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Arkema Inc.

Arkema Inc. Patent applications
Patent application numberTitlePublished
20120129974AQUEOUS COATING COMPOSITIONS - The disclosure relates to aqueous coating compositions and elastomeric coatings formed from the aqueous coating compositions, and in particular to aqueous coating compositions that can be used to form elastomeric coatings with improved dirt pickup resistance and elastomeric properties.05-24-2012
20120129755LIQUID CLEANING COMPOSITION - The present invention relates to a liquid cleaning composition comprising a peroxygen bleach, a sulfonated anionic surfactant and an amphoteric/zwitterionic surfactant where the sulfonated anionic surfactant and the amphoteric/zwitterionic surfactants are in a ratio of from 0.1:1 to 13:1. The combination of the sulfonated anionic surfactant and the amphoteric/zwitterionic surfactants provides for high viscosities and improved cleaning performance.05-24-2012
20120126273OLED SUBSTRATE CONSISTING OF TRANSPARENT CONDUCTIVE OXIDE (TCO) AND ANTI-IRIDESCENT UNDERCOAT - A light-emitting devices and methods for forming light-emitting devices are provided. The device comprises of a substrate having a first refractive index, a transparent electrode that is coupled to an organic layer, where the transparent electrode has a second refractive index different from the first refractive index. An undercoat layer is selected that has a third refractive index to substantially match the first refractive index to the second refractive index. The undercoat layer is selected such that it has a capacity to reduce root mean square roughness of the transparent electrode film deposited. The undercoat layer is selected to improve electrical properties of the transparent electrode layer. The undercoat layer is provided between the substrate and the transparent electrode.05-24-2012
20120108729IMPACT-MODIFIED POLYCARBONATE/POLYESTER OR POLYCARBONATE/POLYAMIDE COMPOSITIONS - The invention relates to impact-modified polymer compositions, containing a polymer blend of polycarbonate with polyester and/or polyamide, plus an impact modifier blend of core/shell and functional polyolefin impact modifiers. The impact modifiers can provide the polymer blend composition with improved impact strength at equivalent loading, and also allow for higher amounts of polyester and/or polyamide in the blend without sacrificing impact strength.05-03-2012
20120108688HYDROFLUOROPROPENE BLOWING AGENTS FOR THERMOPLASTICS - The present invention relates to blowing agent compositions comprising the unsaturated halogenated hydroolefin 3,3,3-trifluoropropene (HFO 1243zf) and combinations including primarily 3,3,3-trifluoropropene (HFO 1243zf). The blowing agent compositions are useful in that they provide sufficient plasticization to permit the production of low density insulating thermoplastic foams with improved k-factor.05-03-2012
20120101177BLOWING AGENT COMPOSITIONS OF HYDROCHLOROFLUOROOLEFINS - The present invention relates to blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited too, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32). The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.04-26-2012
20120097350ALKALINE PEROXIDE TREATMENT OF REJECTS IN AN INTERGRATED NEUTRAL-ALKALINE PAPER MILL - A processes producing mechanical pulps utilizing refiners for improving the quality of screen rejects, and most particularly to a mechanical pulp mill integrated with a neutral-alkaline papermaking process producing mechanical printing paper grades is disclosed. The rejects are treated with hydrogen peroxide, an alkali and an organic stabilizing agent just prior to or during refining to provide improved optical and physical properties of the refined rejects and more efficiently utilize electrical energy to reach target fiber quality after bleaching for cost-effectively producing a wide array of coated and uncoated mechanical printing papers.04-26-2012
20120078020PROCESS FOR THE MANUFACTURE OF HYDROFLUOROOLEFINS - In this invention we are disclosing a process for the synthesis of hydrocchlorofluoro olefins (HCFO) and/or hydrofluoroolefins (HFO). The process is based on the steps of fluorination of hydrochloropropenes or hydrochloropropanes to form hydrochlorofluoropropenes and/or hydrofluoropropenes, followed by gas phase, catalytic fluorination of the hydrochlorofluoropropenes to form hydrofluoropropenes.03-29-2012
20120073632WEATHERABLE POLYVINYLIDENE FLUORIDE COATED SUBSTRATES - The invention relates to architectural substrates coated with a polyvinylidene fluoride (PVDF) dispersion coating to produce a weatherable material. One specific use is as a PVDF coating on a frontsheet or backsheet of a photovoltaic module for capturing and using solar radiation. The polyvinylidene fluoride coating is exposed to the environment and provides chemical resistance, low water vapor transmission, electrical insulation, and UV light protection.03-29-2012
