 10-13-2011 |
| 20110245568 | Dehydrogenation Reactions of N-Butene to Butadiene - A method for the dehydrogenation of n-butene to form butadiene over a dehydrogenation catalyst with a butadiene yield of at least 40 mol % is disclosed. Embodiments involve operating the dehydrogenation reactor at a pressure of 1,000 mbar or less. | 10-06-2011 |
| 20110245561 | Dehydrogenation of Alkyl Aromatics - Dehydrogenation of a reactor system of one or more vertically oriented flow reactors equipped with a system for introducing a catalyst extender into the inlet of the reactor. A vertically oriented radial flow reactor comprises inner and outer reactor tubes having perforated wall members extending longitudily of the reactor and defining an annulus containing a dehydrogenation catalyst. A supply line to the reactor is equipped with a rotation vane. An injection nozzle comprising a coaxial flow tube extends into the supply line downstream of the vane. The coaxial flow tube has an interior chamber and an annular chamber surrounding the interior chamber and extending into the supply line along with the interior chamber. The interior chamber is connected to a catalyst extender source and the annular chamber is connected to a source of a carrier gas which is effective to disperse the extender within feedstock flowing into the reactor. | 10-06-2011 |
| 20110245428 | Polystyrene Blends - A method of preparing a polystyrene blend that includes combining a first polystyrene composition having a first melt flow index with a second polystyrene composition having a second melt flow index and forming a polystyrene blend, the second melt flow index being at least 2 dg/min higher that the first melt flow index. The polystyrene blend has an observed tensile strength value greater than 3% above the expected tensile strength value. The second polystyrene composition can include a recycled polystyrene material, which can include expanded polystyrene. An alternate method of preparing the polystyrene blend includes combining a polystyrene composition with a styrene monomer to form a reaction mixture, polymerizing the reaction mixture and obtaining a polystyrene blend, where the polystyrene containing composition has a melt flow index at least 2 dg/min higher than the melt flow index of the styrene monomer after it has been polymerized. | 10-06-2011 |
| 20110244750 | Bicomponent Spunbond Fiber and Spunbond Fabric Prepared Therefrom - Bicomponent fibers, methods of forming bicomponent fibers and articles formed from bicomponent fibers, are described herein. The bicomponent fibers generally include a sheath component and a core component, wherein the sheath component consists essentially of a first metallocene polypropylene and the core component consists essentially of a second metallocene polypropylene. | 10-06-2011 |
| 20110207982 | PROCESS FOR ETHYLBENZENE PRODUCTION - A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can be regenerated and the regenerated H-beta zeolite catalyst can have a deactivation rate that is no more than 120% of the deactivation rate of a fresh H-beta zeolite catalyst. | 08-25-2011 |
| 20110207980 | Method for Production of Styrene from Toluene and Syngas - A method for the production of styrene comprising reacting toluene and syngas in one or more reactors is disclosed. | 08-25-2011 |
| 20110207898 | Method for Transitioning Between Ziegler-Natta and Metallocene Catalysts in a Bulk Loop Reactor for the Production of Polypropylene - Polymerization processes in a bulk loop reactor are described herein. In particular, a method of contacting a flow of metallocene with a flow of propylene is provided. This method includes directing the flow of metallocene towards a junction, directing the flow of propylene towards the junction and maintaining a portion of the flow of metallocene separate from a portion of the flow propylene within a portion of the junction downstream of the flow of propylene into the junction. In another embodiment, a method of introducing a quantity of antifouling agent into a catalyst mixing system is provided. In this embodiment a portion of the antifouling agent is introduced at or downstream of a point of contact of a stream of propylene with a stream of catalyst. The antifouling agent may be a member, alone or in combination with other members, selected from Stadis 450 Conductivity Improver, Synperonic antifouling agent, and Pluronic antifouling agent. | 08-25-2011 |
| 20110201862 | Processes Using Dividing Wall Distillation Column - A method for the separation of hydrocarbon compounds utilizing a dividing wall distillation column is described. The dividing wall distillation column enables one or more side draw stream to be removed from the dividing wall distillation column in addition to an overhead stream and a bottoms stream. | 08-18-2011 |
| 20110201757 | Methods for Production of High Impact Polystyrene - A method of preparing a high impact polystyrene comprising contacting styrene monomer, a high cis polybutadiene elastomer, and an initiator under high shear within a reaction zone. A high-impact polystyrene comprising a high cis polybutadiene elastomer. A method of preparing a high impact polystyrene comprising contacting styrene monomer, a high cis polybutadiene elastomer, and an initiator under extreme reaction conditions within a reaction zone. | 08-18-2011 |
| 20110196182 | STYRENE PRODUCTION PROCESSES AND CATALYSTS FOR USE THEREIN - Styrene production processes and catalysts for use therein are described herein. The process generally includes providing a C | 08-11-2011 |
| 20110195210 | POLYPROPYLENE AND POLYLACTIC ACID BLENDS OF INJECTION STRETCH BLOW MOLDING APPLICATIONS - Injection stretch blow molded (ISBM) articles containing a bio-based polymers and methods of forming the same are described herein. The method generally includes providing a propylene-based polymer; contacting the propylene-based polymer with polylactic acid to form a polymeric blend; injection molding the blend into a preform; and stretch-blowing the preform into an article. | 08-11-2011 |
| 20110190447 | COMPATIBILIZED POLYPROPYLENE HETEROPHASIC COPOLYMER AND POLYLACTIC ACID BLENDS FOR INJECTION MOLDING APPLICATIONS - Injection molded articles and process of forming the same are described herein. The processes generally include providing a polyolefin including one or more propylene heterophasic copolymers, the polyolefin having an ethylene content of at least 10 wt. % based on the total weight of the polyolefin; contacting the polyolefin with a polylactic acid and a reactive modifier to form a compatiblized polymeric blend, wherein the reactive modifier is produced by contacting a polypropylene, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of a glycidyl methacrylate grafted polypropylene (PP-g-GMA) having a grafting yield in a range from 1 wt. % to 15 wt. %; and injection molding the compatibilized polymeric blend into an article. | 08-04-2011 |
| 20110184218 | USE OF SWING PRELIMINARY ALKYLATION REACTORS - Alkylation systems and processes are described herein. The alkylation system generally includes a preliminary alkylation system containing a preliminary alkylation catalyst therein and adapted to contact an aromatic compound and an alkylating agent with the preliminary alkylation catalyst so as to alkylate the aromatic compound and form a preliminary output stream, wherein the preliminary alkylation system includes a first preliminary alkylation reactor and a second preliminary alkylation reactor connected in parallel to the first preliminary alkylation reactor and a primary alkylation system adapted to receive the preliminary output stream and contact the preliminary output stream and the alkylating agent with a primary alkylation catalyst disposed therein so as to form a primary output stream. | 07-28-2011 |
| 20110183097 | POLYETHYLENE MATERIALS PREPARED USING MIXED ZIEGLER-NATTA CATALYST SYSTEMS - A polyethylene may be prepared using a mixture of a silica supported catalyst and a magnesium chloride supported catalyst. By changing the ratio of the two catalysts, the polyethylene produced may have a varying bulk density and shear response. The method allows for the tuning or targeting of properties to fit a specific application, such as a blow molding or vapor barrier film. | 07-28-2011 |
| 20110174413 | Modification of Polyethylene Pipe to Improve Sag Resistance - Methods of forming pipe articles and pipe articles are described herein. The methods generally include providing a bimodal ethylene based polymer, blending the bimodal ethylene based polymer with up to about 50 ppm peroxide to form modified polyethylene and forming the modified polyethylene into a pipe. | 07-21-2011 |
| 20110172480 | Vaporization and Transportation of Alkali Metal Salts - An apparatus and method for vaporizing and transporting an alkali metal salt is shown. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam forming a solution that can be transported, such as to a remote reaction zone. The solution can be transported via a third conduit that is capable of being heated by a heat source. The method can be used to add a promoter to a dehydrogenation catalyst during a dehydrogenation reaction. | 07-14-2011 |
