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EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

EXXONMOBIL RESEARCH AND ENGINEERING COMPANY Patent applications
Patent application numberTitlePublished
20120130141CATALYST RECOVERY IN HYDROTHERMAL TREATMENT OF BIOMASS - Biomass based feeds are processed under hydrothermal treatment conditions to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment is performed in the presence of catalyst particles. The presence of the heterogeneous catalyst can modify the nature of the hydrocarbon products produced from the hydrothermal treatment. After the hydrothermal treatment, the catalyst particles can be separated from the algae-based solids, to allow for recycle of the catalyst particles.05-24-2012
20120130140REACTOR FOR ISOPARAFFIN OLEFIN ALKYLATION - A reactor for the autorefrigerant alkylation process has a reactor vessel with a lower end inlet for the refrigerant reactant and the sulfuric acid and a series of inlets for the olefin reactant at vertically spaced intervals. A flow path for the reactants is provided by co-acting baffles which define sequential reaction zones. The baffles interact with a rotary mixer with multiple impellers to provide agitation. Outlets for the vaporized refrigerant and the reaction effluent are provided at the upper end of the vessel. In the alkylation process, the liquid isoparaffin hydrocarbon reactant/refrigerant with a sulfuric acid alkylation catalyst is introduced into the lower end and passed along the extended reactant flow path with the olefin reactant introduced at intervals along the path. The reaction mixture flows in the sequence of serial reaction zones within the reactor to promote mixing of the isoparaffin reactant with the acid catalyst.05-24-2012
20120130026MITIGATION OF ELASTOMER REACTOR FOULING USING MECHANICAL VIBRATION - Method of reducing fouling in an elastomer polymerization process that includes providing a reactor capable of housing an industrial-scale elastomer polymerization reaction, and applying a mechanical force to the reactor so as to create a vibration in at least one wall of the reactor, in which fouling is reduced in the reactor. In one embodiment the reaction is an industrial scale butyl polymerization reaction and the reactor is a butyl polymerization reactor.05-24-2012
20120122230METHODS FOR IDENTIFYING HIGH FOULING HYDROCARBON AND FOR MITIGATING FOULING OF PROCESS EQUIPMENT - Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter value indicative of the fouling propensity at no less than two different temperatures, and an activation energy of fouling by the hydrocarbon stream is derived therefrom. In another method, the thus obtained parameter value at no less than two different temperatures and the activation energy are used to select proper heating fluids and operating temperature and to determine whether to add an antifoulant to the hydrocarbon stream to reduce fouling at a given temperature.05-17-2012
20120118794METHODS FOR MITIGATING FOULING OF PROCESS EQUIPMENT - Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter indicative of the fouling propensity by a regression of a series of temperature measurements data for the hydrocarbon stream exiting a test unit. In another method, an effective minimal amount of an antifoulant is added to a hydrocarbon stream to reduce fouling, where the amount of the antifoulant is determined based on the fouling propensity of the hydrocarbon stream.05-17-2012
20120118034ENGINEERED TOPSOIL FOR USE IN LAND RECLAMATION AND A METHOD OF PRODUCING THE SAME - An engineered topsoil for use in soil reclamation and a method of producing the same are disclosed that seek to replicate undisturbed native reference topsoil from near the site in need of land reclamation. The engineered topsoil is formed from a base amount of subsoil and amendment comprised of an effective amount of surrogate humin material sufficient to replicate the estimated humin organic carbon content of the native reference topsoil, and an effective amount of plant residue material sufficient to replicate the estimated non-humin organic carbon content of the native reference topsoil.05-17-2012
20120118009RECOVERY OF GREENHOUSE GAS AND PRESSURIZATION FOR TRANSPORT - A system for isolating a greenhouse gas from an exhaust gas includes a vessel having an inlet to receive an exhaust gas, and an outlet to discharge a process stream, an adsorbent contained in the vessel to selectively adsorb the greenhouse gas from the exhaust gas under suitable conditions, and a heat source to heat the adsorbent and desorb the adsorbed greenhouse gas therefrom to produce a process stream of greenhouse gas for release through the outlet.05-17-2012
20120118004ADSORPTION CHILLING FOR COMPRESSING AND TRANSPORTING GASES - A gas transport system including a conduit (e.g., a pipeline) containing a feed of a gas at a first temperature and first pressure, a source of a refrigerant from an adsorption system in thermal communication with the conduit to cool the feed of gas to a reduced temperature, and at least one compressor to receive the cooled feed of gas and increase the amount of cooled feed of gas to a second pressure, in which the second pressure is greater than the first pressure.05-17-2012
20120115763LUBRICANT COMPOSITIONS BASED ON BLOCK COPOLYMERS AND PROCESSES FOR MAKIN - Provided are lubricant compositions with improved oxidative stability and frictional and wear resistance properties for use in engine oil applications. The lubricant compositions include: i) a first base stock selected from a Group I base stock, a Group II base stock or a combination thereof at 50 to 80 wt %; ii) a block copolymer at 1 to 10 wt %; iii) a viscosity modifier at 3 to 15 wt % selected from polymers and copolymers of methacrylate, butadiene, olefins and alkylated styrenes; and iv) an additive package including a combination of antioxidants, dispersants, detergents, friction modifiers and antiwear agents at 2 to 30 wt %.05-10-2012
20120115762Process for Making Basestocks from Renewable Feedstocks - A process for converting feedstock triglycerides to lube basestocks. The process has the steps of (a) metathesizing the feedstock triglycerides with ethylene in the presence of a metathesis catalyst to form alpha olefins and medium-chain triglycerides and (b) hydroisomerizing the medium-chain triglycerides in the presence of a hydroisomerization catalyst and hydrogen to form methyl-branched triglycerides. The alpha olefins may be oligomerized in the presence of an oligomerization catalyst to form poly(alpha olefins).05-10-2012
20120115713POISON RESISTANT CATALYST SYSTEMS AND ASSOCIATED PROCESSES - Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an active catalyst component comprising a surface, and a metal oxide film coated on the surface of the active catalyst component. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as improved resistance to catalytic deactivation due to sulfur and nitrogen compounds present in the hydrocarbon feedstreams.05-10-2012
20120111768INTEGRATED INTERSTITIAL METAL HYDRIDE CATALYST SUPPORT SYSTEMS AND ASSOCIATED PROCESSES - Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprising a surface, with a metal oxide integrally synthesized and providing a coating on the surface of the interstitial metal hydride. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur and nitrogen reduction in hydrocarbon feedstreams.05-10-2012
20120111767INTERSTITIAL METAL HYDRIDE CATALYST SYSTEMS AND ASSOCIATED PROCESSES - Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride containing catalyst comprising a surface, and a Group VI/Group VIII metal sulfide coated onto the surface of the interstitial metal hydride. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.05-10-2012
20120111315IN-SITU VAPORIZER AND RECUPERATOR FOR ALTERNATING FLOW DEVICE - The present invention relates to a device for converting a liquid feed stream to a gaseous vapor stream comprising: (a) channel means having a first and second end, said channel means having a plurality of channels connecting said first and second end, said channel means having a substantially solid region and a void region, (b) inlet means for directing the liquid feed stream to the first end of the plurality of channels, and (c) outlet means for directing the gaseous vapor stream from said plurality of channels, where said channels have, at any distance d between the inlet and outlet, a geometric configuration, perpendicular to the feed flow direction, wherein the average void fraction ranges from about 0.3 to about 0.95.05-10-2012
20120103870FLUID CATALYTIC CRACKING CATALYST STRIPPING - This disclosure relates to devices, e.g., baffle plate and combination dipleg valve/baffle devices, for use in achieving rapid disengagement of entrained hydrocarbons vapors, especially in high flux spent catalyst flow exiting from a cyclone separator dipleg in a fluidized catalytic cracking (FCC) unit. The baffle plate is preferably located near and typically below the catalyst dipleg of a fluid catalytic cracking reactor or separation zone and comprises a baffle plate body member having a surface, and in preferred embodiments also includes one or more apertures located on at least a portion of the surface. The valve/baffle is located at the outlet of the catalyst dipleg and comprises a combination valve and catalyst baffle in which the valve/baffle is designed to allow the top surface of the valve/baffle to seat against the dipleg outlet until the weight of the catalyst above the valve/baffle forces it to open. This disclosure also relates to FCC units that include the devices, and FCC methods utilizing the devices.05-03-2012
20120101319CATALYTIC HYDROTHERMAL TREATMENT OF BIOMASS - Biomass based feeds are processed under hydrothermal treatment conditions, e.g., to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment is performed in the presence of a dissolved catalyst or catalyst precursor. The presence of the dissolved catalyst or catalyst precursor can modify the nature of the hydrocarbon products produced from the hydrothermal treatment.04-26-2012
20120097581Alumina Forming Bimetallic Tube for Refinery Process Furnaces and Method of Making and Using - Provided is a bimetallic tube for transport of hydrocarbon feedstocks in refinery process furnaces, and more particularly in furnace radiant coils, including: i) an outer tube layer being formed from carbon steels or low chromium steels comprising less than 15.0 wt. % Cr based on the total weight of the steel; ii) an inner tube layer being formed from an alumina forming bulk alloy including 5.0 to 10.0 wt. % of Al, 20.0 wt. % to 25.0 wt. % Cr, less than 0.4 wt. % Si, and at least 35.0 wt. % Fe with the balance being Ni, wherein the inner tube layer is formed plasma powder welding the alumina forming bulk alloy on the inner surface of the outer tube layer; and iii) an oxide layer formed on the surface of the inner tube layer, wherein the oxide layer is substantially comprised of alumina, chromia, silica, mullite, spinels, or mixtures thereof.04-26-2012
20120097289ALUMINA FORMING BIMETALLIC TUBE AND METHOD OF MAKING AND USING - Provided is a bimetallic tube for transport of hydrocarbon feedstocks in a petrochemical process unit and/or refinery process unit, including: i) an outer tube layer being formed from a steam cracker alloy including at least 18.0 wt. % Cr and at least 10.0 wt. % Ni; ii) an inner tube layer being formed from an alumina forming bulk alloy including 5.0 to 10.0 wt. % of Al, 18.0 wt. % to 25.0 wt. % Cr, less than 0.5 wt. % Si, and at least 35.0 wt. % Fe with the balance being Ni, wherein the inner tube layer is formed plasma powder welding the alumina forming bulk alloy on the inner surface of the outer tube layer; and iii) an oxide layer formed on the surface of the inner tube layer, wherein the oxide layer is substantially comprised of alumina, chromia, silica, mullite, spinels, or mixtures thereof.04-26-2012
20120096762PHOSPHORUS RECOVERY FROM HYDROTHERMAL TREATMENT OF BIOMASS - Biomass based feeds are processed under hydrothermal treatment conditions to produce a hydrocarbon liquid product and a solids portion. The solids portion can contain a portion of the phosphorus from the biomass feed. The amount of phosphorus in the solids portion can be increased for some biomass feeds by adding a multivalent metal to the feed. The phosphorus from the solids portion can be recycled for further use, such as for growth of additional biomass.04-26-2012
20120094879HYDROTHERMAL TREATMENT OF BIOMASS WITH HETEROGENEOUS CATALYST - Biomass based feeds are processed under hydrothermal treatment conditions, e.g., to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment can be performed in the presence of heterogeneous catalyst particles that can optionally include a catalyst metal or metal salt. The presence of the heterogeneous catalyst can modify the nature of the hydrocarbon products produced from the hydrothermal treatment.04-19-2012
20120093705METHOD FOR TREATING REFINERY WASTE STREAMS IN A FLUID CATALYTIC CRACKING UNIT AND AN IMPROVED CATALYTIC CRACKING UNIT FOR PROCESSING REFINERY WASTE STREAMS - A method of processing the waste stream includes introducing the waste stream into the Fluid Catalytic Cracking Unit 04-19-2012
20120088654MESOPOROUS ALUMINAS STABILIZED WITH RARE EARTH AND PHOSPHOROUS - A mesoporous oxide composition includes, other than oxygen, a major amount of aluminum and lesser amounts of phosphorus and at least one rare earth element. The compositions have high surface area and excellent thermal and hydrothermal stability, with a relatively narrow pore size distribution in the mesoporous range. These compositions may be prepared by a hydrothermal co-precipitation method using an organic templating agent. These mesoporous oxide compositions may be used as catalysts or as supports for catalysts, for example, in a fluid catalytic cracking process.04-12-2012
20120085126LOW ENERGY DISTILLATION SYSTEM AND METHOD - A distillation system for separating components fluid feed includes a stripper and a rectifier. The stripper includes an inlet to receive a feed of fluid a compressor in fluid communication with a more volatile portion of the fluid within the stripper to provide an output feed, and a reboiler in fluid communication with a less volatile portion of fluid within the stripper. The rectifier receives the output feed and includes a condenser in fluid communication with a more volatile portion of the output feed from the compressor, the condenser including an exit to remove at least one component from the more volatile portion of the output feed, and an outlet to recycle a less volatile portion of the output feed back to the stripper. Heat pipes transfer thermal energy from the rectifier to the stripper.04-12-2012