20120059202PROCESS FOR THE MANUFACTURE OF HYDROFLUOROOLEFINS - In this invention we are disclosing a process for the synthesis of hydrocchlorofluoro olefins (HCFO) and/or hydrofluoroolefins (HFO). The process is based on the gas phase, noncatalytic fluorination of hydrochlorofluoropropenes to form hydrofluoropropenes.03-08-2012
20120045603FOAMED POLYVINYLIDENE FLUORIDE STRUCTURE - The invention relates to a foamed fluoropolymer, preferably a polyvinylidene fluoride (PVDF) structure, such as from Kynar® resins. The foamed structure is continuous self-supporting, sized, and has a dense skin. The foamed structure is manufactured in a process using foaming agents and nucleating agents. The structure is sized into a specific shape during the manufacturing process—requiring a good melt viscosity of the PVDF foam. In one process, a master batch containing the nucleating agent is used. The foamed article could be a sheet, film, profile, tube, pipe, article, rod foam-core structure, or other self-supporting shape. Foamed tubes, pipes, rods, sheets and conduit are especially useful. The foamed structure of the invention provides added value by being lighter weight, more flexible, and more impact resistant than a comparable non-foamed PVDF structure. It also has increased hysteresis, increased insulation properties, reduced dielectric constant, and increased compressibility.02-23-2012
20120035323POLYOLEFIN/POLYLACTIC ACID BLENDS - The invention relates to blends of polyolefins and a biodegradable polymer, such as polylactic acid (PLA) and polyhydroxy butyrate, which are compatabilized by a functionalized olefin (meth)acrylic copolymer. Since PLA and polyolefins are not miscible, the use of the compatibilzer improves the compatibility, thereby improving the processability, and particularly the melt strength and melt elasticity. Useful compatibilizers include Lotader® and Lotryl® copolymers from Arkema, Inc. The blend composition may optionally contain one or more acrylic copolymers as impact modifiers or process aids.02-09-2012
20120028036ASSEMBLIES CONTAINING POLYETHERKETONEKETONE TIE LAYERS - Tie layers comprised of amorphous polyetherketoneketone are used to join substrates to form laminates and other assemblies.02-02-2012
20120027971ROTATIONAL MOLDED ARTICLE FORMED FROM HIGH MOLECULAR WEIGHT POLYAMIDES - The invention relates to an article formed by a rotational molding process, having at least one layer formed from a high molecular weight polyamide. The high molecular weight polyamide is one having a molecular weight in the range of 20,000 to 35,000 and also having an inherent viscosity of 1.05-1.60 dL/g. Rotomolded articles having a high molecular weight polyamide layer have better low-temperature impact performance compared to articles formed from lower molecular weight polyamides.02-02-2012
20120024412ARTICULATED PIPING FOR FLUID TRANSPORT APPLICATIONS - An articulated pipeline assembly for the transport of fluids including a fluid conduit for transporting fluid and an articulating shell assembly that is positioned to encapsulate the fluid conduit. The articulating shell assembly includes a plurality of articulating shell segments, each articulating shell segment comprising both a ball and a socket, wherein the ball of each articulating shell segment is engaged with a socket of an adjacent articulating shell segment to form a ball and socket joint. Each articulating shell segment is configured to rotate with respect to an adjacent articulating shell segment by virtue of the ball and socket joint.02-02-2012
20120015577POLYETHERKETONEKETONE NONWOVEN MATS - The invention provides nonwoven mats comprising polyetherketoneketone fibers or mixtures thereof. Also provided are filters, textiles, blankets, and insulation prepared from polyetherketoneketone nonwoven mats, as well as methods for manufacturing the same.01-19-2012
20120015246WATERBORNE FLUOROPOLYMER COMPOSITION - This invention relates to a waterborne fluoropolymer composition useful for the fabrication of Li-Ion-Battery (LIE) electrodes. The fluoropolymer composition contains an organic carbonate compound, which is more environmentally friendly than other fugitive adhesion promoters currently used in waterborne fluoropolymer binders. An especially useful organic carbonate compound is ethylene carbonate (EC) and vinylene carbonate (VC), which are solids at room temperature, and other carbonates which are liquid at room temperature such as propylene carbonate, methyl carbonate and ethyl carbonate. The composition of the invention is low cost, environmentally friendly, safer, and has enhanced performance compared to current compositions.01-19-2012
20120007016AZEOTROPE-LIKE COMPOSITION OF 1,1,1,2,2,3,3-HEPTAFLUORO-3-METHOXYPROPANE AND 1-CHLORO-3,3,3-TRIFLUOROPROPENE - Provided are azeotrope-like compositions comprising 1,1,1,2,2,3,3-heptafluoro-3-methoxy propane and E-1-chloro-3,3,3-trifluoropropene (K-1233zd) and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, solvent, and aerosol propellants.01-12-2012