| 20110172379 | Ziegler-Natta Catalyst Systems and Polymers Formed Therefrom - Processes of forming catalyst systems, catalyst systems and polymers formed therefrom are described herein. The processes generally include providing a first compound including a magnesium dialkoxide, contacting the first compound with a second compound to form a solution of reaction product “A”, wherein the second compound is generally represented by the formula: | 07-14-2011 |
| 20110144273 | POLYPROPYLENE AND POLYLACTIC ACID FORMULATIONS FOR HEAT SEAL APPLICATIONS - Films (or a cap layer of co-extruded films) and methods of forming the same are described herein. The films generally include a modified olefin based polymer including polypropylene and from 1 wt. % to 30 wt. % polylactic acid (PLA), wherein the modified olefin based polymer exhibits a seal initiation temperature (SIT) that is at least 5° C. less than a seal initiation temperature of the polypropylene absent the PLA and a hot tack range of at least 20° C. | 06-16-2011 |
| 20110132519 | POLYOLEFIN POLYLACTIC ACID BLENDS FOR EASY OPEN PACKAGING APPLICATIONS - Easy open packaging films and methods of forming the same are described herein. The films generally include a polymeric composition, wherein the polymeric composition includes an olefin based polymer and polylactic acid. | 06-09-2011 |
| 20110130609 | Dilute Liquid Phase Alkylation - Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a liquid phase reaction zone and recovering ethylbenzene from the reaction zone. | 06-02-2011 |
| 20110112262 | SUPPORTED METALLOCENE CATALYSTS - Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m | 05-12-2011 |
| 20110112231 | Neutralizer Modified Propylene Based Polymers and Processes of Forming the Same - Polymer articles formed from a modified propylene based polymer and processes of forming the same are described herein. The modified propylene based polymers generally include a propylene based polymer, a nucleator including a hyper nucleator, and a neutralizer composition, wherein the neutralizer composition includes a first compound selected from stearoyl lactylates, lactates, hydrotalcites, hydroxides and combinations thereof and may optionally include a second compound selected from metal stearates, wherein the lactates are selected from modified calcium salts derived from stearic and lactic acids and calcium lactates. | 05-12-2011 |
| 20110105818 | Dehydrogenation Catalyst with a Water Gas Shift Co-Catalyst - A catalyst comprising a dehydrogenation catalyst and a water gas shift co-catalyst can be used for the dehydrogenation of alkylaromatic hydrocarbons to alkenylaromatic hydrocarbons. For instance, the catalyst can be used for the dehydrogenation of ethylbenzene to styrene. The catalyst can include an iron compound, a potassium compound, and a cerium compound. | 05-05-2011 |
| 20110105691 | Blends of Polypropylene and Polyethylene and Methods of Forming the Same - Polymer blends and methods of forming the same are described herein. The polymer blends generally include a single site transition metal catalyst formed polypropylene, a single site transition metal catalyst formed polyethylene and a polyethylene compatible nucleator. | 05-05-2011 |
| 20110105316 | Mixed Metal Oxide Ingredients for Bulk Metal Oxide Catalysts - A bulk metal oxide catalyst can be prepared by combining metal oxide powders or oxide-producing species and reacting selected ingredients prior to their inclusion in the formulation of the catalyst. Mixed metal oxide phases can be designed and prepared for use as an ingredient for a bulk metal oxide catalyst to alter properties for catalytic performance or physical properties that would not be obtained using mixtures of singular metal oxide ingredients. | 05-05-2011 |
| 20110092655 | TRANSITION METAL CATALYSTS AND FORMATION THEREOF - Supported catalysts systems and method of forming the same are described herein. The method generally includes providing a support material, providing a single site transition metal catalyst compound, contacting the transition metal catalyst compound with triisobutyl aluminum (TiBAl) to form a modified catalyst compound and contacting the support material with the modified catalyst compound to form a supported catalyst system. | 04-21-2011 |
| 20110083998 | Petrochemical Processes - Petrochemical processes, including reforming processes are described herein. The reforming processes generally include introducing an input stream to a reforming unit having a reforming catalyst disposed therein, wherein the input stream includes a naphtha having an N+2A value of from about 65 to about 85 and contacting the input stream with the reforming catalyst and hydrogen to form an output stream. | 04-14-2011 |
| 20110077444 | Metathesis Catalyst for Olefin Production - A catalyst includes a metathesis catalyst and an isomerization catalyst. In one embodiment, WO | 03-31-2011 |
| 20110077443 | Process for Catalyst Regeneration and Extended Use - A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst to minimize process upsets due to alkylation catalyst deactivation and the resulting catalyst regeneration or replacement. The H-beta catalyst can be used in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can lead to the reactivation of the catalyst in the primary alkylation reactor. | 03-31-2011 |
| 20110071330 | Offgas Stream Direct Contact Condenser - Methods and systems for the dehydrogenation of hydrocarbons include a direct contact condenser to remove compounds from an offgas process stream. The reduction of compounds can decrease duty on the offgas compressor by removing steam and aromatics from the offgas. The dehydrogenation reaction system can be applicable for reactions such as the dehydrogenation of ethylbenzene to produce styrene, the dehydrogenation of isoamiline to produce isoprene, or the dehydrogenation of n-pentene to produce piperylene. | 03-24-2011 |
| 20110054123 | High Impact Polymers and Methods of Making and Using Same - A method comprising contacting a grafting polymerization initiator with a composition comprising a vinylaromatic monomer and an elastomer under conditions suitable for the formation of a polymeric composition and forming the polymeric composition into an article wherein the article has an Izod impact strength of greater than 2.0 ft. lb./in. A method comprising contacting a grafting polymerization initiator with a vinylaromatic monomer and an elastomer under conditions suitable for the formation of a polymeric composition, wherein the grafting polymerization initiator comprises a peroxyketal. | 03-03-2011 |
| 20110052929 | Multilayer Polypropylene Films and Methods of Making and Using Same - A method including forming a bilayer polymer film having an oriented polypropylene film and a metallocene-catalyzed polypropylene film wherein the metallocene-catalyzed polypropylene film has a seal initiation temperature of from 80° C. to 130° C. A laminate including a biaxially oriented polypropylene film, a metallocene-catalyzed polypropylene film, and a substrate, wherein the metallocene-catalyzed polypropylene film is disposed between the biaxially oriented polypropylene film and the substrate. | 03-03-2011 |
| 20110020576 | Polystyrene Preform Design for Blow Molding of Articles - Preforms for use in injection blow molding processes and such processes are described herein. The preforms can have both a body and a neck wherein the external body diameter of the preform is at most 95% of the external neck diameter. The body comprises internal and external diameters that together form a sidewall, the thickness of which can be greater than 2.0 mm. Also disclosed is a mold for the injection molding of the preform described above. | 01-27-2011 |
| 20110020571 | Polystyrene Nanocomposites for Blow Molding Applications - Disclosed is a polystyrene based polymer/layered compound nanocomposite for injection blow molding or injection stretch blow molding of articles. The nanocomposite can reduce shrinkage and warpage to the preform during the reheating process compared to neat polystyrene. The incorporation of layered compounds can increase the processability of PS preforms, help improve heating efficiency, and improve bottle mechanical properties. The layered compound can be treated with chemicals or compounds having an affinity with the styrene monomer or polystyrene, thus producing a treated layered compound having an affinity with the styrene monomer or polystyrene. The monomer and the layered compound can be combined prior to polymerization. The polymer and layered compound can be combined by solution mixing in a solvent. The layered compound can also be incorporated into the mixture by compounding a polymer product with the layered compound, or the combination of any of the above three approaches | 01-27-2011 |
| 20110015311 | ASPHALT COMPOSITIONS AND THE PREPARATION THEREOF - Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications. | 01-20-2011 |
| 20110003953 | Carbon-Bridged Cyclopentadienyl-Fluorenyl Ligands - The present invention discloses efficient methods for preparing substituted cyclopentadienyl-fluorenyl catalyst components having a mono-carbon bridge. | 01-06-2011 |
| 20100331595 | Process for the Oxidative Coupling of Methane - A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. | 12-30-2010 |