20120083914MODELING TOOL FOR PLANNING THE OPERATION OF REFINERIES - A modeling tool for determining the operation of a production facility. A variety of different activities can be modeled by the present invention, including (a) feed material selection, including quantity and timing, (b) product sales, including quantity and timing, (c) process operations, including process conditions and timing, (d) blending operations, including process conditions and timing, and/or (e) inventory management. The modeling tool may represent time using continuous-time, discrete-time, asynchronous time periods, synchronous time periods, and combinations of these various approaches.04-05-2012
20120083410PREPARATION OF HIGH ACTIVITY COBALT CATALYSTS, THE CATALYSTS AND THEIR USE - A method is provided for preparing a supported cobalt-containing catalyst having substantially homogeneously dispersed, small cobalt crystallites. The method comprises depositing cobalt nitrate on a support and then subjecting the support to a two-step decomposition protocol. In the first step, the support is heated in an oxygen-containing, substantially water-free atmosphere to about 160° C. to form an intermediate decomposition product. This intermediate product is then or hydrolyzed and reduced, or hydrolyzed, calcined and reduced.04-05-2012
20120080389SOx REMEDIATION IN MANUFACTURING OPERATIONS - Method for SOx remediation in a manufacturing operation includes providing a process stream including an organic compound and an amount of a sulfur-containing compound, an oxidation stream including at least one chemical oxidant, and combining at least a portion of the oxidant stream with at least a portion of the process stream to obtain an organic stripper feed stream, in which the amount of the sulfur-containing compound is reduced upon reaction with the at least one chemical oxidant. The method can further include directing at least a portion of the organic stripper feed stream to a combustion operation, and emitting a SOx remediated off gas from the combustion operation. A system using the disclosed method also is provided.04-05-2012
20120080357HYDROCRACKING PROCESS SELECTIVE FOR IMPROVED DISTILLATE AND IMPROVED LUBE YIELD AND PROPERTIES - This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area.04-05-2012
20120072175PROCESS FOR MAPPING OFF-SITE PIPING SYSTEMS IN A REFINERY AND/OR PETROCHEMICAL FACILITY AND A SYSTEM FOR PROVIDING EMERGENCY ISOLATION AND RESPONSE IN A REFINERY AND/OR PETROCHEMICAL FACILITY - A process of mapping piping systems associated with a refinery and petrochemical facilities is disclosed, which maps piping systems, which interconnect facility operating units with other operating units, utilities, distribution facilities and storage units. A system for aiding in the isolation of piping systems, operating units and other facility components is also disclosed. The system includes a search database having representations of the piping systems and its related components. A method of isolating an event within a facility is also disclosed. The method includes identifying the location of an event in the facility, performing a search to identify the impacted piping systems and related components, and identifying measures to isolate the event.03-22-2012
20120071991Method of Connecting Different Layers of Optimization - The present invention is a method for synchronizing multiple layers of constrained optimization with both layers having some common variables in a to processing plant. The layers of optimization can include Planning, Scheduling, Real-Time Optimization and Model Predictive Control.03-22-2012
20120065415PROCESS FOR SEPARATING SOLUTE MATERIAL FROM AN ALGAL CELL FEED SREAM - This invention provides a process for separating solute material from an algal cell feed stream. The algal cell feed stream, which contains the solute material, can be introduced into on portion of a mixer-settler vessel, and a solvent feed stream can be introduced into another portion of the vessel to mix with the algal cell feed stream, with a goal of separating at least a portion of the solute material from the algal feed stream.03-15-2012
20120065112LUBRICANT COMPOSITION WITH IMPROVED VARNISH DEPOSIT RESISTANCE - In one embodiment, a lubricating oil with favorable deposit control is disclosed. The lubricating oil comprises, a major amount of base stock selected from the group consisting of Group II, Group III, GTL and any combination thereof, a mannich based dispersant comprising at least 0.1 and less than 2.0 weight percent of the lubricating oil, a demulsifier comprising apolyoxypropylene-polyoxyethylene block copolymer in tricresyl phosphate (TCP) demulsifier and apolyether glycol demulsifier, the demulsifiers comprising at least 0.002 to less than 2.0 weight percent of the lubricating oil, wherein the lubricating oil has a deposit control value less than 60 mg/kg using 504 hour 120° C. Dry TOST sludge test and an ASTM D-1401 emulsion characteristic of less than 60 minutes at 54° C.03-15-2012
20120063981METHOD AND APPARATUS FOR REMOVING CONTAMINANT FROM FLUID - Methods, apparatus, and systems for removing contaminant in a fluid (e.g., chemical and petrochemical gas streams) using nanostructures of a sorbent material coated on plates such as a silicon wafer. A plurality of such coated plates can be assembled to form a sorption structure having channels between the plates. When a fluid containing the contaminant is directed through the channels, the contaminant is adsorbed by the nanostructures of the sorbent material.03-15-2012
20120063980Alkanolamine CO2 Scrubbing Process03-15-2012
20120063979High CO2 to Amine Adsorption Capacity CO2 Scrubbing Processes03-15-2012
20120063978IONIC LIQUIDS AS AMINE PROMOTER SOLVENTS FOR REMOVAL OF CARBON DIOXIDE - Ionic liquids are capable of acting as solvents for amine CO03-15-2012
20120063977IONIC LIQUIDS FOR REMOVAL OF CARBON DIOXIDE - Ionic liquids containing a cation with a potentially nucleophilic carbon atom bearing a relatively acidic hydrogen atom bonded to a potentially nucleophilic carbon atom, typically in the conjugated —NC(H)N— structure or a —NC(H)S— structure of imidazolium, imidazolidinium or thiazolium salts, can be capable of acting as sorbents for CO03-15-2012
20120063961FLUID INJECTION NOZZLE FOR FLUID BED REACTORS - The liquid feed nozzle assemblies for a circulating fluid bed reactor comprise (i) a throttle body premixer to combine liquid feed with atomization steam upstream of a nozzle body to form a liquid feed/steam mixture comprising liquid feed droplets; (ii) a conduit connected to the venturi premixer and to a discharge nozzle body to convey a flow of the liquid/steam mixture created by the premixer to the nozzle body; (iii) a discharge nozzle connected to the flow conduit to shear the liquid feed/steam mixture to create liquid feed droplets of reduced size and (iv) a disperser at the outlet of the discharge nozzle to provide a spray jet of liquid feed having an increased surface area relative to a cylindrical jet. The nozzle assembles are particularly useful in fluid coking units using heavy oil feeds such a tar sands bitumen.03-15-2012
20120061614NON-AQUEOUS AMINE SCRUBBING FOR REMOVAL OF CARBON DIOXIDE - A method is described for separating CO03-15-2012
20120060686Mixed Amine and Non-Nucleophilic Base CO2 Scrubbing Process for Improved Adsorption at Increased Temperatures03-15-2012
20120035308METHODS OF MAKING 6-HYDROXYHEXANOPHENONE AND 5-BENZOYLPENTANOIC ACID AND MONO OR DIESTERS THEREOF - Mono- or diester plasticizers of the formula:02-09-2012
20120028861METHOD FOR IMPROVING THE DEPOSIT FORMATION RESISTANCE PERFORMANCE OF TURBINE OILS CONTAINING AMINE ANTIOXIDANTS - The deposit formation resistance performance of turbine oils containing amine antioxidants and antiwear additives is enhanced beyond the level of that of turbine oils containing tricresyl phosphate antiwear additive by employing as the antiwear additive a 4,4′-(Isopropylidenediphenyl)bis(diphenyl phosphate).02-02-2012
20120016167HYDROPROCESSING OF BIOCOMPONENT FEEDS WITH LOW PRESSURE HYDROGEN-CONTAINING STREAMS - The invention relates to a method for forming an at least partially renewable diesel product, comprising: hydrodeoxygenating a feedstock comprising about 0.1 wt % to about 50 wt % of a fresh biocomponent portion with a relatively pure hydrogen treat gas in the presence of a hydrodeoxygenation catalyst under relatively low total pressure to form a hydrodeoxygenated product; and separating the hydrodeoxygenated product into a vapor effluent and a liquid effluent, at least a first portion of the latter being recycled to the hydrodeoxygenation step, and at least a second portion of the latter being a diesel product. Advantageously, the hydrodeoxygenation catalyst can have a relatively low catalytic activity (about 50% or less of fresh HDS/HDN activity).01-19-2012
20120004479GAS AND LIQUID PHASE HYDROPROCESSING FOR BIOCOMPONENT FEEDSTOCKS - Diesel fuel is produced from a feedstock that is at least partially biocomponent in origin. A feedstock is treated in a reactor including one or more hydrotreating zones having a continuous gas phase. The liquid effluent from the hydrotreating zones is then hydroprocessed in a hydroprocessing zone having a continuous liquid phase, such as a hydroprocessing zone in the same reactor. The hydroprocessing zone can be operated under effective catalytic dewaxing conditions.01-05-2012
20120004478TWO STAGE HYDROPROCESSING WITH DIVIDED WALL COLUMN FRACTIONATOR - A divided wall column can allow for fractionation of multiple streams while maintaining separate product qualities. Effluents from multiple stages of a reaction system can be processed in a single divided wall column. The divided wall column can produce multiple cuts from each separated area, as well as at least one output from a common area. At least one reaction stage can advantageously have a continuous liquid phase environment.01-05-2012
20120004477LIQUID PHASE DISTILLATE DEWAXING - Hydrocarbon feeds can be hydrotreated in a continuous gas-phase environment and then dewaxed in a liquid-continuous reactor. The liquid-continuous reactor can advantageously be operated in a manner that avoids the need for a hydrogen recycle loop. A contaminant gas can be added to the hydrogen input for the liquid-continuous reactor to modify the hydrogen consumption in the reactor.01-05-2012
20120000829PROCESS FOR THE PREPARATION OF GROUP II AND GROUP III LUBE BASE OILS - The preparation of Group II and Group III lube base oils wherein liquid-continuous hydrotreating is used to treat a lube oil raffinate. The hydrotreated lube oil raffinate is then sent to a dewaxing stage that can be either a solvent or catalytic dewaxing stage.01-05-2012
20120000824INTEGRATED GAS AND LIQUID PHASE PROCESSING OF BIOCOMPONENT FEEDSTOCKS - A mineral feed can be hydrotreated in a trickle-bed reactor or other stage in a continuous gas-phase environment. The effluent from the hydrotreatment stage can be separated to remove gas-phase impurities. The remaining liquid effluent from the hydrotreating stage can then be introduced, in total or in part, into a second stage/reactor. A feed of biocomponent origin can also be introduced into the second stage/reactor. The second stage/reactor can be operated to perform deoxygenation of the mixture of biocomponent feed and hydrotreated liquid effluent in a continuous liquid phase environment.01-05-2012
20120000818PROCESS FOR THE PREPARATION OF GROUP II AND GROUP III LUBE BASE OILS - A process for the preparation of Group II and Group III lube oil base stocks wherein liquid-continuous aromatics saturation is used to treat lube hydrocrackate. The treated hydrocrackate is then be sent to dewaxing unit and then optionally to a hydrotreating step.01-05-2012
20120000817Production of Low Color Middle Distillate Fuels - In a process for producing a low color diesel and/or kerosene fuel, a middle distillate feed can be supplied to a reactor having at least one first catalyst bed containing a first desulfurization and/or isomerization catalyst and at least one second catalyst bed containing a decolorization catalyst downstream from the first catalyst bed(s). The feed can be reacted with the hydrogen in the presence of the first catalyst at a temperature from about 290° C. to about 430° C. to produce a first liquid effluent, which can be cooled by about 10° C. to about 40° C. with a quench medium and cascaded to the at least one second catalyst bed. The cooled first liquid effluent can then be reacted with hydrogen in the presence of the decolorization catalyst at a temperature from about 280° C. to about 415° C. to produce a second effluent having an ASTM color less than 2.5.01-05-2012
20120000792Electrochemical Treatment of Heavy Oil Streams Followed by Caustic Extraction or Thermal Treatment - This invention relates to a process for electrochemical conversion of dibenzothiophene type molecules of petroleum feedstreams selectively to mercaptan compounds that can then be more easily removed from the electrochemically treated product stream by either caustic extraction or thermal decomposition of the thiol functionality to hydrogen sulfide. The conversion of dibenzothiophenes to mercaptans is performed by electrochemical means in the substantial absence of hydrogen and in the substantial absence of water.01-05-2012
20110315603SPENT CATALYST RISER DISTRIBUTOR - The present invention relates to an improved design for use in fluid cracking processes, preferably used in either a fluid catalytic cracking (“FCC”) process or a fluid coking process. In particular, the present invention relates to an apparatus and process for improving the separation and distributing spent catalyst and gases in a spent catalyst riser associated with a fluid cracking process, and most preferably for use in a spent catalyst riser associated with an FCC regenerator vessel. A novel catalyst distributor design and associated processes are presented herein which significantly improve combustion in the dense-phase fluidized catalyst bed of a regenerator and results in improved regenerator dense bed combustion and lower migration of oxygen into the regenerator overhead region. As a result, afterburn is significantly reduced in the regenerator and higher catalyst bed temperatures are achieved with significantly more uniform bed temperatures due to the improved combustion characteristics in the dense-phase fluidized catalyst bed.12-29-2011
20110315599INTEGRATED HYDROCRACKING AND DEWAXING OF HYDROCARBONS - An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or with only a high pressure separation so that the dewaxing still occurs under sour conditions. Various combinations of hydrotreating, catalytic dewaxing, hydrocracking, and hydrofinishing can be used to produce fuel products and lubricant base oil products.12-29-2011