20110309288AZEOTROPE AND AZEOTROPE-LIKE COMPOSITIONS OF E-1-CHLORO-3,3,3-TRIFLUOROPROPENE AND ISOPROPANOL - Provided are azeotrope or azeotrope-like compositions comprised of E-1-chloro-3,3,3-trifluoropropene (HCFO-E-1233zd) and isopropanol, and uses thereof.12-22-2011
20110309287TRANS-1,2-DICHLOROETHYLENE WITH FLASH POINT ELEVATED BY 1-CHLORO-3,3,3-TRIFLUOROPROPENE - A trans-1,2-dichloroethylene blend which comprises a combination of a major amount of trans-1,2-dichloroethylene and a minor amount of a hydrohaloolefin having an elevated flash point is disclosed The combination exhibits a flash point significantly higher than trans-1,2-dichloroethylene alone The preferred hydrohaloolefin is 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) The subject blends find application as heat transfer agents, propellents and sprayable compositions, blowing agents, solvents and cleaning agents.12-22-2011
20110301298ACID FUNCTIONALIZED GRADIENT BLOCK COPOLYMERS - The present invention relates to a class of acid functionalized gradient block copolymers, processes for obtaining them and to their uses including but not limited to hair fixatives, toughening agents, and adhesives. Surprisingly, the applicants have discovered the aforementioned class of acid functionalized gradient block copolymers have advantageous properties and can find utility in a wide variety of application areas. These polymers are easily prepared by sequential monomer addition (i.e., “one-pot” synthesis) and the process does not require any post polymerization modification steps. The aforementioned polymers are derived from commonly utilized monomers. The use of common monomers provides both an economic advantage and an inherent safety advantage, e.g., the common monomers are considered biocompatible.12-08-2011
20110294943FIBERS SIZED WITH POLYETHERKETONEKETONES - Fibers sized with a coating of amorphous polyetherketoneketone are useful in the preparation of reinforced polymers having improved properties, wherein the amorphous polyetherketoneketone can improve the compatibility of the fibers with the polymeric matrix.12-01-2011
20110291045THIXOTROPIC ANHYDROUS SHEAR THINNING PEROXIDE DISPERSIONS - Provided are dispersions which comprise more than about up to 55 percent by weight or more of an organic peroxide which is normally solid in an anhydrous liquid phase such as dibutyl maleate or dioctyl adipate, with about 5% by weight or more fumed silica to provide a thixotropic, storage stable organic peroxide paste. Addition of about 5 weight % or more of fumed silica was found to result in the formation of a shear thinning anhydrous dispersion of organic peroxide which was storage stable.12-01-2011
20110288192TETRAFLUOROPROPENE BASED BLOWING AGENT COMPOSITIONS - The present invention relates to blowing agent compositions comprising tetrafluoropropene (HFO) and at least one co-blowing agent selected from carbon dioxide, water, alkanes and an alcohol used in the preparation of foamable thermoplastic compositions having low density. The HFOs include, but are not limited too, cis- and/or trans-1,3,3,3-tetrafluoropropene (HFO-1234ze), 2,3,3,3-tetrafluoropropene (HFO 1234yf), or mixtures thereof. The blowing agent compositions are useful in the production of low density insulating foams with improved R value.11-24-2011
20110287255HIGH PERFORMANCE FIBERS - Heat-resistant, high strength fibers useful in a wide range of end-use applications are prepared using a polymeric composition containing polyetherketoneketone and mineral nanotubes.11-24-2011
20110287225HIGH PERFORMANCE CONNECTORS - High performance connectors, such as electrical connectors intended for use in circuit boards that are to be subjected to reflow soldering or rework or fiber optic connectors to be employed in harsh operating conditions, are manufactured using polymeric compositions containing polyetherketoneketone and mineral nanotubes. These polymeric compositions provide connectors having exceptional dimensional stability at high temperatures and facilitate the precise and high quality molding of connectors with thin or finely detailed features.11-24-2011
20110278193POLYVINYLIDENE BARRIER LAYER FOR CONTAINER INTERIORS - The invention relates to containers having a thin layer of polyvinylidene fluoride polymer or copolymer on its inner and/or outer surface. The polyvinylidene fluoride layer acts as a barrier layer in reducing or preventing the migration of chemicals from thermoplastic or thermoset polymeric containers into the contents of the container. This is especially applicable for containers in the food, biotech and pharmaceutical industries, as well as for toxic or corrosive materials.11-17-2011