| 20100331593 | Process for the Oxidative Coupling of Hydrocarbons - A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. | 12-30-2010 |
| 20100331174 | Catalysts for Oxidative Coupling of Hydrocarbons - A catalyst includes: (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. | 12-30-2010 |
| 20100273962 | Polyethylene Materials Prepared Using Mixed Ziegler-Natta Catalyst Systems - A polyethylene may be prepared using a mixture of a silica supported catalyst and a magnesium chloride supported catalyst. By changing the ratio of the two catalysts, the polyethylene produced may have a varying bulk density and shear response. The method allows for the tuning or targeting of properties to fit a specific application, such as a blow molding or vapor barrier film. | 10-28-2010 |
| 20100267909 | Bimodal Pipe Resin and Products Made Therefrom - Disclosed is a bimodal Ziegler-Natta catalyzed polyethylene, having a density of from 0.930 g/cc to 0.960 g/cc, and a molecular weight distribution of from 10 to 25, wherein an article formed therefrom has a PENT of at least 1500. Also disclosed is a method of preparing a tubular article including obtaining a bimodal polyethylene having a density of from 0.930 g/cc to 0.960 g/cc and a molecular weight distribution of from 10 to 25, and processing the polyethylene under conditions where a specific energy input (SEI) is less than 300 kW·h/ton, and wherein the article has a PENT of at least 1500. Further disclosed is a method for controlling the degradation of polyethylene including polymerizing ethylene monomer, recovering polyethylene, extruding the polyethylene, and controlling the degradation of polyethylene by measuring the SEI to the extruder and adjusting throughput and/or gear suction pressure keep SEI less than 300 kW·h/ton, and forming an article. | 10-21-2010 |
| 20100249473 | Oxidative Coupling of Hydrocarbons as Heat Source - A process for the coupling of hydrocarbons and utilizing the heat energy produced by the reaction is disclosed. In one embodiment the process can include reacting methane with oxygen to form a product stream containing ethane and further processing the ethane to ethylene in an existing ethylene production facility while using the heat energy produced by the reaction within the facility. | 09-30-2010 |
| 20100249354 | INJECTION STRETCH BLOW MOLDED ARTICLES AND SYNDIOTACTIC POLYMERS FOR USE THEREIN - Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a syndiotactic propylene-based polymer. | 09-30-2010 |
| 20100249327 | METHOD FOR THE PREPARATION OF A HETEROPHASIC COPOLYMER AND USES THEREOF - Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included. | 09-30-2010 |
| 20100247887 | POLYOLEFIN FILMS FOR IN-MOLD LABELS - An in-mold label comprising a cast film and a process for producing a cast film, that comprises a polypropylene resin and a nucleator. The polypropylene resin has a melt flow rate from 2 dg/min. to 10 dg/min., a xylene solubles content less than 1 wt %, and meso pentad distribution greater than 98%. | 09-30-2010 |
| 20100243498 | INJECTION STRETCH BLOW MOLDED ARTICLES AND RANDOM COPOLYMERS FOR USE THEREIN - Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a metallocene random propylene-based copolymer. | 09-30-2010 |
| 20100234533 | Ionomer Compositions and Methods of Making and Using Same - A method comprising contacting at least one metal salt of an organic acid with at least one aromatic compound in a reaction zone under conditions suitable for the formation of a polymer, wherein the metal salt of an organic acid comprises a metal and at least one unsaturated organic acid moiety. A composition comprising polystyrene and a metal salt of cinnamic acid. An article made from a composition comprising polystyrene and a metal salt of cinnamic acid. A composition comprising polystyrene and a salt of a fatty acid. An article made from a composition comprising polystyrene and a salt of a fatty acid. | 09-16-2010 |
| 20100227986 | Methods of Catalyst Activation - A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types. | 09-09-2010 |
| 20100222532 | Polystyrene Having High Melt Flow and High Vicat - A monovinylidene aromatic polymer with a melt flow index of at least 7 g/10 min and a Vicat softening temperature of at least 200° F. may be useful for injection molding with reduced cycle time. The monovinylidene aromatic polymer may be general purpose polystyrene or high impact polystyrene. It may include reduced amounts of mineral oil and increased amounts of an additive such as zinc dimethacrylate to optimize its processability and mechanical characteristics. | 09-02-2010 |
| 20100210797 | Polyethylene Films having Improved Barrier Properties - Blown films and processes of forming the same are described herein. The blown films generally include high density polyethylene exhibiting a molecular weight distribution of from about 1.5 to about 8.0 and a density of from 0.94 g/cc to less than 0.96 g/cc. | 08-19-2010 |
| 20100197819 | Styrenic polymer compositions and methods of making and using same - A method comprising contacting a first styrenic polymer composition comprising residual styrene monomer with a molecular sieve, and recovering a second styrenic polymer composition comprising a reduced amount of residual styrene monomer. A composition comprising a styrenic polymer having a residual styrene monomer amount of less than 100 ppm produced by contacting a styrenic polymer composition having a residual styrene monomer amount of equal to or greater than 100 ppm with a molecular sieve, and recovering the styrenic polymer having a residual styrene monomer amount of less than 100 ppm. A method comprising providing a styrenic polymer composition having a residual styrene monomer amount of equal to or greater than 100 ppm, contacting the styrenic polymer composition with a molecular sieve, adding a nucleating agent, a foaming agent, and a coloring agent to the styrenic polymer composition, and forming an expanded styrenic polymer composition having a residual styrene monomer amount of less than 100 ppm. | 08-05-2010 |
| 20100190909 | Polyethylene-Syndiotactic Polypropylene Composition and Processing Thereof - A processable polypropylene composition comprising a mixture of a major amount of a syndiotactic polypropylene and a minor amount of polyethylene wax. The syndiotactic polypropylene has a designated recrystallization temperature, an original minor melting peak and a higher original melting peak. The polyethylene wax provides a recrystallization temperature of the mixture that is greater than the recrystallization temperature of the syndiotactic polypropylene alone and also provides for a minor melting peak and a major melting peak of the mixture, which has a temperature difference which is lower than the difference between the original minor melting peak and the original major melting peak of the syndiotactic polypropylene alone. A process for the production of polypropylene product employing a polyethylene-syndiotactic polypropylene composition as described which is heated to provide a plastic mass of the syndiotactic polypropylene and polyethylene which is processed to provide the product. | 07-29-2010 |
| 20100190635 | Promotors for Controlling Acidity and Pore Size of Zeolite Catalysts for Use in Alkylation - A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethylbenzene. | 07-29-2010 |
| 20100184920 | Methods of making styrenic polymeric compositions and methods of using same - A method comprising preparing a reaction mixture comprising a styrene monomer, an antioxidant, and a reaction rate improving additive, contacting the reaction mixture with an antioxidant reactive compound, and placing the reaction mixture under conditions suitable for polymerization of the styrene monomer to a styrenic polymer wherein the polymerization occurs at an overall reaction rate that is increased by equal to or less than 20% when compared to an otherwise similar polymerization process carried out in the absence of the reaction rate improving additive A method comprising preparing a reaction mixture comprising a styrene monomer, an elastomer, an antioxidant, a sodium or calcium salt of an organic acid, and an initiator; and placing the reaction mixture under conditions suitable for polymerization of the styrene monomer to a styrenic polymer, wherein the sodium or calcium salt of an organic acid protects the initiator such that the polymerization is carried out at a reaction rate greater than would otherwise be the rate in the absence of the sodium or calcium salt of an organic acid. | 07-22-2010 |
| 20100168486 | Method for Production of Styrene from Toluene and Methanol - A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor. | 07-01-2010 |
| 20100168357 | Branched Ionomers with Metal Methacrylates as Comonomers - A branched aromatic ionomer is prepared with a first monomer having an unsaturated moiety and a second monomer having an unsaturated moiety and an ionic moiety, wherein the ionic moiety comprises a polyvalent metal with a coordination number greater than its oxidation number. An example of the first monomer is styrene, and the product ionomer can be a variety of general purpose polystyrene. Examples of the second monomer are zirconium methacrylate and titanium methacrylate, which may be co-polymerized with at least 0.5 molar equivalents of methacrylic acid as an in-situ formed ionomeric crosslinker. | 07-01-2010 |