20110315596INTEGRATED HYDROCRACKING AND DEWAXING OF HYDROCARBONS - An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants. The integrated process includes an initial dewaxing of a feed under sour conditions, optional hydrocracking of the dewaxed feed, and a separation to form a first diesel product and a bottoms fraction. The bottoms fraction is then exposed to additional hydrocracking and dewaxing to form a second diesel product and optionally a lubricant base oil product. Alternatively, a feedstock can be hydrotreated, fractionated, dewaxed, and then hydrocracked to form a diesel fuel and a dewaxed, hydrocracked bottoms fraction that is optionally suitable for use as a lubricant base oil.12-29-2011
20110294657HYDROPROCESSING CATALYSTS AND THEIR PRODUCTION - Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group and at least 10 carbon atoms or (ii) a second organic compound containing at least one carboxylic acid group and at least 10 carbon atoms, but not both, wherein the reaction product contains additional unsaturated carbon atoms, relative to the first or second organic compound, wherein the metals of the catalyst precursor composition are arranged in a crystal lattice, and wherein the reaction product is not located within the crystal lattice. A process for preparing the catalyst precursor composition is also described, as is sulfiding the catalyst precursor composition to form a hydroprocessing catalyst.12-01-2011
20110294656HYDROPROCESSING CATALYSTS AND THEIR PRODUCTION - Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group, and (ii) a second organic compound separate from said first organic compound and containing at least one carboxylic acid group. A process for preparing the catalyst precursor composition is also described, as is sulfiding the bulk mixed metal oxide catalyst precursor composition to form a hydroprocessing catalyst.12-01-2011
20110289842Corrosion Resistant Gasifier Components - The present invention relates to an improved gasifier reactor design. In particular, the present invention relates to improved design of gasifier reactor faceplates, gasifier reactor walls, gasifier reactor cooling tubes, and gasifier reactor walls with integrated cooling channels. The present invention utilizes aluminum nitride and/or aluminum nitride/metal composite materials which promote many benefits to the present design herein, including improved corrosion and erosion resistively as compared to high alloy metal materials.12-01-2011
20110287990METHOD FOR REDUCING ONE OR MORE OF DEPOSITS AND FRICTION OF A LUBRICATING OIL - The present invention is directed to a method for improving one or more of the control of deposit formation and friction in an engine lubricated using a lubricating oil comprising a base oil and additives by employing as the additive the necessary combination of a borated hydroxyl saturated hydrocarbyl ester amide-amine mixture, zinc dialkyl dithiophosphate, and metal salicylate detergent, the deposit formation and friction being improved as compared to a lubricating oil containing the borated hydroxyl saturated hydrocarbyl ester amide-amine mixture, zinc dialkyl dithiophosphate and a detergent other than metal salicylate, such as metal phosphate and/or metal sulfonate.11-24-2011
20110282118METHOD FOR MAKING DIESEL WITH LOW POLYAROMATIC CONTENT - Distillate feeds are hydroprocessed to produce a product having a low content of polyaromatic hydrocarbons (PAHs). The hydroprocessing includes dewaxing and aromatic saturation of the feed. The temperature of the aromatic saturation process can be controlled to make a distillate product having a desired aromatic content, such as less the 0.02 wt % of polyaromatic hydrocarbons having three or more aromatic rings.11-17-2011
20110277888CHROMIUN-ENRICHED OXIDE CONTAINING MATERIAL AND PREOXIDATION METHOD OF MAKING THE SAME TO MITIGATE CORROSION AND FOULING ASSOCIATED WITH HEAT TRANSFER COMPONENTS - A method of providing sulfidation corrosion resistance and corrosion induced fouling resistance for a heat transfer component is disclosed. The heat transfer component includes a heat exchange surface formed from a chromium-enriched oxide containing material formed from the composition δ, ε, and ζ, wherein ζ is a steel containing at least about 5 to about 40 wt. % chromium, ε is a chromium enriched oxide (M11-17-2011
20110277377HYDROPROCESSING OF PYROLYSIS OIL AND ITS USE AS A FUEL - This invention provides low sulfur fuels, particularly low sulfur bunker fuels, comprising hydroprocessed pyrolysis oil. The hydroprocessed pyrolysis oil can be produced using a catalyst suited to processing pyrolysis oils that may be relatively high in water content and under relatively low severity conditions to limit water formation, while making the hydroprocessed pyrolysis oil more stable than prior to hydroprocessing. The pyrolysis oil can be converted to a more stable hydroprocessed product, e.g., by converting at least a majority of the aldehydes, ketones, and/or carboxylic acids in the pyrolysis oil to more highly stable compounds, such as alcohols. The hydroprocessed product can be particularly suited as a blend component for producing a variety of reduced sulfur fuels.11-17-2011
20110276165Integrated Expert System for Identifying Abnormal Events in an Industrial Plant - A computer-implemented integrated expert system for the identification of abnormal events in an industrial plant. The expert system integrates a model-based expert system with a rule-based expert system. The model-based expert system receives data on the operating conditions of a process unit in the industrial plant and calculates one or more results that determine whether the process unit is operating abnormally. The rule-based expert system also receives data on the operating conditions of the process unit and applies its rules to the process data. The rule-based expert system also applies its rules to the one or more results generated by the model-based expert system. The integrated system may also suppress any redundant messages generated by the model-based expert system.11-10-2011
20110275877Separation of Normal Paraffins from Isoparaffins Using Rapid Cycle Pressure Swing Adsorption - The separation of normal paraffins from isoparaffins using rapid cycle pressure swing adsorption. The present invention also relates to an isomerization process wherein normal paraffins are converted to isoparaffins resulting in an effluent stream containing a mixture of normal paraffins and isoparaffins, which effluent stream is sent to a rapid cycle pressure swing adsorption unit to perform the separation of normal paraffins from isoparaffins.11-10-2011
20110263469POLY (ALKYL EPOXIDES), PROCESS FOR MAKING, AND LUBRICANT COMPOSITIONS HAVING SAME - A process for making a poly(alkyl epoxide). The process has the step of polymerizing one or more alkyl epoxide monomers in the presence of a cationic catalyst according to the following sequences:10-27-2011
20110259793Low pressure production of low cloud point diesel - A diesel fuel product with beneficial cold flow properties can be produced. A suitable feedstock for forming a diesel boiling range product can be hydrotreated to have a sulfur content of at least about 100 wppm and then dewaxed. This two stage process can allow for production of an arctic or winter diesel without use of high pressures. Optionally, a divided wall column fractionator can be used to allow a single separation stage to handle the effluent from both the hydroprocessing and the dewaxing stages.10-27-2011
20110257317TETRACARBOXYLIC ESTER PLASTICIZERS - Tetraesters of a C10-20-2011
20110245545METHODS FOR PRODUCING PYROLYSIS PRODUCTS - The present invention provides pyrolysis products that have greater stability than pyrolysis products obtained from conventional pyrolysis production processes. The invention involves pyrolyzing a hydrocarbon feedstock in the presence of a basic metal oxide catalyst to produce a pyrolysis product. The pyrolysis product of the present invention can advantageously be particularly high in alcohol content.10-06-2011
20110240526Debris Separation Device and Method of Use - A device for use in separating debris from a flowing stream which comprises a substantially hollow, substantially conical shaped structure comprising a top end member and a plurality of adjacently positioned side members angularly extending from a top end member to a substantially circular bottom end. The top end member has a smaller diameter than the circular bottom end. The adjacently positioned side members are configured to provide multiple tiers in a vertical plane in the conically shaped structure. The multiple tiers comprise a plurality of apertures in a horizontal plane in the conically shaped structure. The plurality of apertures are configured for separating large debris particles, generally formed from coke and spent catalyst, from a flowing fluidized catalytic cracking stream, and directing the captured debris toward the circular bottom end of the device. A method of separating debris from a flowing stream is also provided. In particular, the device and method are useful for separating coke deposits in a fluidized catalytic cracking (FCC) process.10-06-2011
20110240521HYDROPROCESSING OF GAS OIL BOILING RANGE FEEDS - A system and method for producing fuels and lubricant basestocks from gas oil boiling range feeds is provided. Desulfurization and conversion stages are used to form fuel and lubricant products. The product from a desulfurization stage can be fractionated, and a portion of the fractionated bottoms can be used as an input feed for a conversion or hydrocracking stage. The configuration can advantageously allow for reduced amounts of catalyst in the conversion stage.10-06-2011
20110239692UTILIZATION OF WASTE HEAT USING FIBER SORBENT SYSTEM AND METHOD OF USING SAME - The disclosed subject matter relates to process modifications and apparatus designs that are conducive towards minimizing temperature swings (ΔT) useful to yield operating pressures that provide work and/or refrigeration (e.g., electricity and/or refrigeration) in sorption systems. Such process modifications and designs are particularly suited to make use of waste heat in industrial process, (e.g., a chemical processing or petrochemical refining operation) in which low grade heat source(s) are used to drive the sorption system.10-06-2011
20110233042BIOMASS CONVERSION PROCESS - Biomass is used as a co-feed for a heavy petroleum oil coking process to improve the operation of the coking process and to utilize biomaterial for the production of transportation fuels. The coking process may be a delayed coking process or a fluidized bed coking process and in each case, the presence of the biomass will decrease the coke drying time so reducing coke handling problems in the unit besides forming a superior coke product. In the case of a fluidized bed coking process using a gasifier for the coke, the addition of an alkali metal salt improves the operation of the gasifier.09-29-2011
20110232493METHOD OF PROTECTING A SOLID ADSORBENT AND A PROTECTED SOLID ADSORBENT - The present application provides a protected solid adsorbent that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.09-29-2011
20110232305SYSTEMS AND METHODS FOR GENERATING POWER AND CHILLING USING UNUTILIZED HEAT - The present application provides a sorption system for generating power and chilling that includes at least one absorber to absorb a working fluid in a liquid sorbent, a pump in fluid communication with the absorber to yield a feed of pressurized liquid sorbent and absorbed working fluid, a heat source to heat the feed of pressurized liquid sorbent and absorbed working fluid to yield a feed of working fluid at a supercritical state, a generator in fluid communication with the feed of working fluid at a supercritical state to yield power and a feed of working fluid in an at least partially condensed state, and an evaporator in fluid communication with the feed of working fluid in the at least partially condensed state to yield chilling and uncondensed working fluid. Additional systems and method for the generating power and chilling are provided.09-29-2011
20110232164BIOMASS OIL CONVERSION PROCESS - A biomass pyrolysis oil is used as a co-feed for a heavy petroleum oil coking process to improve the operation of the coking process and to utilize biomaterial for the production of transportation fuels. The coking process may be a delayed coking process or a fluidized bed coking process and in each case, the presence of the biomass pyrolysis oil will decrease the coke drying time while reducing coke handling problems in the unit besides forming a superior coke product. In the case of a fluidized bed coking process using a gasifier for the coke, the addition of an alkali metal salt improves the operation of the gasifier.09-29-2011
20110232163BIOMASS OIL CONVERSION USING CARBON MONOXIDE AND WATER - A pyrolysis oil derived from a lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the oil with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass oil from 0.5:1 to 5.0:1, to dissolve the oil into the reaction mixture and depolymerize, deoxygenate and hydrogenate the oil, so converting it into liquid transportation fuel precursors.09-29-2011
20110232162BIOMASS CONVERSION USING CARBON MONOXIDE AND WATER - A lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the biomass material with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass material from 0.5:1 to 5.0:1, to dissolve the biomass material into the reaction mixture and depolymerize, deoxygenate and hydrogenate the lignocellulose biomass material, so converting the biomass material into liquid transportation fuel precursors.09-29-2011
20110232161BIOMASS OIL CONVERSION PROCESS - Biomass pyrolysis oil is converted into precursors for hydrocarbon transportation fuels by contacting the oil with liquid superheated water or supercritical water to depolymerize and deoxygenate the components of the oil and form the transportation fuel precursors. Temperatures above 200° C. and preferably above 300° C. are preferred with supercritical water at temperatures above 374° C. and pressures above 22 MPA providing the capability for fast conversion rates.09-29-2011
20110232160BIOMASS CONVERSION PROCESS - Biomass material is converted into precursors for hydrocarbon transportation fuels by contacting the biomass with liquid superheated water or supercritical water to depolymerize and deoxygenate the biomass into the transportation fuel precursors. Temperatures above 200° C. and preferably above 300° C. are preferred with supercritical water at temperatures above 374° C. and pressures above 22 MPa providing a capability for higher conversion rates.09-29-2011