20110251329METHOD FOR PREPARING pH-INSENSITIVE SURFACTANT FREE POLYMER PARTICLE DISPERSION IN AQUEOUS MEDIUM - The invention provides a polymer particle dispersion in an aqueous medium and a method of making the same, which comprises an emulsion polymerized polymer and a macroinitiator covalently bonded to the emulsion polymerized polymer. The living macroinitiator comprises a hydrophilic, pH-insensitive monomer in reacted form. The polymer particle dispersion may be obtained by reacting at least one monomer with the living macroinitiator and without a surfactant to effect polymerization of the monomer(s). The emulsion polymerized polymer may be comprised of at least one additional ethylenically unsaturated monomer in polymerized form.10-13-2011
20110250373POLYMERIZATION CONTROLLERS FOR ORGANIC PEROXIDE INITIATOR CURED COMPOSITES - The use of nitroxides to control free radical cured resin systems used in the production of thermosetting materials such as in vacuum infusion, resin transfer molding and cured in place piping systems is disclosed. The invention could also be employed in other resin systems where control of kinetics would be desirable such as in adhesive formulations, in solid surface composites, and certain types of polyester casting resins.10-13-2011
20110224356LOW SURFACE ENERGY BLOCK CO-POLYMER PREPARATION METHODS AND APPLICATIONS - Methods for the preparation of low surface energy block co-polymers are disclosed. The block co-polymers comprise at least two blocks, each of which comprises, in polymerized form, an acrylic monomer, a methacrylic monomer, or a mixture thereof. At least one block is a low surface energy block, which comprises, in polymerized form, a low surface energy monomer. Low surface energy macroinitiators useful in forming the block co-polymers are also disclosed. The block co-polymers may be prepared by nitroxide mediated controlled free radical polymerization.09-15-2011
20110218370PROCESS FOR THE MANUFACTURE OF HYDROCHLOROFLUOROOLEFINS - The present invention provides a process for the manufacture of trans 1-chloro-3,3,3-trifluoropropene (E-09-08-2011
20110218369PROCESS FOR THE MANUFACTURE OF HYDROFLUOROOLEFINS - The invention relates to a process for manufacturing 1,1,1,2-tetrafluoropropene (1234yf, CF09-08-2011
20110207841WATER FLUX POLYMER MEMBRANES - The invention relates to a polymer membrane composition having improved water flux and stable pore size. The water flux is improved by increasing the hydrophilicity of the membrane using a matrix polymer blended with controlled architecture amphiphilic block copolymers. Preferred membranes are those having a fluoropolymer matrix and acrylic amphiphilic block copolymers. The addition of the amphiphilic block copolymers are especially useful in microfiltration and ultra filtration membranes when used in water filtration.08-25-2011
20110201842METHOD FOR RECOVERING CARBOXYLIC ACIDS FROM DILUTE AQUEOUS STREAMS - Improvement in separating lower carboxylic acids from aqueous streams via liquid-liquid extraction with pressurized liquefied propylene and/or propane, wherein carboxylic acid is transferred from the aqueous phase into the liquid solvent phase (extract).08-18-2011
20110198227HIGH PURITY ELECTROLYTIC SULFONIC ACID SOLUTIONS - Disclosed is a solution for an electrochemical process, the solution containing a sulfonic acid and having a low concentration of sulfur compounds, either low or high valence, that are susceptible to reduction and which is intended for use in electrodeposition, batteries, conductive polymers and descaling processes.08-18-2011
20110172462CONTROL OF A PROCESS FOR THE PURIFICATION OF (METH)ACRYLIC ACID USING ON-LINE, NEAR IR ANALYSIS - An improved process for the manufacture of technical grade (meth)acrylic acid, e.g., acrylic acid, the process comprising producing a hydrated reaction product from the gas-phase oxidation of at least one (meth)acrylic acid precursor, e.g., propylene, followed by first dehydrating and then concentrating the reaction product, the improvement comprising controlling at least one of the water, acetic acid and (meth)acrylic acid content of the reaction product during the purification of the reaction product using on-line, near IR spectroscopy.07-14-2011
20110172320POLY VINYL CHLORIDE FOAM PROMOTERS - The density of rigid foamed articles made by the thermal decomposition of a blowing agent in a vinyl chloride polymer is reduced by the use of a tin based blowing agent activator(s). The tin based activator also reduces the activation temperature of a chemical blowing agent, allowing for more optimal evolution of gas during plastic processing. Dibutyl tin oxide or tin maleates are superior activators of vinyl chloride polymer blowing agents.07-14-2011