| 20100168347 | Processes Using Dividing Wall Distillation Column - A method for the separation of hydrocarbon compounds utilizing a dividing wall distillation column is described. The dividing wall distillation column enables one or more side draw stream to be removed from the dividing wall distillation column in addition to an overhead stream and a bottoms stream. | 07-01-2010 |
| 20100168345 | Synthesis with Metal Methacrylates as Comonomers - A method for the in-situ preparation of an ionic comonomer from its chemical precursors, prepared in a solution of styrene monomer is disclosed. In one embodiment, the ionic comonomer is zirconium methacrylate, Zr(MA) | 07-01-2010 |
| 20100168334 | Polymeric Compositions and Polymerization Initiators Using Photo-Peroxidation Process - A rubber-modified polymeric composition having predominately core-shell morphology is disclosed. The rubber-modified polymeric composition can be a polystyrene comprising styrene, polybutadiene, and a high-grafting initiator formed by contacting singlet oxygen with an olefin containing an allylic hydrogen or a diene to form a hydroperoxide or peroxide. The singlet oxygen can be formed by contacting ground state oxygen with a photo catalyst, such a photosensitive dye exposed to light. | 07-01-2010 |
| 20100167913 | Catalyst with an Ion-Modified Binder - A solid catalyst, such as a molecular sieve catalyst or solid acid catalyst, is supported by a binder, such as amorphous silica or alumina, wherein the binder is charged with metal ions to form an ion-modified binder. The ion-modified binder is capable of attachment to polar contaminants and inhibit their contact with the catalyst. The catalyst can be a zeolite and can be the catalyst for an alkylation reaction, such as the alkylation of benzene with ethylene. | 07-01-2010 |
| 20100162826 | Synthesis of Styrene-Soluble Ionic Comonomer - A method for the in-situ preparation of an ionic comonomer, such as zinc dimethacrylate, dissolved in styrene monomer, for use in production of polystyrene is disclosed. The method generally includes adding comonomer chemical precursors to a solution of styrene and nonionic surfactant. The resulting ionic comonomer may be further dissolved in styrene and polymerized to form a product that may have improved properties. | 07-01-2010 |
| 20100162617 | Stabilization of Pygas for Storage - A method for stabilizing pyrolysis gasoline in storage involves adding an effective amount of a quinone methide compound to the pyrolysis gasoline. The quinone methide does not require oxygen for activity. Embodiments of the quinone methide do not contain nitrogen and will have a reduced tendency for ammonia production. | 07-01-2010 |
| 20100160570 | Blown Films and Processes of Forming the Same - Blown films and processes of forming the same are described herein. The processes generally include providing a bimodal ethylene based polymer, blending the bimodal ethylene based polymer with at least about 30 ppm peroxide to form modified polyethylene and forming the modified polyethylene into a blown film. | 06-24-2010 |
| 20100159173 | Polyethylene Polymerization Processes - Polymer articles and processes of forming the same are described herein. The processes generally include providing a bimodal ethylene based polymer, blending the bimodal ethylene based polymer with a nucleator to form modified polyethylene and forming the modified polyethylene into a polymer article, wherein the polymer article is selected from pipe articles and blown films. | 06-24-2010 |
| 20100140835 | Styrenic polymers for injection stretch blow molding and methods of making and using same - A method comprising preparing a styrenic polymer composition, melting the styrenic polymer composition to form a molten polymer, injecting the molten polymer into a mold cavity to form a preform, heating the preform to produce a heated preform, and expanding the heated preform to form an article. A method comprising substituting a styrenic polymer composition comprising from 0 wt. % to 6.5 wt. % plasticizer and equal to or greater than 2.5 wt. % elastomer for polyethylene terephthalate in an injection stretch blow molding process, wherein the wt. % is based on the total weight of the polymeric composition. A method comprising preparing a preform from a styrenic polymer composition, subjecting the preform to one or more heating elements, and rapidly heating the preform to produce a heated preform. | 06-10-2010 |
| 20100136310 | Polyethylene Fibers and Processes of Forming the Same - Fibers and methods of forming the fibers are described herein. The fibers generally include an ethylene based polymer exhibiting a molecular weight distribution of from about 2 to about 8. | 06-03-2010 |
| 20100129734 | Polypropylene Providing Improved Surface Properties - Propylene based films and methods of forming the sate are described herein. The propylene based films generally include a core layer formed of an olefin polymer, an embossing layer disposed on an exterior surface of the core layer and entirely formed of a metallocene formed propylene based polymer selected from propylene homopolymers, propylene based random copolymers formed of of polypropylene and polyethylene and combinations thereof, wherein the embossing layer includes an outer surface having a marking formed thereon and wherein the film is capable of retaining the marking thereon. | 05-27-2010 |
| 20100129652 | Polyethylene Films - The present invention relates to polyethylene films, and to processes for making films. In particular the invention relates to solid state stretched films that may be monoaxially or biaxially oriented. The processes can tolerate high draw ratios and lower extrusion pressures and amperes while producing films having high tensile strength and modulus as well as low shrinkage. The polyethylene used to make the films has a density of from 0.940 to less than 0.960, a molecular weight distribution of greater than 10, a melt flow index ranging from 0.30 dg.min to 1.00 dg/min and a weight average molecular weight of 300,000 or less. | 05-27-2010 |
| 20100129579 | Rapid Crack Properties in High Performance Pipe - Pipe articles and methods of forming the same are described herein. The pipe articles generally include a bimodal polyethylene including a greater amount of high molecular weight fraction than low molecular weight fraction and wherein the pipe article exhibits a critical temperature of less than about 0° C. at 5 bar. | 05-27-2010 |
| 20100125124 | Methods of catalyst activation - A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types. | 05-20-2010 |
| 20100099834 | Transition Metal Catalyst Systems and Formation Thereof - Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system. | 04-22-2010 |
| 20100099822 | High impact polymeric compositions and methods of making and using same - A method comprising contacting at least one conventional elastomer, at least one singlet oxygen functionalized elastomer (SOFE), and a styrene monomer in a reaction zone under conditions suitable for the formation of a styrenic polymer composition. A method comprising contacting a reaction mixture comprising styrene, polybutadiene, and a photoperoxidized polybutadiene in a reaction zone under conditions suitable for the formation of a polymeric composition, wherein the elastomer particle size distribution in the polymeric composition does not linearly correlate with the elastomer particle size distribution in the reaction mixture. A reactor blended polymer comprising styrene, a conventional elastomer, and a singlet oxygen functionalized elastomer. | 04-22-2010 |
| 20100098586 | Propylene Polymers for Lab/Medical Devices - Polymer compositions and articles formed therefrom are described herein. The compositions include a random copolymer and a radiation additive, wherein the random copolymer includes propylene and less than 2 wt. % ethylene and exhibits a melt flow rate of from about 300 to 100 dg/min., the polymer composition exhibits a flexural modulus of from about 160 kpsi to about 200 kpsi and the polymer composition is adapted to produce a polymer article exhibiting low plate out, a haze at 20 mils of no greater than 15%, radiation stability and autoclavability. | 04-22-2010 |
| 20100087602 | Long chain branched polypropylene for cast film applications - A method comprising contacting a polypropylene, an acrylate-containing compound, and an initiator to form a composition, and reactive extruding the composition to form a polymer blend. A method comprising contacting a polypropylene, a multi-functional acrylate monomer, and an initiator to form a composition, reactive extruding the composition to form a reactive extruded composition, and forming the reactive extruded composition into a film wherein the reactive extruded composition has a melt flow rate that is reduced by equal to or greater than 5% when compared to neat polypropylene. | 04-08-2010 |
| 20100081856 | Process for Ethylbenzene Production - A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst to minimize process upsets due to alkylation catalyst deactivation and the resulting catalyst regeneration or replacement. The H-beta catalyst can be used in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can reduce the deactivation of the catalyst in the primary alkylation reactor. | 04-01-2010 |