20110231335SYSTEM FOR OPTIMIZING TRANSPORTATION SCHEDULING - A computer modeling application is disclosed for finding the optimal solution to maximize total net margin, for the assignment of vehicles (e.g., especially vessels) in an available fleet to perform a set of voyages to transport cargo comprising one or more bulk products during a planning period, as well as an apparatus and method employing the same. The fleet can include term vehicles and spot vehicles. The vehicles, voyages, and cargos can be heterogeneous. In one embodiment, the vehicles are crude carrier vessels and the bulk products are different grades of crude oil. To increase speed, the model is broken into linear programming and mixed integer (linear) programming problems. The model can be run on a real-time basis to support complex scheduling operations.09-22-2011
20110230680LUBRICATING COMPOSITIONS CONTAINING ASHLESS CATALYTIC ANTIOXIDANT ADDITIVES - The invention comprises lubricating compositions and hydraulic to fluids containing N,N′-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids. The invention further comprises a method of making N,N′-diaryl-o-phenylenediamine compounds.09-22-2011
20110220549Low Small Mesoporous Peak Cracking Catalyst and Method of Using - This invention relates to the composition, method of making and use of a fluidized catalytic cracking (“FCC”) catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 Å (angstrom) range as determined by nitrogen adsorption measurements. FCC catalysts made from this new zeolite exhibit improved rates of heavy oil cracking heavy oil bottoms conversions and gasoline conversions. The fluidized catalytic cracking catalysts herein are particularly useful in fluidized catalytic cracking (“FCC”) processes for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms.09-15-2011
20110220415ULTRA-LOW FRICTION COATINGS FOR DRILL STEM ASSEMBLIES - Provided are drill stem assemblies with ultra-low friction coatings for subterraneous drilling operations. In one form, the coated drill stem assemblies for subterraneous rotary drilling operations include a body assembly with an exposed outer surface including a drill string coupled to a bottom hole assembly, a coiled tubing coupled to a bottom hole assembly, or a casing string coupled to a bottom hole assembly and an ultra-low friction coating on at least a portion of the exposed outer surface of the body assembly, hardbanding on at least a portion of the exposed outer surface of the body assembly, an ultra-low friction coating on at least a portion of the hardbanding, wherein the ultra-low friction coating comprises one or more ultra-low friction layers, and one or more buttering layers interposed between the hardbanding and the ultra-low friction coating. The coated drill stem assemblies disclosed herein provide for reduced friction, vibration (stick-slip and torsional), abrasion, and wear during straight hole or directional drilling to allow for improved rates of penetration and enable ultra-extended reach drilling with existing top drives.09-15-2011
20110220348Coated Oil and Gas Well Production Devices - Provided are coated oil and gas well production devices and methods of making and using such coated devices. In one form, the coated device includes one or more cylindrical bodies, hardbanding on at least a portion of the exposed outer surface, exposed inner surface, or a combination of both exposed outer or inner surface of the one or more cylindrical bodies, and a coating on at least a portion of the inner surface, the outer surface, or a combination thereof of the one or more cylindrical bodies. The coating includes one or more ultra-low friction layers, and one or more buttering layers interposed between the hardbanding and the ultra-low friction coating. The coated oil and gas well production devices may provide for reduced friction, wear, erosion, corrosion, and deposits for well construction, completion and production of oil and gas.09-15-2011
20110219802SORPTION SYSTEMS HAVING IMPROVED CYCLE TIMES - The present invention relates to process modifications and apparatus designs that are conducive towards minimizing temperature swings (ΔT) useful to yield operating pressures that provide work and/or refrigeration (e.g., electricity and/or refrigeration) in sorption systems. Such process modifications and designs are particularly suited to make use of waste heat an industrial process, (e.g., a chemical processing or petrochemical refining operation) in which low grade heat source(s) are used to drive the sorption system.09-15-2011
20110219770METHODS OF UTILIZING WASTE HEAT FOR CREATING A PRESSURIZED WORKING FLUID - A method of utilizing waste heat to create a pressurized working fluid is disclosed. The method includes providing a vessel containing a sorbent system, introducing a feed of waste heat to a heat exchanger external to the vessel to heat a feed of working fluid, introducing the heated working fluid from the heat exchanger to the vessel to obtain pressurized working fluid, and directing the pressurized working fluid from the vessel to a work component. The method is particularly suited to make use of waste heat an industrial process, (e.g., a chemical processing or petrochemical refining operation) in which low grade heat source(s) are used to drive the sorption system.09-15-2011
20110219671DEWAXING OF RENEWABLE DIESEL FUEL - Feeds containing a hydrotreated biocomponent portion, and optionally a mineral portion, can be processed under catalytic conditions for isomerization and/or dewaxing. The sulfur content of the feed for dewaxing can be selected based on the hydrogenation metal used for the catalyst. Diesel fuel products with improved cold flow properties can be produced.09-15-2011
20110219669Hydroprocessing of diesel range biomolecules - Non-hydrotreated biocomponent feeds can be mixed with mineral feeds and processed under catalytic isomerization/dewaxing conditions. The catalytic isomerization/dewaxing conditions can be selected to advantageously also substantially deoxygenate the mixed feed. Diesel fuel products with improved cold flow properties can be produced.09-15-2011
20110217218Systems and Methods for Acid Gas Removal - A method and system for the selective removal of CO09-08-2011
20110209525Simulation Distillation by Comprehensive Two-Dimensional Gas Chromatography - A method to simulate distillation of a petroleum stream by comprehensive two-dimensional gas chromatography including the step of separating said petroleum stream with a two-dimensional gas chromatograph to determine polarity as a function of temperature, and integrating vertically the two-dimensional gas chromatograph at a given temperature to determine signal intensity as a function of temperature.09-01-2011
20110208576FUEL LOYALTY REWARDS AND INCENTIVE PROGRAM - A computer-implemented method of providing a discount for fuel to a customer is disclosed. The method includes identifying a customer to a retail store using a first reader device in operative communication with a host computer, which is communication with an identification module. The identification module creates and associates a customer with a customer identification record. A preliminary award record is created and maintained, which includes a discount-per-gallon award for fuel associated with the customer identification record in response to a purchase recognized by the host computer. The host computer adds subsequent preliminary award records to the preliminary award record associated with a customer identification to create an intermediate award record, which includes all the discount-per-gallon awards associated with the customer. A purchase of fuel is initiated by the purchaser at a fuel station with at least one fuel pump. The customer is identified by the fuel pump controller in operative communication with both a second reader device and a second identification module. The intermediate award record is retrieved by the host computer from a database and the host computer recognizes that the customer is eligible for a fuel station supplementary discount. A final discount record received by the customer and the customer is provided with the final discount associated with the final discount award record.08-25-2011
20110207641PROCESS FOR PREPARING FINE POWDER POLYUREA AND GREASES THEREFROM - Polyurea compounds are prepared by reacting amines and polyisoyanates in the presence of a liquid diluent in a high-pressure impingement mixing device under conditions sufficient to produce polyurea compounds having the consistency of a powder and in which diluent is dispersed.08-25-2011
20110207639METHOD FOR IMPROVING THE FUEL EFFICIENCY OF ENGINE OIL COMPOSITIONS FOR LARGE LOW AND MEDIUM SPEED ENGINES BY REDUCING THE TRACTION COEFFICIENT - The present invention is directed to a method for improving the fuel efficiency of large low and medium speed engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using a blend consisting of one or more Group I base oils having a kinematic viscosity at 100° C. of from 2 to less than 12 mm08-25-2011
20110206563CIRCULATING FLUID BED REACTOR WITH IMPROVED CIRCULATION - A circulating fluid bed reactor such as that used in fluid coking processes has a circular dense bed reaction section above the reactor base where the fluidizing gas is injected and a plurality of frusto-conical baffles in the dense bed reaction section, each of which depends downwardly and radially inwards from the reactor wall to a lower, inner edge defining a central aperture. The baffles are preferably provided with downcomers which permit downward flow of solids and upward flow of gas through the baffles.08-25-2011
20110203791COATED SLEEVED OIL AND GAS WELL PRODUCTION DEVICES - Provided are coated sleeved oil and gas well production devices and methods of making and using such coated sleeved devices. In one form, the coated sleeved oil and gas well production device includes one or more cylindrical bodies, one or more sleeves proximal to the outer diameter or inner diameter of the one or more cylindrical bodies, hardbanding on at least a portion of the exposed outer surface, exposed inner surface, or a combination of both exposed outer or inner surface of the one or more sleeves, and a coating on at least a portion of the inner sleeve surface, the outer sleeve surface, or a combination thereof of the one or more sleeves. The coating includes one or more ultra-low friction layers, and one or more buttering layers interposed between the hardbanding and the ultra-low friction coating. The coated sleeved oil and gas well production devices may provide for reduced friction, wear, erosion, corrosion, and deposits for well construction, completion and production of oil and gas.08-25-2011
20110202328System for the determination of selective absorbent molecules through predictive correlations - A method for determining absorbent molecules that are effective for the property of acid gas removal from feedstreams comprising a) determining a set of known molecules that are effective for acid gas removal, b) defining descriptive parameters (descriptors) that correlate with the structure of molecules with known acid gas removal, c) assigning a value to each descriptor for each of the known molecules and developing a quantitative structure and property relationship (QSPR), and d) generating molecular structures that will be effective for acid gas removal from the structure and property relationship.08-18-2011
20110196116POLYMERIZATION PROCESSES FOR BROADENED MOLECULAR WEIGHT DISTRIBUTION - Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.08-11-2011
20110196115POLYMERIZATION PROCESSES FOR BROADENED MOLECULAR WEIGHT DISTRIBUTION - Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.08-11-2011
20110195884METHOD FOR IMPROVING THE FUEL EFFICIENCY OF ENGINE OIL COMPOSITIONS FOR LARGE LOW AND MEDIUM SPEED ENGINES BY REDUCING THE TRACTION COEFFICIENT - The present invention is directed to a method for improving the fuel efficiency of engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using a blend of one or more first base stock(s) selected from Group II base stock, Group III base stock and Group IV base stock and a second base stock selected from polyisobutylene (PIB) and, preferably, additized with a detergent.08-11-2011
20110195883METHOD FOR IMPROVING THE FUEL EFFICIENCY OF ENGINE OIL COMPOSITIONS FOR LARGE LOW AND MEDIUM SPEED GAS ENGINES BY REDUCING THE TRACTION COEFFICIENT - The present invention is directed to a method for improving the fuel efficiency of large engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using at least two base stocks of different kinematic viscosity wherein the differences in kinematic viscosity between the base stocks is at least 32 mm08-11-2011
20110195882METHOD FOR IMPROVING THE FUEL EFFICIENCY OF ENGINE OIL COMPOSITIONS FOR LARGE LOW, MEDIUM AND HIGH SPEED ENGINES BY REDUCING THE TRACTION COEFFICIENT - The present invention is directed to a method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient of the oil by formulating the oil using at least two base stocks of different kinematic viscosity wherein the differences in kinematic viscosity between the base stocks is at least 30 mm08-11-2011
20110195878METHOD FOR IMPROVING THE FUEL EFFICIENCY OF ENGINE OIL COMPOSITIONS FOR LARGE LOW AND MEDIUM SPEED ENGINES BY REDUCING THE TRACTION COEFFICIENT - The present invention is directed to a method for improving the fuel efficiency of low and medium speed engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using at least two base stocks of different kinematic viscosity wherein the differences in kinematic viscosity between the base stocks is at least 30 mm08-11-2011
20110192766DEWAXING CATALYSTS - A supported catalyst comprises a zeolite having a silica to alumina molar ratio of 500 or less, a first metal oxide binder having a crystallite size greater than 200 Å and a second metal oxide binder having a crystallite size less than 100 Å, wherein the second metal oxide binder is present in an amount less than 08-11-2011
20110190557HYDROPROCESSING CATALYSTS AND THEIR PRODUCTION - In a process for producing a hydroprocessing catalyst, a particulate metal oxide composition comprising an oxide of at least one first metal selected from Group 6 of the Periodic Table of the Elements can be mixed with particles of a sulfide of at least one second metal selected from Groups 8 to 10 of the Periodic Table of the Elements to produce a particulate catalyst precursor. The particulate catalyst precursor can then be sulfided under conditions sufficient to at least partially convert the particulate catalyst precursor into a layered metal sulfide having defect sites associated with the second metal sulfide.08-04-2011
20110185898HYDROGEN UTILIZATION WITHIN A REFINERY NETWORK - Hydrogen can be recovered in a refinery network using a combination of a cycling adsorber unit and a membrane separation unit. A membrane separation unit can be used to generate at least a portion of the purge hydrogen stream for the cycling adsorber unit. This can reduce the portion of the hydrogen product stream from the cycling adsorber unit required for regeneration of the adsorbent.08-04-2011