20110160338FUNCTIONALIZED BIMODAL IMPACT MODIFIERS - The invention relates to functionalized bimodal butadiene-methylmethacrylate impact modifiers. The impact modifiers are especially useful in blends of engineering resins, particularly where the blend contains both functional and non-functional resins. Polycarbonate (PC)/polyethylene terephthalate (PET) blends using the functionalized bimodal butadiene-methylmethacrylate impact modifiers of the invention have excellent low temperature impact performance.06-30-2011
20110147654METALLOCARBENE COMPLEX PEROXIDE ACTIVATORS - A bleaching composition comprising a peroxy compound and one or more activator present in an effective amount to activate the peroxy compound, present in an amount effective to accomplish bleaching or cleaning or oxidation. The activator is a metallocarbene of the general structure (XX′C)yMLn′ where M represents a metal center, C represents the carbene carbon bound to the metal center, X and X′ may be the same or different and may furthermore be part of a cyclic structure, Ln′ represents one or more other ligands which may or may not include one or more metal centers, and where y>1.06-23-2011
20110147307METHOD FOR RECOVERING CARBOXYLIC ACIDS FROM DILUTE AQUEOUS STREAMS - Improvement in separating lower, C2 saturated and/or C3, and/or C4, saturated and/or unsaturated mono carboxylic acids from aqueous streams via extraction by using as the extractant an organic acid or ester or mixtures thereof with a melting point below 10° C., a normal boiling point between 190 and 280° C. and a Hildebrand solubility parameter between 8 and 11 cal06-23-2011
20110136706ORGANOSULFONYL LATENT ACIDS FOR PETROLEUM WELL ACIDIZING - Oil wells are treated with latent acids containing a sulfonyl moiety, wherein the latent acid is capable of providing an active acid after injection into an oil well. The latent acids are converted to active acids such as mineral acids or strong organic acids in the oil well, with resultant dissolution of acid-soluble minerals that impede oil or gas flow. Exemplary latent acids are according to any of formulas (I), (II), and (III)06-09-2011
20110130599CATALYTIC GAS PHASE FLUORINATION OF 1230XA TO 1234YF - A one reactor, gas phase catalyzed process for the fluorination of 1,1,2,3-tetrachloropropene (1230xa) to produce 1,1,1,2-tetrafluoropropene (1234yf) is disclosed. The process of the present invention is a catalytic, gas phase fluorination using a high pressure activated catalyst which is supported or unsupported. Fluorination products of the formula CF3R, where R is selected from —CCl=CH2, —CF=CH2, —CF2—CH3, —CFCl—CH3 and mixtures thereof are produced. Co-produced materials are separated from the desired product and recycled to the same reactor.06-02-2011
20110118403FLUOROPOLYMER AQUEOUS HYBRID COMPOSITIONS WITH IMPROVED FILM FORMATION - The invention relates to aqueous fluoropolymer hybrid compositions made by a seeded emulsion polymerization process, having improved film formation properties. The seed is a fluoropolymer dispersion. At least two different monomer compositions are added sequentially to the seeded dispersion. These monomer compositions preferably include acrylic monomers. The first monomer composition is selected for miscibility with the fluoropolymer dispersion. The second monomer composition is selected to have a glass transition temperature (Tg) of less than 30° C. The final composition can be formulated to make coatings with a minimum film forming temperature (MFFT) of less than 5° C., and a maximum VOC of 50 g/liter. The composition is especially useful for coatings and films.05-19-2011
20110112253AMPHIPHILIC BLOCK COPOLYMER FORMULATIONS - The invention relates to an amphiphilic block copolymer having an increased speed of water adsorption. The non-water soluble copolymer, having a hydrophilic middle block and hydrophobic endblocks, has a high rate water transmission and/or permeation. The increase in rate is due to neutralization, or partial neutralization of the hydrophilic block of the copolymer. Furthermore, the absorption rate can be controlled by the extent of the neutralization. Another aspect of the invention is the use of co-monomers and/or additives to further increase or tailor the water absorption properties. The use of additives and comonomers is also shown to enhance the processability of the disclosed polymer composition.05-12-2011
20110111156NOVEL VINYLIDENE FLUORIDE COPOLYMERS - The invention relates to a copolymer composition of poly(vinylidene fluoride-trifluoropropene) copolymers. The copolymers formed have excellent optical properties, with very low haze, as well as high melting points, excellent flexibility and toughness.05-12-2011
20110097529VINYLIDENE FLUORIDE / 2,3,3,3-TETRAFLUOROPROPENE COPOLYMERS - This invention relates to copolymer compositions of poly(vinylidene fluoride-2,3,3,3-tetrafluoropropene) copolymers. The copolymers formed have excellent optical properties, corrosion resistance and electrical properties, with very low haze. Tetrafluoropropene monomer units may be present at from 0.5 to 60 weight percent of the copolymer.04-28-2011