| 20100081855 | Semi-Supported Dehydrogenation Catalyst - A catalyst having at least 5 weight percent of an alumina compound useful for the dehydrogenation of alkylaromatic hydrocarbons to alkenylaromatic hydrocarbons and methods of use are disclosed. | 04-01-2010 |
| 20100081767 | Articles Formed from Nucleated Polyethylene - Polymer articles and processes of forming the same are described herein. The processes generally include providing an ethylene based polymer, blending the ethylene based polymer with a modifier to form modified polyethylene and forming the modified polyethylene into a polymer article, wherein the polymer article exhibits a haze that is at least about 10% less than a polymer article prepared with a similarly modified polyethylene. | 04-01-2010 |
| 20100081746 | Color Reduction in Polyethylene Modified by Radical Initiation - Polyethylene modified by using radical initiators such as oxygen and peroxides sometimes has a yellow color which may be reduced or eliminated by incorporating additives such as polyethylene glycol, and/or neutralizing species such as alkali metal stearates, particularly calcium stearate, and zinc oxide. | 04-01-2010 |
| 20100081743 | Polypropylene for Reduced Plate Out in Polymer Article Production Processes - Polymer articles and processes of forming polymer articles are described herein. The processes generally include providing a propylene based polymer formed from a metallocene catalyst and melt processing the propylene based polymer to form a polymer article. | 04-01-2010 |
| 20100078465 | Paperboard Extrusion Coating Processes and Polymers for Use Therein - Packaging materials and methods of forming the same are described herein. The methods generally include providing a paperboard substrate having an exterior surface and an interior surface opposite the exterior surface, coating the exterior surface of the paperboard substrate with a first polymer to form an exterior layer forming a wall structure, forming the wall structure into a packaging material and adhering a closure assembly to the packaging material, wherein a portion of the closure assembly is directly attached to the exterior layer and wherein the portion of the closure assembly is formed of the first polymer. | 04-01-2010 |
| 20100047596 | ROTOMOULDED ARTICLES PREPARED FROM A BLEND OF POLYETHYLENE POWDERS - The present invention discloses the use of a dry blend comprising a polyethylene resin and a functionalised polyolefin or ionomer in a composition with a thermoplastic resin in order to produce a layer that provides adhesion, fire resistance and low permeation rate in a multi layer rotomoulded article. | 02-25-2010 |
| 20100047571 | Process of Making Bicomponent Fiber - Bicomponent fibers, methods of forming bicomponent fibers and articles formed from bicomponent fibers are described herein. Tile bicomponent fibers generally include a sheath component and a core component, wherein the sheath component consists essentially of a first metallocene polypropylene and the core component consists essentially of a second metallocene polypropylene. | 02-25-2010 |
| 20100041934 | Toluene Disproportionation Using Nb/Mordenite Catalyst - A molecular sieve catalyst useful in the conversion of hydrocarbons containing niobium is disclosed, along with a process for the disproportionation of toluene to benzene and xylene using such catalyst. | 02-18-2010 |
| 20100041933 | Catalyst and Process for Hydrocarbon Conversions - A nickel-mordenite catalyst promoted with Rhodium that is useful in the conversion of hydrocarbons is disclosed. The catalyst and methods for its use can provide hydrocarbon conversion with an extended catalyst life as compared to nickel-mordenite catalyst not promoted with Rhodium. | 02-18-2010 |
| 20100041931 | Method for Production of Styrene from Toluene Syngas - A method for the production of styrene comprising reacting toluene and syngas in one or more reactors is disclosed. | 02-18-2010 |
| 20100022817 | Dehydrogenation Reactions of Hydrocarbons to Alkenes - A method for the dehydrogenation of hydrocarbons to alkenes, such as n-pentene to piperylene and n-butane to butadiene at pressures less than atmospheric utilizing a dehydrogenation catalyst are disclosed. Embodiments involve operating the dehydrogenation reactor at a pressure of 1,000 mbar or less. | 01-28-2010 |
| 20100022816 | Dehydrogenation of Methylbutenes to Isoprene - A method for the dehydrogenation of isoamylene to isoprene at pressures less than atmospheric utilizing a dehydrogenation catalyst is disclosed. Embodiments involve operating the dehydrogenation reactor at a pressure of 1,000 mbar or less. | 01-28-2010 |
| 20100022813 | Process for Reducing Ethylbenzene Content from an Aromatic Stream - A method of reducing the ethylbenzene content in a stream containing xylene is disclosed. The method includes the reaction of ethylbenzene, such as a disproportionation or transalkylation reaction, to produce benzene and other hydrocarbon compound and can include the separation of at least a portion of the resulting benzene and other hydrocarbon compounds to produce a xylene stream having reduced ethylbenzene content. | 01-28-2010 |
| 20100016528 | Ethylene and alpha-olefins polymerisation catalyst system based on fluorenyl ligand - The present invention discloses a catalyst system comprising a cyclopentadienyl-£luorenyl-based catalyst component wherein the cyclopentadienyl is di-substituted and the fluorenyl is monosubstituted. It also discloses its method of preparation and its use in the polymerisation of ethylene. | 01-21-2010 |
| 20100015331 | Hot melt adhesive compositions and methods of making and using same - A method comprising reactively extruding a polyolefin, an acrylate containing compound, and an initiator to form a polyolefin/polyacrylate blend, and applying the blend in a melted form to one or more substrates. A method comprising extruding a metallocene ethylene-propylene random copolymer to form a melt, wherein the copolymer has a melt flow rate of from 0.5 g/10 min. to 2000 g/10 min., and applying the melt to one or more substrates. A method comprising reactively extruding a metallocene ethylene-propylene random copolymer, an acrylate containing compound, and a peroxide to form a polyolefin/polyacrylate blend, wherein the blend has a melt flow rate of greater than 100 g/10 min., and applying the blend in a melted form to one or more substrates. | 01-21-2010 |
| 20100010175 | Additives for Polyolefin Extruder Start-Up - Polymerization processes and polymers formed therefrom are described herein. The polymerization processes generally include contacting an olefin monomer with a catalyst system to form polymer within a reaction vessel, withdrawing polymer from the reaction vessel, contacting the polymer with one or more initiation additives to form a modified polymer and extruding the modified polymer. | 01-14-2010 |
| 20100003494 | Opaque Films for Use in Packaging - An opaque polymer film is prepared by admixing high crystalline polypropylene with a microvoid causing filler and extruding to form a sheet that is then biaxially stretched to form an opaque film. End uses for these films include soda bottles, candy wrappers and synthetic paper. | 01-07-2010 |
| 20090326152 | Compatibilized polypropylene and polylactic acid blends and methods of making and using same - A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %. | 12-31-2009 |
| 20090326130 | POLYMERIC BLENDS AND METHODS OF USING SAME - A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article. | 12-31-2009 |
| 20090324911 | Polymeric compositions comprising polylactic acid and methods of making and using same - A multi-component article comprising a first component comprising a biodegradable polymer, and a second component comprising a polyolefin and a reactive modifier. A method of preparing a multi-layer film comprising coextruding first and second film layers, wherein the first layer comprises a polylactic acid and the second layer comprises a polyolefin and an epoxy-functionalized polyolefin. A method of preparing a multi-component fiber comprising coextruding a core component and a sheath component, wherein the core component comprises a polyolefin and an epoxy-functionalized polyolefin and the sheath component comprises a polylactic acid. | 12-31-2009 |
| 20090315226 | Injection Stretch Blow Molded Articles and Polymers for Use Therein - Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a propylene-based impact copolymer. | 12-24-2009 |
| 20090273110 | Composites Comprising a Polymer and a Layered Compound and Methods of Preparing and Using Same - A method comprising extrusion compounding a styrenic polymer and a layered compound to produce a composite, and orienting the composite to produce an oriented composite wherein the layered compound comprises natural clay, synthetic clay, natural colloid, synthetic colloid, natural sol, synthetic sol, natural gel, synthetic gel, natural fumes, synthetic fumes, or combinations thereof. A method of preparing an oriented film comprising extrusion compounding a styrenic polymer and a clay to produce a nanocomposite, casting the nanocomposite into a film, and orienting the film in at least one direction. | 11-05-2009 |