20110184105Phenylene Oxo-Diester Plasticizers and Methods of Making - A process for making non-phthalate, 1,2-phenylene oxo-diester plasticizers for polymer compositions, by selectively hydrogenating naphthalene to form a partially hydrogenated naphthalene, oxygenating said partially hydrogenated naphthalene to form phenylene diacids, and esterifying said phenylene diacids with oxo-alcohols to form 1,2-phenylene oxo-diesters. Also a process for making phenylene oxo-diester plasticizers by selectively brominating xylenes to form bisbromomethylbenzene, catalytic carboalkoxylation of the bromo-compound to form phenylene diacetate, followed by transesterification to form the phenylene oxo-diester.07-28-2011
20110180457SELECTIVE DESULFURIZATION OF NAPHTHA USING REACTION INHIBITORS - A reaction inhibitor can be used to reduce catalyst activity at the beginning of a naphtha selective hydrodesulfurization process. The use of the reaction inhibitor can allow greater flexibility in selecting the reaction conditions to accommodate both the start and end of the hydrodesulfurization process. The reaction inhibitor can be removed during the hydrodesulfurization process, possibly in conjunction with modification of the reaction temperature, in order to maintain a substantially constant amount of sulfur in the naphtha product.07-28-2011
20110180453Catalytic Dewaxing Process - In a catalytic dewaxing process, a catalyst comprising from 40 to 80 wt % of ZSM-48 having a silica to alumina molar ratio of less than 200:1 and from 0.3 to 1.5 wt % of a metal or metal compound from Groups 8 to 10 of the Periodic Table of the Elements is provided in a reaction zone. The catalyst is periodically contacted in the reaction zone under dewaxing conditions with a first hydrocarbon feedstock having a wax content of less than 50 wt % and with a second hydrocarbon feedstock having a wax content of 50 wt % or more.07-28-2011
20110174684Sweet or Sour Service Catalytic Dewaxing in Block Mode Configuration - Sweet and sour lubricant feeds are block and continuous processed to produce lubricant basestocks. Total liquid product yields at a desired pour point are maintained for catalytic dewaxing of both sweet and sour conditions. The desired pour point is achieved for both the sweet and sour feeds by varying the catalytic dewaxing reaction temperature as a function of sulfur content entering the reactor.07-21-2011
20110163009HYDROPROCESSING OF HIGH NITROGEN FEED USING BULK CATALYST - Methods are provided for hydrotreating high nitrogen feeds with improved results for nitrogen removal, aromatic saturation, and/or sulfur removal. The method includes hydrotreating the feed with a supported hydrotreating catalyst followed by a bulk metal catalyst, the hydrotreated effluent of which can be suitable for use as a feed to an FCC reactor.07-07-2011
20110162751Protective Coatings for Petrochemical and Chemical Industry Equipment and Devices - Provided are coated petrochemical and chemical industry devices and methods of making and using such coated devices. In one form, the coated petrochemical and chemical industry device includes a petrochemical and chemical industry device including one or more bodies, and a coating on at least a portion of the one or more bodies, wherein the coating is chosen from an amorphous alloy, a heat-treated electroless or electro plated based nickel-phosphorous composite with a phosphorous content greater than 12 wt %, graphite, MoS07-07-2011
20110160487ITQ-40, New Crystalline Microporous Material - ITQ-40 (INSTITUTO DE TECNOLOGÍA QUÍMICA number 40) is a new crystalline microporous material with a framework of tetrahedral atoms connected by atoms capable of bridging the tetrahedral atoms, the tetrahedral atom framework being defined by the interconnections between the tetrahedrally coordinated atoms in its framework. ITQ-40 can be prepared in silicate compositions with an organic structure directing agent. It has a unique X-ray diffraction pattern, which identifies it as a new material.06-30-2011
20110160107Lubricant Base Stocks Based on Block Copolymers and Processes For Making - Provided is a block copolymer having an “A” block of a functionalized hydrocarbon moiety including one or more functional end groups selected from the group consisting of: epoxides, amines, acids, acid chlorides, acid anhydrides, halogens, vinyl or vinylidene double bond, aromatic rings and thiols, and a “B” block of a functionalized polyether moiety including one or more functional end groups selected from the group consisting: epoxides, amines, acids, acid chlorides, acid anhydrides, halogens, vinyl or vinylidene double bond, aromatic rings and thiols. The end group of the polyether moiety is different than the end group of the hydrocarbon moiety, and the hydrocarbon moiety and the polyether moiety are copolymerizable therewith. Preferably, the hydrocarbon moiety is a poly-α-olefin and the polyether moiety is a polyalkylene glycol.06-30-2011
20110155636HYDROPROCESSING OF BIOCOMPONENT FEEDSTOCKS WITH LOW PURITY HYDROGEN-CONTAINING STREAMS - A biocomponent feedstock can be hydroprocessed using a hydrogen-containing refinery as a source of hydrogen gas. A relatively low cost catalyst, such as a water gas shift catalyst and/or spent hydrotreating catalyst, can be used as a hydrogenation catalyst for the process. The hydroprocessing can allow for olefin saturation and/or deoxygenation of the biocomponent feed by using a relatively low value refinery stream, e.g., containing from about 20 mol % to about 60 mol % hydrogen.06-30-2011
20110152594PROCESS AND SYSTEM TO CONVERT METHANOL TO LIGHT OLEFIN, GASOLINE AND DISTILLATE - The present invention provides a process for forming a refined hydrocarbon that includes providing a feed including methanol, dimethyl ether or a mixture thereof, and contacting the feed with a methanol conversion catalyst under suitable conditions to yield an intermediate composition including olefins having at least two carbon atoms. The intermediate composition is introduced to an oligomerization catalyst under suitable conditions to yield gasoline boiling range components and distillate boiling range components.06-23-2011
20110152062DRYING DEVICE FOR PRODUCING SMALL QUANTITIES OF CONTROLLED PARTICLE SIZE CATALYSTS WHICH ARE APPROPRIATE FOR USE IN FLUIDIZED BED OPERATIONS SUCH AS FLUID CATALYTIC CRACKING - Catalysts for experimentation are produced having a controlled matrix pore structure. The manufacturing process utilizes tape casting in the drying procedure in which a catalyst slurry is cast on a substrate and dried at a temperature of between about 50° C. to 200° C. for a period of time of about 0.1 to 1.0 hour. The dried catalyst particles can be removed from the substrate by several techniques, including scraping, burning, and deforming the substrate material, The resulting catalytic particles can be produced in an amount of about ca. 3 g to 300 g from slurries with volumes between 5 cc to 500 cc, which are suitable for small scale FCC reactors and for high throughput experimentation.06-23-2011
20110151162Process for Making Triglyceride Plasticizer - Provided are processes for making, and processes for using triglycerides as plasticizers. The process for making the triglyceride plasticizer includes: (i) recovering at least one linear C06-23-2011
20110150730CARBON DIOXIDE SORBENTS - Improved CO06-23-2011
20110147275POLYALKYLENE EPOXY POLYAMINE ADDITIVES FOR FOULING MITIGATION IN HYDROCARBON REFINING PROCESSES - The present invention provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process and adding an antifouling agent containing a polymer base unit and a polyamine group to the crude hydrocarbon. The antifouling agent can be obtained by reacting an epoxidation reagent with a vinyl-terminated polymer, such as polypropylene or poly(ethylene-co-propylene), to form a terminal epoxy group, followed by reacting a polyamine with the epoxy group.06-23-2011
20110147274REGENERATION OF ALKALI METAL REAGENT - After desulfurizing a hydrocarbon feedstream using an alkali metal reagent, the hydrocarbon feedstream can include particles of spent alkali metal salts. The spent alkali metal salts can be separated from the hydrocarbon feedstream and regenerated to form an alkali metal reagent, such as a alkali hydroxide or alkali sulfide. The regeneration process can pass through an intermediate stage of forming an alkali carbonate by successive reactions with carbon dioxide and calcium oxide. The calcium oxide can also be regenerated.06-23-2011
20110147273DESULFURIZATION PROCESS USING ALKALI METAL REAGENT - Hydrocarbon feedstreams are desulfurized using an alkali metal reagent, optionally in the presence of hydrogen. Improved control over reaction conditions can be achieved in part by controlling the particle size of the alkali metal salt and by using multiple desulfurization reactors. After separation of the spent alkali metal reagent, the resulting product can have suitable characteristics for pipeline transport and/or further refinery processing.06-23-2011
20110147271PROCESS FOR PRODUCING A HIGH STABILITY DESULFURIZED HEAVY OILS STREAM - Self-compatible heavy oil streams are produced from converted and/or desulfurized fractions. In a preferred embodiment, an incompatibility stream is added to the converted and/or desulfurized stream to reduce the solubility number of the stream. After using a water wash to remove incompatible material, a lighter fraction is removed from the stream to increase the solubility number.06-23-2011
20110147267RAPID CYCLE REFORMING PROCESS - This invention relates to process for producing a reformate or gasoline product. The process involves a rapid cycle of reacting hydrocarbon feedstock to form the product and then regenerating the catalyst used in the reaction. The process can be carried out at relatively high liquid hourly space velocities and preferably at relatively low hydrogen to hydrocarbon ratios to produce a reformed product having relatively high liquid yield and hydrogen content.06-23-2011
20110147263PROCESS AND SYSTEM TO CONVERT OLEFINS TO DIESEL AND OTHER DISTILLATES - The present invention provides a process for producing a hydrocarbon fuel composition that includes introducing an olefin feed composition including light olefins to an oligomerization catalyst to yield an intermediate composition including olefins having at least four carbon atoms, introducing the intermediate composition and a second feed of aromatic compounds (e.g., a feed including from 2 to 99.9% benzene or other alkylatable aromatics) to an aromatic alkylation catalyst to yield a fractionation feed to provide a composition which can be further refined to provide one or more hydrocarbon fuel compositions.06-23-2011
20110139687METHOD AND SYSTEMS TO REMOVE POLAR MOLECULES FROM REFINERY STREAMS - The present invention relates to methods and systems for removing polar molecule contaminants from a refinery stream in connection with the processing of hydrocarbon fluids, chemicals, whole crude oils, blends and fractions in refineries and chemical plants that include adding high surface energy and/or high surface area nanoparticle compounds to a refinery stream to remove the polar molecule contaminants.06-16-2011
20110139583ACTIVE SOLIDS SUPPLY SYSTEM AND METHOD FOR SUPPLYING SOLIDS - A solids supply systems having a solids deaeration zone and a solids pump zone, and to methods for supplying the solids e.g., pulverized dry coal, to an application, e.g., gasification process. The solids deaeration zone includes a roller system containing a plurality of porous roller assemblies, or a belt system containing a plurality of porous belt assemblies. The solids deaeration zone is operable to deaerate and convey the solids to the solids pump zone. In the solids deaeration zone, the solids become sufficiently compacted prior to and upon entry into the solids pump zone to be effectively conveyed through the solids pump zone.06-16-2011
20110139257PASSIVE SOLIDS SUPPLY SYSTEM AND METHOD FOR SUPPLYING SOLIDS - A solids supply system having a solids deaeration zone and a solids pump zone, and a method for supplying the solids e.g., pulverized dry coal, to an application, e.g., gasification process. The solids deaeration zone includes a container having a passageway defined by one or more sloped walls. The solids deaeration zone is operable to deaerate and convey the solids to the solids pump zone. In the solids deaeration zone, the solids become sufficiently compacted prior to and upon entry into the solids pump zone to be effectively conveyed through the solids pump zone.06-16-2011
20110138679METHODS FOR ANALYZING AND OPTIMIZING BIOFUEL COMPOSITIONS - The invention provides novel methods for optimizing the design of a fatty acid alkyl ester-containing biofuel (e.g. a biodiesel, a biodiesel blend, or a jet biofuel) and for identifying a fatty acid alkyl ester-containing biofuel's feedstock.06-16-2011
20110136714High Viscosity Novel Base Stock Lubricant Viscosity Blends - A lubricant formulation and method of blending a lubricant formulation is disclosed. The lubricant formulation comprises at least two base stocks. The first base stock comprises a viscosity greater than 135 cSt, Kv100° C. and a tight molecular weight distribution as a function of viscosity. The second base stock comprises a viscosity less than 60 cSt, Kv100° C. The formulation also comprises a polyol ester. The lubricant formulation provides favorable properties.06-09-2011
20110132806REMOVAL OF NITROGEN COMPOUNDS FROM FCC DISTILLATE - A method for the removal of nitrogen compounds from FCC feed or from catalytically cracked distillates including FCC cycle oils by using formaldehyde to selectively couple organic heterocyclic nitrogen species in the FCC feed or FCC distillate to form higher boiling coupling products out of the boiling range of FCC distillate. Removal of the nitrogenous compounds improves the operation of subsequent hydrodesulfurization steps needed for the distillate fraction to conform to low sulfur standards. The formaldehyde is preferably used in the form of paraformaldehyde. The reaction between the nitrogenous compounds in the cycle oil fraction with the formaldehyde is conveniently carried out in the cycle oil pumparound circuit of the FCC main column.06-09-2011
20110132803TWO STAGE HYDROPROCESSING WITH DIVIDED WALL COLUMN FRACTIONATOR - A divided wall column allows for fractionation of multiple streams while maintaining separate product qualities. Effluents from multiple stages of a reaction system can be processed in a single divided wall column. The divided wall column can produce multiple cuts from each separated area, as well as at least one output from a common area.06-09-2011