20110097503ALKALINE COATING COMPOSITION FOR AUTODEPOSITION - Embodiments of the present disclosure include processes for autodepositing a coating on a metal surface, a method of producing a coating on a non-stainless steel metal substrate surface, and an alkaline coating composition, where the process for autodepositing a coating on a metal substrate surface includes immersing at least a portion of the metal substrate surface in a coating composition that includes a latex and an amount of base sufficient to raise the pH of the composition to an alkaline pH, where the coating autodeposits on the metal substrate surface, as metal ions from the metal substrate surface interact with the alkaline coating composition.04-28-2011
20110086959SHEAR THINNING PEROXIDE DISPERSIONS - Provided are dispersions which comprise more than about (40) percent by weight of an organic peroxide which is normally solid, an effective dispersing amount of a pharmaceutically acceptable dispersing agent and water. The water and about (40) percent or more peroxide forms a paste. Addition of the dispersing agent/surfactant to a non-flowing organic paste resulted in the formation of a shear thinning aqueous dispersion. The aqueous dispersions can also contain optional components such as thickening agents and anionic emulsifiers.04-14-2011
20110082224BIODEGRADABLE IMPACT-MODIFIED POLYMER COMPOSITIONS - The invention relates to a impact-modified bio-degradable polymer composition having large particle size impact modifiers dispersed in a continuous biodegradable polymer phase. The impact modifiers have a core-shell morphology and have average sizes of greater than 250 nm. The impact-modified composition has good impact properties and low haze. The biodegradable polymer is preferably a polylactide or polyhydroxy butyrate. The composition comprises 30-99.9 weight percent of degradable polymer and 0.1 to 15 weight percent of one or more impact modifiers.04-07-2011
20110041529COMPOSITIONS OF HYDROCHLOROFLUOROOLEFINS - The present invention relates to solvent/cleaner and heat transfer fluid compositions comprising at least one hydrochlorofluoroolefin (HCFO), 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer. The HCFO of the present invention can be used in combination with co-agents including, hydrofluorocarbons (HFCs), hydrofluoroolefins (HFOs), hydrocarbons, ethers including hydrofluoroethers (HFEs), esters, ketones, alcohols, 1,2-transdichloroethylene and mixtures thereof.02-24-2011
20110034632POLYMERIZATION OF FLUOROPOLYMERS USING POLYCAPROLACTONE - The present invention relates to a method for the polymerization of fluoromonomers using non-fluorinated polycaprolactone, and to the fluoropolymers formed thereby. Specifically, the method of the polymerization uses one or more polycaprolactone, or salts thereof.02-10-2011
20110034612FUNCTIONAL MBS IMPACT MODIFIERS FOR USE IN ENGINEERING RESINS - The invention relates to a methylmethacrylate-butadiene-styrene (MBS) core/shell polymer impact modifier containing functionalization in the shell. The functionalized MBS is useful as an impact modifier in engineering resins, and especially in blends of engineering resins, particularly where the blend contains both functional and non-functional resins. One specific engineering resin blend having excellent low temperature impact performance is a polycarbonate (PC)/polyethylene terephthalate (PET) blend with the functional MBS of the present invention.02-10-2011
20110017661CAUSTIC RESISTANT MEMBRANE - The invention relates to caustic resistant membranes formed by solvent casting a blend of one or more polyvinylidene fluoride polymers with one or more acrylic polymers.01-27-2011
20110009678COMPOSITIONS CONTAINING A COMBINATION OF Z AND E STEREOISOMERS OF HYDROFLUOROOLEFINS - Disclosed are the combinations containing Z and E stereoisomers of hydrofluoroolefins where the more toxic isomer is less than about 30% weight of the combination (vs the sum of Z+E), to minimize the toxicity impact in the applications they will be used for such as cooling and heat fluids, foams blowing agents or solvents. Also disclosed are means to obtain combinations containing Z and E stereoisomers of hydrofluoroolefins.01-13-2011
20110001080STABLE FORMULATED SYSTEMS WITH CHLORO-3,3,3-TRIFLUOROPROPENE - The present invention relates to formulated systems of 1-chloro-3,3,3-trifluoropropene (R-1233zd) and/or 2-chloro-3,3,3-trifluoropropene (R-1233xf) that are sufficiently thermally and chemically stable such that they can be effectively used sans additional stabilizers. The formulations of the present invention are particularly useful compositions for refrigeration, heat transfer, and foam pre-mixes.01-06-2011
20100330286AQUEOUS EMULSION POLYMER FOR SCRUB RESISTANCE AND WET ADHESION - An aqueous emulsion polymer and a method for preparing the aqueous emulsion polymer, where the aqueous emulsion polymer is useful in an aqueous coating composition to provide good scrub resistance while maintaining wet adhesion of the aqueous coating composition.12-30-2010