| 20090270566 | Olefin Polymerization Processes and Catalysts for Use Therein - Polymerization process and polymers formed therefrom are described herein. The polymerization processes generally include introducing an olefin monomer into a reaction vessel, introducing a single-site transition metal catalyst into the reaction vessel, introducing a multi-functional block copolymer non-ionic surfactant into the reaction vessel, contacting the olefin monomer with the catalyst system in the presence of the non-ionic surfactant within the reaction vessel under polymerization conditions to form a polyolefin and withdrawing the polyolefin from the reaction vessel. | 10-29-2009 |
| 20090264278 | Method and Apparatus for Addition of an Alkali Metal Promoter to a Dehydrogenation Catalyst - An apparatus and method for adding an alkali metal promoter into steam and contacting the solution with a dehydrogenation catalyst during a dehydrogenation reaction is disclosed. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam prior to entry into a dehydrogenation reaction zone. | 10-22-2009 |
| 20090247801 | Process for Toluene and Methane Coupling in a Microreactor - A process for making ethylbenzene and/or styrene by reacting toluene with methane in one or more microreactors is disclosed. In one embodiment a method of revamping an existing styrene production facility by adding one or more microreactors capable of reacting toluene with methane to produce a product stream comprising ethylbenzene and/or styrene is disclosed. | 10-01-2009 |
| 20090246501 | Reduced Weight Multilayer Polymeric Articles and Methods of Making and Using Same - A method of preparing a refrigeration insulation liner comprising forming a multilayer polymeric sheet comprising at least one foam layer and at least one solid layer disposed adjacent to the foam layer, shaping the multilayer polymeric sheet into the liner, wherein the liner is an insulator, wherein the layers of the sheet adhered to each other by melt extrusion, and wherein the liner resists degradation in the event of contact with a refrigerant. A method of preparing a refrigeration device liner comprising coextruding a foamed polystyrene layer between two solid layers of high impact polystyrene to form a sheet, thermoforming the sheet into the liner, and incorporating the liner into the refrigeration device. A method of forming a multilayer polymeric sheet comprising melting a first styrenic polymer composition, melting and foaming a second styrenic polymer composition, and coextruding the first and second styrenic polymer compositions to form a multilayer polymeric sheet. | 10-01-2009 |
| 20090246491 | Co-Extruded Film Structures of Polypropylene Impact Copolymer with Other Copolymers - It has been discovered that the properties of sheet or film materials or structures can be improved by co-extruding a polypropylene based impact copolymer core layer with at least a second polyolefin that may be a high density polyethylene (HDPE), medium density polyethylene (MDPE), linear low density polyethylene (LLDPE), and/or low density polyethylene (LDPE). Improvements can include, but are not limited to, reduced haze and increased gloss. These sheet or film materials may be co-extruded with other resins or laminated with other materials after extrusion. | 10-01-2009 |
| 20090203856 | Ziegler-Natta catalyst - The present invention relates generally to catalysts, to methods of making catalysts, to methods of using catalysts, to methods of polymerizing, and to polymers made with such catalysts. More particularly, the present invention relates to polyolefin catalysts and to Ziegler-Natta catalysts, to methods of making such catalysts, to methods of using such catalysts, to polyolefin polymerization, and to polyolefins. | 08-13-2009 |
| 20090198023 | Polyethylene Materials Prepared Using Mixed Ziegler-Natta Catalysts Systems - A polyethylene may be prepared using a mixture of a silica supported catalyst and a magnesium chloride supported catalyst. By changing the ratio of the two catalysts, the polyethylene produced may have a varying bulk density and shear response. The method allows for the tuning or targeting of properties to fit a specific application, such as a blow molding or vapor barrier film. | 08-06-2009 |
| 20090191388 | Modifiers for Oriented Polypropylene - A biaxially oriented film that comprises polypropylene and either polytrimethylene terephthalate or polymethylpentene as a cavitating agent in an amount from 5 wt % to 25 wt %. The film has a haze of from 90% to 100% and a gloss of from 10 to 150. The film may be used in food packaging applications and in industrial applications. | 07-30-2009 |
| 20090186999 | Low melt flow rate (MFR) propylene based polymers for injection stretch blow molding - Injection stretch blow molded (ISBM) articles and processes for forming the same are described herein. The articles include a propylene based polymer having a melt flow rate of less than 10 g/10 min. | 07-23-2009 |
| 20090182072 | Use of Zinc Oxide to Improve Compatibility of Polymer Modified Asphalt Crosslinked with Phenol Aldenyde Resin - In methods of preparing asphalt and elastomeric polymer compositions crosslinked with phenol aldehyde resins and sulfur, such as polymer modified asphalt (PMA), it has been discovered that the MP1 compatibility may be improved by adding certain ionic metal salts. Suitable ionic metal oxides include, but are not necessarily limited to, zinc oxide, cadmium oxide, and the like. Acceptable elastomeric polymers include, but are not necessarily limited to, styrene-butadiene copolymers. Additional sulfur-containing crosslinkers may also be used. | 07-16-2009 |
| 20090163688 | FLUORENYL CATALYST COMPOSITIONS AND OLEFIN POLYMERIZATION PROCESS - An olefin polymerization process comprising contacting one or more olefins and a catalyst component in a reaction zone under suitable reaction conditions to form a polyolefin, wherein the catalyst component is characterized by the formula: | 06-25-2009 |
| 20090163680 | Ziegler-Natta catalyst for particle size control - Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product “A | 06-25-2009 |
| 20090162590 | Polypropylene Composition for Injection Stretch Blow Molding - A method of manufacturing an end-use article comprising: preparing a polymeric composition and converting the polymeric composition into an end-use article by injection stretch blow molding, wherein the article has an initial flexural modulus from about 100,000 psi to about 150,000 psi. A method of manufacturing an end-use article comprising: preparing a polymeric composition; converting the polymeric composition into an end-use article by injection stretch blow molding; and determining the initial mechanical properties of the end-use article. Articles prepared by the disclosed methodologies. | 06-25-2009 |
| 20090156873 | Method for Extending Catalyst Life in Processes for Preparing Vinyl Aromatic Hydrocarbons - Methods and systems for extending the life of a dehydrogenation catalyst are described herein. For example, one embodiment includes providing an alkyl aromatic hydrocarbon feed stream to a reaction chamber, contacting the feed stream with a dehydrogenation catalyst to form a vinyl aromatic hydrocarbon, the dehydrogenation catalyst including iron oxide and an alkali metal catalysis promoter and supplying a catalyst life extender to at least one reaction chamber, the reaction chamber loaded with the dehydrogenation catalyst, wherein the catalyst life extender includes a potassium salt of a carboxylic acid. | 06-18-2009 |
| 20090156773 | Modified resins for blown film - Processes for enhancing blown film processability and the blown films formed thereby are described herein. One embodiment of the processes generally includes providing a first propylene based heterophasic copolymer having a first melt flow rate, modifying the first propylene based heterophasic copolymer to form a second heterophasic polymer having a second melt flow rate, wherein the second melt flow rate is greater than the first melt flow rate, contacting the first heterophasic polymer, the second heterophasic copolymer or a combination thereof with a plurality of additives, wherein the plurality of additives include a nucleator, polyethylene and mineral oil to form a modified heterophasic copolymer and blowing the modified heterophasic polymer into a film. | 06-18-2009 |
| 20090156761 | Fluorinated transition metal catalysts and formation thereof - Supported catalyst systems and methods of forming the same are described herein. In one specific embodiment, the methods generally include providing an inorganic support material and contacting the inorganic support material with an aluminum fluoride compound represented by the formula AlF | 06-18-2009 |
| 20090155614 | Polypropylene Materials and Method of Preparing Polypropylene Materials - A polypropylene material may be prepared from a blend of heterophasic propylene copolymers and propylene homopolymers. The material may be prepared by blending the polymers while they are in a molten state, and forming a film or sheet from the polymer blend. The materials may also be formed as coextruded materials or as ternary blends with a polyethylene or a single phase random propylene copolymer. The blends and neat polymers have particular application to forming slit film tapes and similar materials. The resultant materials may exhibit increased tenacity, elongation and toughness and greater surface roughness as compared to those materials prepared solely from propylene homopolymers. | 06-18-2009 |