20110131870METHOD FOR INCREASING COLOR QUALITY AND STABILITY OF FUEL FIELD OF THE INVENTION - This invention relates to process for increasing color quality and thermal stability of fuel. Fuel that is provided as a feedstock is contacted or treated with an acidic, ion-exchange resin to increase the color quality and stability of the fuel. The process provides the benefit of substantially increasing the long term quality of both color and oxidation (JFTOT) stability.06-09-2011
20110130857METHOD AND APPARATUS FOR OPTIMIZING A PERFORMANCE INDEX OF A BULK PRODUCT BLENDING AND PACKAGING PLANT - A method of generating capacity, production and inventory plans, over a designated planning horizon, which will optimize, with respect to a designated performance index, the operations of one or more bulk product blending and packaging plants and a specified number, ranging from zero to a certain count, of distribution centers while meeting key operating constraints. Also decision making tools and computer implemented programs for performing the method.06-02-2011
20110130316METHOD FOR IMPROVING THE RESISTANCE TO ONE OR MORE OF CORROSION, OXIDATION, SLUDGE AND DEPOSIT FORMATION OF LUBRICATING OIL COMPOSITIONS FOR BIODIESEL FUELED ENGINES - Lubricating oil used for the lubrication of engines run on biodiesel fuels are improved in their resistance to oxidation, sludge and deposits formation by the addition to said lubricating oil of detergent to increase the TBN of the lubricating oil or the addition of organic bases.06-02-2011
20110119993HIGH SEVERITY HYDROPROCESSING INTERSTITIAL METAL HYDRIDE CATALYSTS AND ASSOCIATED PROCESSES - The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride containing catalyst and hydrogen at process conditions of at least 400 psig pressure and temperatures of at least 200° C. These processes use interstitial metal hydrides that possess significant hydrogen capacities and high hydrogen kinetics rate properties. The catalysts and processes of the present invention may be used with or without radio frequency or microwave energy and are preferably run under conditions of high hydrogen partial pressure above about 350 psia. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams as compared to processes of the prior art operated under similar conditions.05-26-2011
20110119992OXIDATION RESISTANT INTERSTITIAL METAL HYDRIDE CATALYSTS AND ASSOCIATED PROCESSES - The present invention relates to novel interstitial metal hydrides and catalyst containing interstitial metal hydrides that are resistant to oxidation and resultant loss of catalytic activity. The processes of the present invention include use of these improved, oxidation resistant interstitial metal hydride compositions for improved overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.05-26-2011
20110119991INTERSTITIAL METAL HYDRIDE CATALYST ACTIVITY REGENERATION AND HYDROPROCESSING PROCESSES - The present invention relates to new processes for regenerating oxidized interstitial metal hydride containing catalysts prior to the use of such catalysts in a hydroprocessing process. Interstitial metal hydride containing catalysts are easily oxidized in the environment and once oxidized, the hydroprocessing activity of the interstitial metal hydrides is most often severely diminished and this lost activity due to oxidization of the iMeH is not susceptible to recovery under hydroprocessing conditions. As a result, these catalysts in the present art require considerable special handling in inert environments all through processes from fabrication, shipping, loading, use, and maintenance of the catalyst systems to protect the activity of the interstitial metal hydride components. The present invention embodies a process regenerating oxidized interstitial metal hydride containing catalysts prior to their use in a hydroprocessing environment, thereby eliminating the requirement for maintaining the interstitial metal hydride containing catalysts in an inert environment, and allowing the handling of such catalysts in an oxidized condition prior to use.05-26-2011
20110118522OLEFIN FEED PURIFICATION PROCESS - A light olefin feed for an olefin conversion process is subjected to a water wash to remove water-soluble contaminants after which the water is separated from the olefin prior to the conversion reaction. The water used for the wash is free of boiler feedwater additives, especially basic nitrogenous additives, which adversely affect catalytic function.05-19-2011
20110118420Process for Making Dendritic Hydrocarbon Polymers - A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of one or more alkadiene monomers and/or one or more alkenylaromatic polymers under anionic conditions in the presence of a di- or tri-functional organic lithium initiator to produce a polyalkadiene defining a multiplicity of lithiated chain ends; (b) reacting the polyalkadiene with an amount of a tri- or di-functional silane coupling agent to form a dendritic polyalkadiene; and (c) hydrogenating the dendritic polyalkadiene to form a substantially saturated dendritic hydrocarbon polymer. Also a process for process for making a dendritic hydrocarbon polymer, comprising: (a) polymerizing an amount of one or more alkadiene monomers and/or one or more alkenylaromatic polymers under anionic conditions in the presence of a di- or tri-functional organic lithium initiator to produce a hydrocarbon polymer defining a multiplicity of lithiated chain ends; and (b) reacting the hydrocarbon polymer with an amount of a tri- or di-functional silane coupling agent to form a dendritic hydrocarbon polymer.05-19-2011
20110114468FLUID COKING UNIT STRIPPER - An improved, fouling-resistant configuration for the stripper sheds of fluid coking units comprises an inverted, open-bottomed channel with apertures spaced along the length of the channel and spaced from the apex of the channel. Preferably, the channels are of an inverted-V configuration with a downwardly extending lip provided on each side of the channel, extending from the bottom edge of each side of the channel. The stripper sheds may be positioned parallel to one another in the stripper section of the reactor vessel or, alternatively, the sheds in different tiers in the stripper section may be disposed so that the longitudinal axes of the sheds are rotated angularly relative to the sheds in other rows.05-19-2011
20110104384Erosion Resistant Cermet Linings for Oil & Gas Exploration, Refining and Petrochemical Processing Applications - The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K05-05-2011
20110104383Erosion Resistant Cermet Linings for Oil & Gas Exploration, Refining and Petrochemical Processing Applications - The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K05-05-2011
20110099891HYDROPROCESSING FEEDSTOCK CONTAINING LIPID MATERIAL TO PRODUCE TRANSPORTATION FUEL - This invention provides processes for producing fuel, particularly transportation fuel, from biological material, e.g., lipid material. One aspect of the invention involves hydroprocessing a feedstock in a hydroprocessing zone that is maintained at conditions that promote the efficiency of converting the lipid-containing feedstock into transportation fuel. Such conditions include one or more of maintaining CO content of the hydroprocessing zone at a predetermined amount and recycling or providing a hydrogen-containing gas to the hydroprocessing zone that has been treated to remove CO.05-05-2011
20110098390Process for Making Mixed Triglyceride Plasticizer From Benzoic and Toluic Acid - Provided are compositions, processes for making, and processes for using mixed triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C04-28-2011
20110094627Erosion Resistant Cermet Linings For Oil & Gas Exploration, Refining and Petrochemical Processing Applications - The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K04-28-2011
20110082063Novel Base Stock Lubricant Blends - A method of improving air release is disclosed. The method comprises obtaining a lubricant comprising two base stocks. The first base stock comprises a viscosity greater than 100 cSt, Kv100° C. The second base stock comprises a viscosity less than 10 cSt, Kv100° C. In addition, a lubricant formulation and method of blending a lubricant formulation is also disclosed. The lubricant formulation comprises at least two base stocks. At least 5 percent and no more than 90 percent of a first base stock comprising oil with a viscosity greater than 300 cSt, Kv100° C. At least 5 percent and no more than 90 percent of a second base stock comprising oil with a viscosity less than 10 cSt, Kv100° C.04-07-2011
20110082062LUBRICATING OIL COMPOSITIONS FOR BIODIESEL FUELED ENGINES - Lubricating oil used for the lubrication of engines run on biodiesel fuels are improved in their resistance to oxidation by the addition to said to lubricating oil of particular detergents, and premixed mixtures of particular detergents and anti-oxidants.04-07-2011
20110082061ALKYLATED NAPHTYLENE BASE STOCK LUBRICANT FORMULATIONS - In one embodiment a novel lubricant is disclosed. The lubricant comprises an alkylated naphthalene base stock with a viscosity of at least 2 cSt and less than 22 cSt kv100° C., the alkylated naphthalene base stock is greater than 55 weight percent of the lubricant, a PAO base stock with at least 4 cSt and less than 250 cSt kv100° C., the PAO base stock is at least 2 and less than 40 weight percent of the lubricant, at least 0.5 and less than 1.5 weight percent of the lubricant is an amine antioxidant additive, at least 0.5 and less than 1.5 weight percent of the lubricant is a defoamant additive, at least 0.1 and less than 0.4 weight percent of the lubricant is an alkylated rust inhibitor additive, and the lubricant has a viscosity of at least 4 cSt and less than 10 cSt kv100° C., less than 10 ppm metals, less than 100 ppm sulfur, and a VI greater than 70.04-07-2011
20110079542STACKING OF LOW ACTIVITY OR REGENERATED CATALYST ABOVE HIGHER ACTIVITY CATALYST - Processes are provided for using employing lower activity hydrodesulfurization catalysts while achieving a desired product sulfur content. After determining effective reaction conditions for hydrodesulfurization using a reference catalyst system, an upstream portion of the catalyst system can be replaced with a lower activity upstream portion. The process allows tailored product sulfur levels to be achieved using reaction conditions similar to those for the reference catalyst system.04-07-2011
20110072715FUEL PRODUCTION FROM FEEDSTOCK CONTAINING TRIGLYCERIDE AND/OR FATTY ACID ALKYL ESTER - This invention relates to processes for the production of a fuel composition from a feedstock that comprises lipid material (e.g., bio-material) and mineral oil. The processes can be carried out without producing a significant mount of undesirable side reactions such as cracking, polymerization, and aromatization, which can be an undesirable consequence of large heats of reaction. As a result, the invention provides for the production of a product that is relatively high in quality, and catalyst used in the processes is not adversely affected to any significant extent.03-31-2011
20110056869FUEL PRODUCTION FROM FEEDSTOCK CONTAINING LIPIDIC MATERIAL - This invention relates to the production of dewaxed and/or hydroisomerized fuel composition that includes a step of hydrotreating a feedstock containing the lipidic material. The fuel compositions are high quality fuel compositions in which the fuel can be ultimately tailored for a variety of end uses such as jet fuel or diesel fuel.03-10-2011
20110056122STABLE ALKOXYLATED FATTY ACID ALKYL ESTERS FROM TRANSESTERIFICATION-ALKOXYLATION OF VEGETABLE OILS - Alkoxylated fatty acid alkyl esters are produced from a bio-component feed, preferably containing triglycerides. The triglycerides can be reacted with an alcohol in the presence of an acidic catalyst to form alkoxylated fatty acid alkyl esters, which can provide improved low temperature properties and/or improved oxidative stability in petrochemical products, relative to non-alkoxylated versions of the fatty acid alkyl esters.03-10-2011
20110054230REDUCING HYDROGEN CONSUMPTION IN HYDROTREATING OF BIOCOMPONENT FEEDS - Processes are provided for deoxygenation of a biocomponent feedstock with reduced hydrogen consumption. The biocomponent feedstock can be processed under relatively low hydrogen partial pressures and at a relatively low treat gas ratio compared to the hydrogen need of the feedstock. The relatively low pressure, relatively low treat gas ratio hydroprocessing can result in reduced production of water and carbon monoxide and in increased production of carbon dioxide compared to relatively higher pressure process conditions.03-03-2011
20110036857Distribution Method for Low-Sulfur Fuels Products - Method for transporting low and ultra-low sulfur fuel products using common, non-dedicated distribution systems also used to transport and distribute high-sulfur fuel products.02-17-2011
20110036755Operating Method for Hydrodenitrogenation - The present invention relates to a catalytic process for removing organonitrogen species from hydrocarbon mixtures such as refinery process feedstreams. More particularly, this invention relates to a new operating and catalyst loading strategies based on organonitrogen concentration, composition, and structure.02-17-2011
20110034749Synthesis and use of ZSM-12 - A process is described for synthesizing a porous, crystalline material having the framework structure of ZSM-12 of the formula:02-10-2011
20110024261MITIGATION OF REFINERY PROCESS UNIT FOULING USING HIGH-SOLVENCY-DISPERSIVE-POWER (HSDP) RESID FRACTIONS - Atmospheric and/or vacuum resid fractions of a high solvency dispersive power (HSDP) crude oil are added to a blend of crude oil to prevent fouling of crude oil refinery equipment and to perform on-line cleaning of fouled refinery equipment. The HSDP resid fractions dissolve asphaltene precipitates and maintain suspension of inorganic particulates before coking affects heat exchange surfaces.02-03-2011
20110024260HIGH-SOLVENCY-DISPERSIVE-POWER (HSDP) CRUDE OIL BLENDING FOR FOULING MITIGATION AND ON-LINE CLEANING - A high solvency dispersive power (HSDP) crude oil is added to a blend of incompatible and/or near-incompatible oils to proactively address the potential for fouling heat exchange equipment. The HSDP component dissolves asphaltene precipitates and maintains suspension of inorganic particulates before coking affects heat exchange surfaces. HSDP co-blending for fouling mitigation and on-line cleaning can be affected using different concentrations of top-performing and moderate-performing HSDP crude oils.02-03-2011