20100326517HIGH EFFICIENCY PHOTOVOLTAIC MODULES - The invention relates to high efficiency solar collection devices having a matte surface, a low refractive index surface, or both, that increases solar radiation transmission into the device. The matte surface is on a thermoplastic and may be provided in many ways, such as by a matting agent, by the use of a matte chill roll, embossing, or other techniques. The matte and/or low refractive index surface may be a coating, film (single or multi-layer) or sheet (single or multi-layer). The invention is especially useful in both rigid and flexible photovoltaic modules.12-30-2010
20100326095USE OF R-1233 IN LIQUID CHILLERS - This invention relates to the use of chloro-trifluoropropenes as refrigerants in negative-pressure liquid chillers and methods of replacing an existing refrigerant in a chiller with chloro-trifluoropropenes. The chloro-trifluoropropenes, particularly 1-chloro-3,3,3-trifluoropropene, have high efficiency and unexpectedly high capacity in liquid chiller applications and are useful as more environmentally sustainable refrigerants for such applications, including the replacement of R-123 and R-11.12-30-2010
20100304270AQUEOUS POLYVINYLIDENE FLUORIDE COMPOSITION - The invention relates to an aqueous fluoropolymer, and preferably polyvinylidene fluoride (PVDF), composition for manufacturing electrodes for use in non-aqueous-type electrochemical devices, such as batteries and electric double layer capacitors. The composition contains aqueous PVDF binder, and one or more powdery electrode-forming materials. In one embodiment, the composition is free of fluorinated surfactant In another embodiment, one or more fugitive adhesion promoters are added. The electrode formed from the composition of the invention exhibits interconnectivity and irreversibility that is achieved from the use of aqueous PVDF binder.12-02-2010
20100273958ACRYLIC-BASED RUBBER MODIFIED THERMOSET COMPOSITION - The invention relates to a liquid rubber acrylic block copolymer, and its use in modifying a thermoset composition. The liquid rubber acrylic block copolymer adds toughness and flexibility to a thermoset composition. The acrylic block copolymers are especially useful for modifying epoxy compositions.10-28-2010
20100258162PHOTOVOLTAIC MODULE USING PVDF BASED FLEXIBLE GLAZING FILM - The invention relates to flexible photovoltaic (PV) modules, and in particular to those having a polyvinylidene fluoride (PVDF) glazing layer. The PVDF layer may be a monolayer or a multi-layer structure.10-14-2010
20100249012HARD SURFACE CLEANER CONTAINING POLYFUNCTIONAL SULFONIC ACID - The invention is directed toward improved aqueous hard surface cleaning compositions which include one or more polyfunctional sulfonic acids. The inclusion of one or more polysulfonic acids in a hard surface composition provides for improved removal of insoluble salt deposits resulting from hard water.09-30-2010
20100234642NAPHTHENIC HYDROCARBON ADDITIVES FOR DIARYL PHOSPHIDE SALT FORMATION - The invention relates to the use of polycyclic aromatic hydrocarbons (PAHs) such as naphthalene and its alkyl, aryl, or heteroatom substituted analogs, that act as catalysts in the presence of an alkali metal (Li, K, Na) for the reduction of electron-deficient and electron-rich triaryl phosphines to their corresponding alkali metal diaryl phosphide salts. The process is also useful for the catalysis of triaryl phosphine chalcogen adducts such as the sulfides, oxides, and selenides, diaryl(halo)phosphines, triaryl phosphine-borane adducts, and tetra-aryl bis(phosphines) that can also be reduced to their corresponding alkali metal diaryl phosphide salts. The invention also relates to small molecule PAHs and polymer tethered PAHs naphthenics.09-16-2010
20100233461HIGH SOLAR REFLECTIVITY, COLORED MULTI-LAYERED COMPOSITION - The invention relates to a colored, multi-layered composition having a high level of Total Solar Reflectance (TSR). The composition includes a thin top, weatherable layer having a minimal amount of colored pigment suitable for optical hiding. In one embodiment a pigmented topcoat having less than 12 percent colored (non-white) pigment in a KYNAR AQUATEC emulsion (Arkema Inc.) is placed over a white elastomeric acrylic primer on a substrate to produce a colored multiplayer composition with a TSR of greater than 70%.09-16-2010