| 20090149685 | Treatment of Alkylation Catalyst Poisons with Dehydrogenation - Methods and processes for reducing alkylation catalyst poisoning are described herein. Such methods generally include providing a dehydrogenation system including a dehydrogenation reactor and a separation system, wherein the separation system includes a first column and a second column, introducing an alkyl aromatic hydrocarbon into the dehydrogenation reactor, contacting the alkyl aromatic hydrocarbon with a dehydrogenation catalyst disposed within the dehydrogenation reactor to form a dehydrogenation output stream comprising a vinyl aromatic hydrocarbon, passing at least a portion of the dehydrogenation output stream to first column, recovering a first overhead fraction including benzene and a first bottoms fraction from the first column, passing at least a portion of the benzene from the first column to an alkylation system including an alkylation catalyst, passing the first bottoms fraction from the first column to the second column, recovering a second overhead fraction and a second bottoms fraction from the second column, withdrawing offtest from effluent streams selected from the dehydrogenation output stream, the first bottoms fraction, the second bottoms fraction and combinations thereof to form withdrawn offtest and introducing the withdrawn offtest into the separation system downstream from the first column. | 06-11-2009 |
| 20090149605 | Heterophasic propylene based polymers for forming fiber - Fibers and articles formed therefrom are described herein. The fibers generally include a first polymer including a first propylene based impact copolymer and a second propylene based polymer. | 06-11-2009 |
| 20090149577 | Using Excess Levels of Metal Salts to Improve Properties when Incorporating Polymers in Asphalt - In methods of preparing asphalt and elastomeric polymer compositions such as polymer modified asphalt (PMA), it has been discovered that the compatibility can be improved by adding excess amounts of certain organic and inorganic metal salts beyond the proportions normally used. Suitable metal salts may be metal oxides that include, but are not necessarily limited to, zinc oxide, calcium oxide, and the like. The method of the invention also permits asphalt modified with other polymers such as ground tire rubber (GTR) to have improved compatibility. Additionally, the use of excess amounts of these metal salts helps control gel formation. | 06-11-2009 |
| 20090148351 | Plug Flow Reactor and Polymers Prepared Therewith - A plug flow reactor having an inner shell | 06-11-2009 |
| 20090146345 | Preform design for injections stretch blow molding - Preforms for use in injection stretch blow molding processes and such processes are described herein. The preforms generally include a neck having an internal neck diameter and an external neck diameter and a body having an internal body diameter and an external body diameter, the internal body diameter and the external body diameter forming a sidewall, wherein the internal body diameter is at least 80% of the internal neck diameter. The preforms further include an end-cap positioned on the body at a transition point and having an end-cap depth and a transition point radius, wherein the end-cap depth is greater than the transition point radius. | 06-11-2009 |
| 20090143504 | Bitumen/Rubber Compositions Crosslinked with Polythiomorpholines, Polysulfides and/or Mercaptobenzimidazole - Asphalt and elastomeric polymer compositions crosslinked with mixed polythiomorpholines or at least one alkyl polysulfide can give polymer modified asphalts (PMAs) with improved properties and/or reduced H | 06-04-2009 |
| 20090131616 | Methods for Improving Heat Transfer in Polymerization Processes - Methods for improving heat transfer in polymerization processes are described herein. The methods generally include contacting olefin monomer with a catalyst system within a reaction zone to form particles having a first average particle size and altering the reaction zone to improve heat transfer and form polymer particles having a second average particle size. For example, the second average particle size may be larger than the first average particle size and the second particle size results in improved heat transfer over the first particle size. | 05-21-2009 |
| 20090118430 | Polystyrene Blends and a Method of Making Same - Disclosed are blends of polystyrene and at least one of syndiotactic polypropylene, ethylene propylene copolymers, and styrene-butadiene-styrene triblock copolymers. These blends are prepared using solution polymerization and have unique morphologies and desirable physical properties. The blends can also be prepared with graft-promoting or crosslinking agents and rubbers to prepare modified high impact polystyrene. | 05-07-2009 |
| 20090111955 | Fluorinated Impregnated Catalyst Systems and Methods of Forming the Same - Methods of forming supported catalyst systems, supported catalyst systems and polymerization processes utilizing the supported catalyst systems are described herein. The methods generally include providing an inorganic support material and contacting the inorganic support material with a support solvent to form a support solution. The methods further include contacting the support solution with a fluorine containing compound represented by the formula AlF | 04-30-2009 |
| 20090110944 | Blends of Polypropylene Impact Copolymers with Other Polymers - It has been discovered that the properties of sheet or film materials of broad molecular weight distribution ethylene/propylene rubber impact-modified heterophasic copolymer (ICP) can be improved by blending the ICP with a second polyolefin. The second polyolefin may be a syndiotactic polypropylene (sPP), a random copolymer (RCP) of propylene and comonomer (e.g. ethylene and/or butene) made using a Ziegler-Natta or metallocene catalyst, medium density polyethylene (MDPE), linear low density polyethylene (LLDPE), or low crystalline copolymer of propylene/α-olefin. Improvements include, but are not necessarily limited to, reduced motor amps, lower secant modulus, increased dart drop strength, increased gloss, reduced haze, increased elongation to yield, elimination of stress whitening, improved puncture resistance, and decreased seal initiation temperature. This sheet of film materials may be co-extruded with other resins or laminated with other materials after extrusion. | 04-30-2009 |
| 20090105433 | Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins - Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCp | 04-23-2009 |
| 20090088531 | POLYMER COMPOSITIONS FOR REDUCED SHRINKAGE - A polymeric composition comprising a polymer and a nucleation agent, and having isotropic shrinkage of less than about 20% and a differential shrinkage of less than about 20%. | 04-02-2009 |
| 20090087602 | Propylene based polymers for injection stretch blow molding - Injection stretch blow molded (ISBM) articles and methods of forming the same are provided herein. In one embodiment, the ISBM articles generally include a propylene based random copolymer having a molecular weight distribution of from about 9 to about 20. In another embodiment, the ISBM articles generally include a propylene based random copolymer formed from a Ziegler-Natta catalyst including a succinate internal donor. | 04-02-2009 |
| 20090076315 | PROCESS FOR THE PREPARATION OF SUBSTITUTED FLUORENES - Methods for the preparation of fluorenyl-type ligand structures and substituted fluorenyl groups which may be employed in metallocene-type olefin polymerization catalysts. There is provided a 2,2′-dihalogen-diphenylmethylene having a methylene bridge connecting a pair of phenyl groups. Each phenyl group has a halogen on a proximal carbon atom relative to the methylene bridge. The halogenated diphenylmethylene is reacted with a coupling agent comprising a Group 2 or 12 transition metal in the presence of a nickel or palladium-based catalyst to remove the halogen atoms from the phenyl groups and couple the phenyl groups at the proximal carbon atoms to produce a fluorene ligand structure. The coupling agent may be zinc, cadmium or magnesium and the catalyst may be a monophosphene nickel complex. The halogenated diphenylmethylene may be an unsubstituted ligand structure or a monosubstituted or disubstituted ligand structure. The halogenated diphenylmethylene may be monosubstituted with a tertiary butyl group or may be a dialkyl diphenylmethylene having alkyl substituents at the directly distal positions of the phenyl groups relative to the methylene bridge. | 03-19-2009 |