20110015454HYDROPROCESSING OF BIOCOMPONENT FEEDSTOCKS WITH FCC OFF-GAS - A biocomponent feedstock can be hydroprocessed using an FCC off-gas as a hydrogen source. A relatively low cost catalyst, such as a water gas shift catalyst and/or spent hydrotreating catalyst, can be used as a hydrogenation catalyst for the process. The hydroprocessing can allow for olefin saturation and/or deoxygenation of the biocomponent feed by using a relatively low value refinery stream.01-20-2011
20110015423Functionalized Carbon Nanostructures Which are Soluble in Hydrocarbons and Method for Preparation - Carbon nanomaterials functionalized on their surface with ester or amide functionality are made using a technique involving multiple space apart in time or dropwise additions of reactants to the carbon nanomaterials, and are soluble in hydrocarbon liquids.01-20-2011
20110015106Reduced Friction Lubricating Oils Containing Functionalized Carbon Nanomaterials - Lubricating oil of reduced friction comprise lubricating oil base stock and dissolved therein carbon nanomaterials functionalized on their surface with ester or amide functionality and made using a technique involving multiple space apart in time or dropwise additions of reactants to the carbon nanomaterials.01-20-2011
20110009548OIL BASED POLYOLS OR DIACIDS ESTERIFIED WITH OXO-ACIDS OR OXO-ALCOHOLS FOR PRODUCING PLASTICIZERS - Oxo-diesters of cyclic olefins, methods of making them and their use as plasticizers in polymer compositions are disclosed.01-13-2011
20110008229SULFUR RECOVERY PLANT TAIL GAS TREATMENT PROCESS - A process for the removal of hydrogen sulfide from a gas stream in which the gas stream is first passed through a Claus unit operating at a sub-stoichiometric ratio (H01-13-2011
20110005912DELAYED COKING PROCESS - Petroleum cokes derived from extra-heavy crude sources can be made more amenable to quenching by adding water or a water/light oil mixture to the coker feed downstream of the furnace. The coke product resulting from this addition of normally volatile liquids to the hot coker feed is still relatively dense but is more friable and usually is in a compact, relatively free-flowing, granular form. The coke is more amenable to uniform quenching in the drum and so can be cut and discharged with a reduced risk of eruptions and a reduced risk of fires in the coke pit or when the coke is subsequently handled and transported.01-13-2011
20110005911DELAYED COKING PROCESS - The morphology of petroleum cokes produced by the delayed coking of feeds produced from extra-heavy crude sources such as those from the Venezuela Orinoco Heavy Oil Belt can be controlled to produce a less dense coke which is less likely to inflame in the coke pit or in subsequent handling. An aqueous solution of an alkali metal or alkaline earth metal carbonate salt when added to a feed of this type which would normally produce a dense coke product is effective to produce a quenchable coke product of lower density and higher porosity, usually in compact, granular form permitting it to be readily discharged from the drum.01-13-2011
20100332273TOOLS FOR ASSISTING IN PETROLEUM PRODUCT TRANSPORTATION LOGISTICS - A tool to assist decision-making in the logistics of bulk product transportation. For example, the tool may be used to solve a problem involving the transportation and the inventory management of crude oil, in which the transportation of crude oil between supply ports and discharge ports are performed by a fleet of ships. The tool is capable of handling a typical petroleum product transportation problem, which can be quite complex. The tool uses advanced modeling and optimization technology to find a solution (either optimal or near optimal) for the allocation of bulk products, vehicle routing, vehicle scheduling, and/or bulk product blending operations.12-30-2010
20100331586PROCESS FOR PREPARING DIESEL FUELS USING VEGETABLE OILS OR FATTY ACID DERIVATIVES - A process for preparing fuels, such as diesel fuels or jet fuels, by hydrotreating vegetable oils or fatty acid derivatives that may be applied to existing equipment for treating fossil fuels. The process comprises feeding hydrotreating a combined oxygenate feed stream, such as FAME, and a hydrocarbon feed stream until not more than 86 wt % of the esters in the oxygenate feed stream are converted to hydrocarbons, and optionally further hydrotreating the product stream within at least a second hydrotreatment reaction zone until at least 90 wt % of the esters in the oxygenate feed stream are converted to hydrocarbons, before removing and separating a hydrocarbon stream suitable for use as fuel.12-30-2010
20100326387Expanding the operating envelope of advanced combustion engines using fuel-alcohol blends - The invention provides methods that expand the operating envelope of advanced combustion engines during operation in an advanced combustion mode by supplying an engine cylinder during operation in the advanced combustion mode with fuel-alcohol blends, e.g. gasoline-alcohol blends. In methods of the invention, fuel-alcohol blends combust efficiently over a wide range of engine loads, and the need for EGR, VVT, NVO, rebreathing, or multiple fuel injection is either reduced or eliminated.12-30-2010
20100324852DETERMINING THE RESONANCE PARAMETERS FOR MECHANICAL OSCILLATORS - The prior art describes the application of mechanical oscillators for the measurement of corrosion and/or deposition. Mechanical oscillators employ the use of resonance parameters, frequency and the quality factor Q, for the measurement of corrosion or deposition. However, the prior art does not consider the required precision for measuring frequency or Q in the presence of noise to make these measurements. In particular, the ability of the mechanical oscillator to measure small amounts of metal loss or deposition is not only dependent upon the mechanical design but is limited by the precision in determining the resonance frequency and Q. The present invention discloses methods for measuring these resonance parameters with a high precision in the presence of noise. This degree of precision is required to maximize the utility of these devices as sensitive probes for corrosion and deposition (fouling) measurement. All of the embodiments described herein employ curve fitting consistent with modeling the mechanical oscillator as a simple harmonic oscillator. This curve fitting procedure, combined with averaging and utilizing signal processing parameters to mitigate noise effects, adds considerable precision in measuring resonance parameters.12-23-2010
20100324326Mixed Metal Oxide Catalysts and Processes For Their Preparation and Use - A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula Mo12-23-2010
20100320120HIGH TEMPERATURE HYDROPYROLYSIS OF CARBONACEOUS MATERIALS - Heat from nuclear reactor as a source of thermal energy is applied to the conversion of carbonaceous materials such as heavy petroleum crude oils, coals and biomass to liquid hydrocarbons. The heat is applied to provide at least a portion of the process heat used in the high temperature, short contact time hydropyrolysis of the carbonaceous material which is supplied with hydrogen generated by a high temperature process such as high temperature steam electrolysis, the sulfur-iodine cycle, the hybrid sulfur cycle, the zinc-zinc oxide cycle, a solid oxide fuel cell or by methane steam cracking. The heat from the nuclear reactor may be used to generate electricity to operate high temperature steam electrolysis used in generation of the hydrogen. By the use of nuclear thermal energy, hydrocarbon resource utilization for process heat is eliminated along with carbon dioxide evolution associated with burning of the hydrocarbon resource to generate process heat. The substitution of zero carbon emission sources therefore offers the potential for significant carbon emission reductions in refinery operations where external process heat can be applied and effectively utilized.12-23-2010
20100320071INTEGRATED SOLAR THERMAL AND NUCLEAR ENABLED WATER PURIFICATION AND HYDROCARBON REFINING PROCESSES - Saline waters are made suitable for use in large quantities in petroleum refining operations by evaporative desalination of a water source having a dissolved salt content of at least 30,000 ppmw with the heat liberated during the steam condensation used as low quality heat for petroleum refining operations. Sea water is most suitable for evaporative purification processes.12-23-2010
20100314297CYCLIC PETROLEUM REFINING - Heat from solar or nuclear heat sources is applied to provide at least a portion of the heat used in a cyclic petroleum refining process in which a hydrocarbon feedstream is contacted with a solid particulate contact material in a first step to treat the feedstream after which the solid contact material is separated or disengaged from the treated feedstream and regenerated in a separate regeneration zone before being returned to the first step for contact with additional feedstream. The entire cycle may be characterized as including an endothermic step, generally a reduction, and an exothermic step, generally an oxidation, with heat from the exothermic step being transferred from the exothermic step to the endothermic step by means of the circulating contact material. The application of the nuclear or solar heat may be applied to whichever step of the process requires heat from external sources. This technique may be applied to a method of regenerating catalysts and sorbents used in gas refining processes for removing contaminants from hydrocarbons and other gases including natural gas and syngas as well as to the FCC process.12-16-2010
20100314294HYDROCARBON DEHYDROGENATION PROCESS - A hydrocarbon dehydrogenation process in which a hydrocarbon feed, normally a straight run naphtha, comprising acyclic and cyclic paraffins is dehydrogenated at elevated temperature of at least 540° C. with process heat provided at least in part by a solar or nuclear thermal energy source.12-16-2010
20100314235HIGH TEMPERATURE HYDROPYROLYSIS OF CARBONACEOUS MATERIALS - Heat from a concentrated solar power source is applied to the conversion of carbonaceous materials such as heavy petroleum crude oils, coals and biomass to liquid hydrocarbons. The solar heat is applied to provide at least a portion of the process heat used in the high temperature, short contact time hydropyrolysis of the carbonaceous material which is supplied with hydrogen generated by a high temperature process such as high temperature steam electrolysis, the sulfur-iodine cycle, the hybrid sulfur cycle, the zinc-zinc oxide cycle or by methane steam cracking. The heat from the solar source may be used to generate electricity to operate high temperature steam electrolysis used in generation of the hydrogen. By the use of solar thermal energy sources, hydrocarbon resource utilization for process heat is eliminated along with carbon dioxide evolution associated with burning of the hydrocarbon resource to generate process heat. The substitution of zero carbon emission sources therefore offers the potential for significant carbon emission reductions in refinery operations where external process heat can be applied and effectively utilized.12-16-2010
20100312033OLEFIN FEED PURIFICATION PROCESS - A light olefin feed for an olefin utilization process is subjected to a water wash to remove water-soluble contaminants after which the water is separated from the olefin by coalescence separation at a low temperature, typically below 40° C. The coalescence separation technique is effective for separating the olefins from the water with its dissolved contaminants. If desired, a supplemental washing may be carried out by adding additional water to the feed/water mix after the initial wash step but before the coalescer in order to remove provide additional contaminant removal.12-09-2010
20100300930PROCESS FOR MAKING HIGH OCTANE GASOLINE WITH REDUCED BENZENE CONTENT BY BENZENE ALKYLATION AT HIGH BENZENE CONVERSION - A process for the alkylation of a benzene-containing refinery stream such as reformate with light refinery olefins which is capable of achieving high benzene conversion levels operates in a fixed bed of an MWW zeolite catalyst, preferably MCM-22, in single pass mode in the liquid phase at a relatively low to moderate temperatures with pressure maintained at a value adequate to ensure subcritical operation. High levels of benzene conversion with conversions of at least 90% and higher, e.g. 92% or 95% or even higher are achievable. A high octane product is produced, comprising mono-, di- and tri-alkylbenzenes with lesser levels of the tetra-substituted products. By operating with staged olefin injection, the end point of the alkylation product can be maintained at a low value while, at the same time, achieving high levels of benzene and olefin conversion.12-02-2010
20100287073METHOD FOR OPTIMIZING A TRANSPORTATION SCHEME - A method and apparatus for optimal transporting of cargo is provided. The method includes optimizing a plurality of transportation decisions and mechanically transporting cargo through movement of a plurality of vehicles in accordance with a set of optimized transportation decisions. The decisions include transportation routes and schedules for the transportation vehicles, allocation of cargo to be transported to one or more demand locations by the transportation vehicles, nomination of cargo pickup by the transportation vehicles from the one or more supply locations, the use of specialized transportation locations, and vehicle assignments for each of the transportation vehicles. The set of decisions is optimized by collecting data relating to the various transportation decisions, using the data collected as part of a mixed integer linear programming model, and obtaining a solution to the model to arrive at a set of optimized transportation decisions.11-11-2010
20100275689Tuning Fork Oscillator Activated or Deactivated by a Predetermined Condition - The present invention is a tuning fork oscillator for detection and measurement of corrosive or foreign materials. The elements include a means for mechanical excitation, and a mechanical oscillator, wherein said mechanical oscillator has a resonant frequency, f, and a quality factor, Q. A fuse fixed to the oscillator to change oscillator amplitude to or from essentially zero to resonance amplitude. In a preferred embodiment, the tuning fork has one region compatible with the service fluid and the other region is incompatible with the service fluid or other contaminant. The sensor alarms when a measured amount of the incompatible material has been removed or deposited.11-04-2010
20100263262Unleaded aviation gasoline - The present invention relates to an aviation gasoline formed by blending (i) an unleaded base fuel having a base MON of at least 94, with (ii) at least one aromatic amine effective to provide the base fuel with a final MON of at least 100.10-21-2010