| 20090076213 | Random Copolymers and Formulations Useful for Thermoforming and Blow Molding Applications - A composition that may be useful for thermoforming and blow molding applications comprises a metallocene catalyzed propylene-ethylene random copolymer having an ethylene content of from about 0.1 to about 1.5 weight percent based on the copolymer, and exhibits a flexural modulus of at least about 1,100 MPa, a haze of less than about 40 percent, a melt flow of from about 1.0 dg/min to about 3.0 dg/min, and a xylene solubles content from about 0.2 weight percent to about 1.0 weight percent based on the copolymer. A process for preparing the copolymer and articles prepared therefrom are also disclosed. The composition's properties may make it particularly desirable for applications such as bottles, syringes and containers such as those used for food and medical purposes. | 03-19-2009 |
| 20090072432 | Biaxially-Oriented Metallocene-Based Polypropylene Films Having Reduced Thickness - A polymer film having a thickness of 10 microns or less and improved barrier characteristics to both water vapor and oxygen is formed from a biaxially-oriented polypropylene film of isotactic polypropylene. The polypropylene is prepared by the polymerization of propylene in the presence of an isospecific metallocene catalyst. The film has a permeability to water vapor of less than about 2.5 g/m | 03-19-2009 |
| 20090054715 | Method and Apparatus for Addition of Aqueous Solutions to High Temperature Processes - Methods and systems for extending the life of a dehydrogenation catalyst are described herein. For example, one embodiment includes providing a reaction vessel loaded with a dehydrogenation catalyst with a feedstream via a conduit in operable communication with the reaction vessel. The feedstream may include an alkyl aromatic hydrocarbon and the dehydrogenation catalyst may be adapted to convert the alkyl aromatic hydrocarbon to a vinyl aromatic hydrocarbon. The feedstream may be contacted with an aqueous catalyst life extender, wherein the aqueous catalyst life extender enters the conduit at a linear velocity sufficient to prevent vaporization of the catalyst life extender in the conduit prior to contact with the feedstream. | 02-26-2009 |
| 20090035546 | POLYETHYLENE FILMS - The present invention relates to polyethylene films, and to processes for making films. In particular the invention relates to solid state stretched films that may be monoaxially or biaxially oriented. The processes can tolerate high draw ratios and lower extrusion pressures and amperes while producing films having high tensile strength and modulus as well as low shrinkage. The polyethylene used to make the films has a density of from 0.940 to less than 0.960, a molecular weight distribution of greater than 10, a melt flow index ranging from 0.30 dg.min to 1.00 dg/min and a weight average molecular weight of 300,000 or less. | 02-05-2009 |
| 20090035545 | POLYETHYLENE FILMS WITH IMPROVED BUBBLE STABILITY - This invention relates to high density polyethylene blown films having good barrier properties and improved processing characteristics. The method incorporates the use of peroxide which results in improved bubble stability without sacrifice in barrier properties. The polyethylenes have a density greater than about 0.950 g/cc, are relatively narrow in molecular weight distribution MWD (in the range of from about 2.0 to about 6.5), and are of medium molecular weight. In an embodiment, the films also have a rheological breadth parameter, a, that has been reduced by at least about 5%, but not more than 45%, by addition of a peroxide to the polyethylene. The addition of peroxide improves processability without sacrificing strength and barrier properties such as oxygen transmission rate. | 02-05-2009 |
| 20090029098 | Resin Composition for Improved Slit Film - Slit films and processes of forming the same are generally described herein. In one embodiment, the slit films include an impact copolymer (ICP) formed of polypropylene and less than about 8 wt. % total ethylene, wherein the slit film exhibits less shrinkage and higher tenacity than a slit film formed from an ICP having greater than 10 wt. % ethylene. In one embodiment, the slit films include an impact copolymer including propylene and ethylene, wherein the slit film is absent another polymer. | 01-29-2009 |
| 20090023966 | Treatment of Alkylation Catalyst Poisons - Alkylation processes are described herein. The alkylation process generally includes contacting an input stream including benzene with an alkylation catalyst and an alkylating agent to form an alkylation output stream including ethylbenzene. The alkylation process further includes contacting at least a portion of the alkylation output stream with a transalkylation catalyst and a benzene source to form a transalkylation output stream, wherein the benzene source is selected to minimize the amount of alkylation catalyst poisons contacting the alkylation catalyst. | 01-22-2009 |
| 20090023875 | Process for Controlling Morphology of Ziegler-Natta Catalysts - Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. | 01-22-2009 |
| 20090012214 | Performance Grade Asphalt Composition and Method of Production Thereof - An asphalt material having improved paving characteristics and processes for its preparation. An asphalt base material is heated in a mixing chamber to a temperature sufficient to melt the asphalt so that it can be stirred. A water-insoluble heavy metal soap is incorporated into the chamber in an amount effective to reduce the PAV-DSR temperature of the asphalt base material by an incremental amount of at least 1° C. Thereafter, the asphalt material is recovered from the mixing chamber to provide an asphalt product containing the heavy metal soap which exhibits a PAV-DSR temperature which is less than the PAV-DSR temperature for the corresponding base material without the addition of the heavy metal soap. The water-insoluble soap is a C | 01-08-2009 |
| 20090005526 | Tridentate Metal Catalyst for Olefin Polymerization - In accordance with the present invention, there is provided a transition metal olefin polymerization catalyst component characterized by the formula: | 01-01-2009 |
| 20080306226 | Polymerization Catalyst System Based on Monooxime Ligands - The present invention discloses active oligomerisation and polymerisation catalyst systems based on monooxime ligands. | 12-11-2008 |
| 20080281048 | Heat resistant polypropylene film - A heat resistant film that comprises at least one layer that comprises a high crystallinity propylene polymer having a melt flow rate of from 0.5 g/10 min. to 15 g/10 min. and a xylene solubles of less than 3.5%. The propylene polymer may have a melting point above 158° C. The heat resistant film may further comprise at least a second layer, which may be a heterophasic random copolymer. The heat resistant film may be, for example, a blown film, a cast film, or an oriented film, and may be used in such articles of manufacture as construction films, retort packaging, and laminated articles. | 11-13-2008 |
| 20080275286 | Freeze Dry Process for the Preparation of a High Surface Area and High Pore Volume Catalyst - The present invention provides a process for the preparation of a catalyst having a high surface area and pore volume. The process includes freeze drying an intermediary of the catalyst. The present invention further includes a catalyst prepared by a process that includes the freeze drying step. The present invention also includes a catalyst having a high acidity, as indicated by having an ammonium desorption peak at greater than about 500° C. The prevent invention further includes a method of manufacturing isomerized organic compounds using the catalyst. | 11-06-2008 |
| 20080275197 | Bimodal Polyethylene Resins That Have High Stiffness and High ESCR - A bimodal polyethylene having a high density ranging from about 0.955 to about 0.959 g/cc, an improved environmental stress cracking resistance (ESCR) of from about 400 to about 2500 hours, and an improved 0.4% flexural modulus of from about 180,000 to about 260,000 psi (1,200 MPa to about 1,800 MPa) may be formed using a Ziegler-Natta polymerization catalyst using two reactors in series. The bimodal polyethylene may have a high load melt index (HLMI) of from about 2 and about 30 dg/min and may be optionally made with a small amount of alpha-olefinic comonomer in the second reactor. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. | 11-06-2008 |
| 20080275180 | Radiation Resistant Polypropylene Materials - A polypropylene material is provided having increased radiation resistance compared to solely isotactic polypropylene. The material is formed by utilizing a syndiotactic polypropylene. The isotactic polypropylene may be an isotactic metallocene or Ziegler-Natta catalyzed polypropylene and may include an amount of syndiotactic polypropylene. The material may be used in forming a variety of materials that may undergo exposure to radiation, such as sterilization procedures using radiation. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. | 11-06-2008 |
| 20080255397 | Promotors for Controlling Acidity and Pore Size of Zeolite Catalysts for Use in Alkylation - A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethyl benzene. | 10-16-2008 |
| 20080249274 | POLYMERIZATION CATALYST SYSTEM UTILIZING EXTERNAL DONOR SYSTEMS AND PROCESSES OF FORMING POLYMERS THEREWITH - External donor systems, catalyst systems and olefin polymerization processes are described herein. The external donor systems generally include a first external donor represented by the general formula SiR | 10-09-2008 |