20100248944Lightly Branched Higher Olefin Oligomerization with Surface Modified Zeolite Catalyst - A substantially surface-deactivated catalyst composition that is stable at least to 300° C. The catalyst includes a zeolite catalyst (e.g., ZSM-22, ZSM-23, or ZSM-57) having active internal Brönsted acid sites and a surface-deactivating amount of a rare earth or yttrium oxide (e.g., chosen from lanthanum oxide or lanthanides oxide). This to catalyst is preferably used in a process for producing a higher olefin by oligomerizing a light olefin, wherein the process includes contacting a light olefin under oligomerization conditions with the substantially surface-deactivated catalyst composition.09-30-2010
20100193159VIBRATION ACTUATION SYSTEM WITH INDEPENDENT CONTROL OF FREQUENCY AND AMPLITUDE - Vibrational energy generated with a pneumatic vibrator is controlled to independently adjust the amplitude and the frequency. A mechanical resonator is used to adjust the frequency. The controlled vibrational energy can be applied to equipment, such as a heat exchanger to mitigate fouling.08-05-2010
20100170829POLYALKYL SUCCINIC ANHYDRIDE DERIVATIVES AS ADDITIVES FOR FOULING MITIGATION IN PETROLEUM REFINERY PROCESSES - The present invention provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process; adding at least one polyalkyl succinic anhydride derivative additive disclosed herein. The additive can be complexed with a boronating agent, such as boric acid, to yield a boron-containing polyalkyl succinic anhydride derivative.07-08-2010
20100160680PROCESS FOR THE EXTRACTION OF HIGH MOLECULAR WEIGHT NAPHTHENIC ACIDS FROM CALCIUM NAPHTHENATE SALTS - A method for recovering high molecular weight naphthenic tetra-acids, particularly ARN acids from a calcium naphthenate deposit. Calcium naphthenate deposits contain large amounts of calcium naphthenate salts of ARN acids. The method dual solvent extraction process in which the naphthenic tetra-acids chemically bound as calcium naphthenate salts are converted into free acid monomers by an aqueous acid. The resulting free acid monomers are then dissolved into an organic solvent phase and the counterions dissolve in the aqueous acid phase. The naphthenic tetra-acids are then recovered from the organic solvent phase.06-24-2010
20100155322Vehicle mounted fuel separation apparatus - A fuel separation apparatus comprises a stock fuel storage tank storing stock fuel, a separator provided with a separation film separating the stock fuel into high octane value fuel with an octane value higher than the stock fuel and a low octane value fuel with an octane value lower than the stock fuel, and a high octane value fuel storage tank storing the high octane value fuel separated by the separator. When the temperature of the separation film is lower than the high octane value fuel separation temperature, the high octane value fuel stored in the high octane value fuel storage tank is supplied to the separator. Due to this, vaporization of fuel is suppressed and the fuel can be quickly raised in temperature. Due to this, a vehicle mounted fuel separation apparatus able to quickly raise the temperature of the fuel supplied to the separation film so as to quickly raise the temperature of the separation film at the time of engine cold start can be provided.06-24-2010
20100155315Vehicle-mounted fuel separation system - A vehicle-mounted fuel separation system 06-24-2010
20100154394Exhaust heat recovery system - An exhaust heat recovery system 06-24-2010
20100152900Optimizing refinery hydrogen gas supply, distribution and consumption in real time - The present invention is directed to innovative and unique mathematical models that capture key constraints, process kinetics and control structures such that a wide envelope of hydrogen gas and associated light gas supply, distribution and use can be modeled. The present invention is also directed to a real time optimization (RTO) computer application for effective optimization of hydrogen and associated light gas supply and distribution and, thereby, consumption, in a refinery that employs said models and solves an objective function, as well as to a method and refinery using the same. The objective function can be an economic objective function such as the minimization of cost for hydrogen supply and distribution or the maximization of profit based on a valuation of products made by hydrogen consumers in the hydrogen system minus the corresponding cost of the hydrogen supply and distribution.06-17-2010
20100147739ADDITION OF HIGH MOLECULAR WEIGHT NAPHTHENIC TETRA-ACIDS TO CRUDE OILS TO REDUCE WHOLE CRUDE OIL FOULING - High molecular weight naphthenic tetra-acids are added to a base crude oil to prevent and/or reduce fouling of crude oil refinery equipment. The method includes adding an effective amount of a high molecular weight naphthenic tetra-acid to the base crude oil to form a crude oil mixture and feeding the crude oil mixture to a crude oil refinery component. Particularly, the high molecular weight naphthenic tetra-acids include ARN acids.06-17-2010
20100147333Non-high solvency dispersive power (non-HSDP) crude oil with increased fouling mitigation and on-line cleaning effects - Non-high solvency dispersive power (non-HSDP) crude oil with increased fouling mitigation and on-line cleaning effects includes a base non-HSDP crude oil and an effective amount of resins isolated from a high solvency dispersive power (HSDP) crude oil, and method of making same. Also, methods of using such non-HSDP crude oil for on-line cleaning of a fouled crude oil refinery component, for reducing fouling in a crude oil refinery component, and in a system capable of experiencing fouling conditions associated with particulate or asphaltene fouling.06-17-2010
20100132359SYSTEM USING UNUTILIZED HEAT FOR COOLING AND/OR POWER GENERATION - A sorption system is disclosed that includes a sorbent material and a fluid, in which the sorbent material and fluid in combination have a pressure index of at least 1.2.06-03-2010
20100116478DISPLACEABLE BAFFLE FOR A HEAT EXCHANGER AND METHOD FOR REDUCING VIBRATION FOR THE SAME - A tube bundle device having at least one displaceable baffle which supports the tubes in the bundle device is disclosed in order to reduce tube vibration. The displaceable baffle includes at least two displaceable portions, which can be moved to installed position such that tubes in a tube bundle are deflected.05-13-2010
20100078352Method for treating refinery waste streams in a fluid catalytic cracking unit and an improved catalytic cracking unit for processing refinery waste streams - A method of processing the waste stream includes introducing the waste stream into the Fluid Catalytic Cracking Unit such that waste stream is processed within the regenerator unit or in CO boiler unit such that the waste stream and the regenerator flue gas are burned within the regenerator unit or the CO boiler unit. The waste stream contains NH04-01-2010
20100059412Visbreaking yield enhancement by ultrafiltration - Ultrafiltration may be effectively used to produce visbreaker feeds of improved quality which enable the visbreaker to be operated at higher severity with higher yields of distillable products. A heavy oil feed stream is separated by ultrafiltration or membrane separation into a permeate fraction and a retentate fraction by contacting the heavy oil feed with the first side of a porous membrane separation element in a membrane separation zone. The permeate fraction, comprised of materials which pass selectively through the porous membrane element, is retrieved and at least a portion of it is subjected to visbreaking with the improved liquid yield, especially of lighter distillate fractions. The retentate fraction can be retrieved from the first side of the porous membrane and can also be subjected to visbreaking.03-11-2010
20100038290POLYALKYL SUCCINIC ACID DERIVATIVES AS ADDITIVES FOR FOULING MITIGATION IN PETROLEUM REFINERY PROCESSES - The present application provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process; adding a polyalkyl succinic acid derivative additive. The additive can be complexed with a boronating agent, such as boric acid, to yield a boron-containing polyalkyl succinic acid derivative.02-18-2010
20100038289METAL SULPHONATE ADDITIVES FOR FOULING MITIGATION IN PETROLEUM REFINERY PROCESSES - The present application provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process; adding an additive selected from:02-18-2010
20100037773PROCESS FOR REMOVING POLAR COMPONENTS FROM A PROCESS STREAM TO PREVENT HEAT LOSS - A process and system for removing polar components from a process stream in a refinery process without cooling the process stream are disclosed. The process stream is fed to a first adsorber unit to remove contaminants containing sulfur from the process stream. The process stream is processed within the first adsorber unit to remove sulfur containing contaminants. The process stream is processed with the first adsorber unit at substantially the same elevated temperature. The process stream is processed within the first adsorber unit by exposing the process stream to at least one of a metal oxide and a mixed metal oxide to remove the sulfur containing contaminants from the process stream and produce a metal sulfide and a desulfurized process stream. The metal sulfide may be exposed to a stream of oxygen to regenerate the at least one of a metal oxide and a mixed metal oxide. The desulfurized process stream may be exposed to at least one of the regenerated metal oxide and regenerated mixed metal oxide to remove moisture from the desulfurized process stream. The desulfurized process stream is then fed through a second adsorber unit to remove contaminants containing nitrogen from the process stream. The process stream is processed within the second adsorber unit to remove nitrogen containing contaminants, where the process stream being processed at substantially the same elevated temperature. The process stream is processed within the second adsorber unit by exposing the process stream to at least one of a molecular sieve and zeolites to remove nitrogen containing contaminants from the process stream.02-18-2010
20100015564HIGH PERFORMANCE COATINGS AND SURFACES TO MITIGATE CORROSION AND FOULING IN FIRED HEATER TUBES - A fired heater tube that is resistant to corrosion and fouling is disclosed. The fired heater tube comprises an advantageous high performance coated material composition resistant to corrosion and fouling comprises: (PQR), wherein P is an oxide layer at the surface of (PQR), Q is a coating metal layer interposed between P and R, and R is a base metal layer, wherein P is substantially comprised of alumina, chromia, silica, mullite, spinels, and mixtures thereof, Q comprises Cr, and at least one element selected from the group consisting of Ni, Al, Si, Mn, Fe, Co, B, C, N, P, Ga, Ge, As, In, Sn, Sb, Pb, Sc, La, Y, Ce, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Re, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au and mixtures thereof, and R is selected from the group consisting of low chromium steels, ferritic stainless steels, austenetic stainless steels, duplex stainless steels, Inconel alloys, Incoloy alloys, Fe—Ni based alloys, Ni-based alloys and Co-based alloys.01-21-2010
20090322544METHOD AND APPARATUS FOR REAL TIME ENHANCING OF THE OPERATION OF A FLUID TRANSPORT PIPELINE - A real time method and dynamic logic-based system for enhancing the operation of a pipeline network is disclosed. The system and method perform monitoring of the operation of a pipeline network, generate alarms in response to differing levels of destabilized pipeline operations, manage the generation of alarms based upon known operating events and operating conditions, diagnose potential source of the detected destabilized events and manage the operation of the pipeline.12-31-2009
20090314689Method to alter coke morphology using either polynuclear aromatic compounds or functionalized lignin - A method for altering coke morphology in a delayed coking process of heavy oil is provided. An effective amount of one or more oil dispersible or oil soluble polynuclear aromatic compounds, or functionalized lignin, is added or contacted with the resid or heavy oil at a point before or after the step of heating the heavy oil to coking temperatures. The addition of additives facilitates the formation of shot coke and inhibits the formation of sponge coke.12-24-2009
20090299121ITQ-26, New Crystalline Microporous Material - ITQ-26 (INSTITUTO DE TECNOLOGIA QUIMICA number 26) is a new crystalline microporous material with a framework of tetrahedral atoms connected by atoms capable of bridging the tetrahedral atoms, the tetrahedral atom framework being defined by the interconnections between the tetrahedrally coordinated atoms in its framework. ITQ-26 can be prepared in silicate compositions with an organic structure directing agent. It has a unique X-ray diffraction pattern, which identifies it as a new material. ITQ-26 is stable to calcination in air, absorbs hydrocarbons, and is catalytically active for hydrocarbon conversion.12-03-2009
20090287033Reactor for isoparaffin olefin alkylation - An improved reactor for the autorefrigerant alkylation process has a generally cylindrical upright reactor vessel with the inlet for the refrigerant reactant and the sulfuric acid at its lower end and a series of inlets for the olefin reactant at vertically spaced intervals up the length of the reactor. An extended, sinuous flow path for the reactants is provided by means co-acting baffles which define sequential reaction zones in which alkylation takes place. The baffles interact with a rotary mixer with multiple impellers located on the reactor axis which provides agitation to the mixture ascending the reactor additional to that created by the ebullition of the refrigerant. Outlets for the vaporized refrigerant and the reaction effluent are provided at the upper end of the vessel. In the alkylation process operated in the reactor, the liquid isoparaffin hydrocarbon reactant/refrigerant with a sulfuric acid alkylation catalyst is introduced into the lower end of the reactor and passed along the extended reactant flow path with the olefin reactant introduced at intervals along the path. The reaction mixture flows alternately towards and away from the reactor walls in the sequence of serial reaction zones within the reactor to promote mixing of the isoparaffin reactant with the acid catalyst. With the evolution of the heat of reaction, a portion of the reactant refrigerant is vaporized to effect temperature control in the reactor. Agitation is provided by means of the rotary mixer with its mixing impellers in each of the sequential reaction zones. The vaporized reactant refrigerant and alkylation reaction products leave the reactor at its upper end.11-19-2009

Patent applications by EXXONMOBIL RESEARCH AND ENGINEERING COMPANY