20100215948RUBBERY-BLOCK CONTAINING POLYMERS, FIBER SIZINGS THEREOF AND COMPOSITES THEREOF - The present invention relates generally to sizing compositions for fibers used in composite materials. More specifically, this invention relates to siloxane fiber sizing solutions comprising rubbery-polymers and their use in preparing composite materials. Using the sizings of the present invention not only improves the energy absorption of the composite materials made thereof, but also maintains the interfacial strength of composite materials. Particularly, the rubbery-polymers of the present invention are functionalized with chemical groups that react to the fiber surface and/or to the polymeric resin. In addition, because the rubbery-polymer is incorporated as one block of a block copolymer, it advantageously improves both, the interfacial strength and energy absorption.08-26-2010
20100210781PROCESS AND PERFORMANCE AID FOR CARBON NANOTUBES - A polymer composition which includes carbon nanotubes in a resin matrix such as cyclic butylene terephthalate where the resin matrix is compounded into a polymer matrix. The carbon nanotube resin matrix is compatible in a wide variety of polymer matrixes having many end uses. The resin matrix provides good compatibility with many polymer systems, e.g., polyamides, polyesters, acrylics and is easy to use exhibiting a low melting point and low viscosity in melt and provides for a polymer matrix having good properties, including a higher electrical conductivity and/or increased mechanical properties.08-19-2010
20100203346TRANSPARENT OR TRANSLUCENT EXTRUDED POLYAMIDE - The invention relates to extruded transparent or translucent article that have been melt calendered to improve the physical properties and optical clarity. The polyamide article is a sheet, film, or profile.08-12-2010
20100197816HIGH TEMPERATURE STABLE POLYELECTROLYTES HAVING BACKBONE AROMATIC GROUPS - The invention relates to polyelectrolytes having backbone aromatic groups, and in particular to aromatic backbone group polyelectrolytes having high levels of sulfonation as well as cross-linking functionality. Preferably the polyelectrolyte back-bone is free of linear alkyl groups.08-05-2010
20100185030PROCESS FOR THE MANUFACTURE OF HYDROFLUOROOLEFINS - In this invention we are disclosing a process for the synthesis of hydrochlorofluoro olefins (HCFO) and/or hydrofluoroolefins (HFO). The process is based on the following steps of liquid phase, noncatalytic fluorination of hydrochloropropenes to form hydrochlorofluoropropenes and/or hydrofluoropropenes, followed by gas phase, catalytic fluorination of the hydrochlorofluoropropenes to form hydrofluoropropenes.07-22-2010
20100185029TWO STEP PROCESS FOR THE MANUFACTURE OF HYDROFLUOROOLEFINS - The present invention discloses a process for the synthesis of hydrofluoroolefins (HFO). The process is based on the following two steps: the liquid phase fluorination of a hydrochloropropane(s) to hydrofluoropropane(s) (HFP) followed by the dehydrofluorination of the hydrofluoropropane(s) (HFP) to hydrofluoroolefins (HFO).07-22-2010
20100181524STABILIZED HYDROCHLOROFLUOROOLEFINS AND HYDROFLUOROOLEFINS - Disclosed is a combination of hydrofluoroolefins and/or hydrochlorofluoroolefins with stabilizers wherein the stabilizers minimize the degradation of the hydrofluoroolefins and hydrochlorofluoroolefins during storage, handling and use yet allow for atmospheric degradation. The combinations exhibit low or zero ozone depletion potential and lower global warming potential making them of interest as replacements for chlorofluorocarbons and hydrfluorocarbons. The combinations of the present invention comprise hydrofluoroolefins and/or hydrochlorofluoroolefins in combination with a stabilizer or stabilizers selected from free radical scavengers, acid scavengers, oxygen scavengers, polymerization inhibitors and combinations thereof.07-22-2010
20100179237THERMOPLASTIC FOAM BLOWING AGENT COMBINATION - A blowing agent for thermoplastic foams such as extruded polystyrene foam is disclosed. The blowing agent is a blend of a low solubility blowing agent, such as 1,1,1,2-tetrafluoroethane, and a dichloroethylene such as trans-1,2-dichloroethylene. The blowing agent combination enhances processability of thermoplastic foam.07-15-2010
20100175742PHOTOVOLTAIC MODULES HAVING A POLYVINYLIDENE FLUORIDE BACKSHEET - The invention relates to a photovoltaic module for capturing and using solar radiation having as a backsheet a composition containing polyvinylidene fluoride. The polyvinylidene fluoride backsheet layer is exposed to the environment and provides chemical resistance, low water vapor transmission, electrical insulation, and UV light protection.07-15-2010
20100117035ELECTROCONDUCTIVE TIN OXIDE HAVING HIGH MOBILITY AND LOW ELECTRON CONCENTRATION - Tin oxide having high mobility and a low electron concentration, and methods for producing layers of the tin oxide layers on a substrate by atmospheric pressure chemical vapor deposition (APCVD) are disclosed. The tin oxide may undoped polycrystalline n-type tin oxide or it may be doped polycrystalline p-type tin oxide. When the layer of tin oxide is formed on a crystalline substrate, substantially crystalline tin oxide is formed. Dopant precursors for producing doped p-type tin oxide are also disclosed.05-13-2010
20100113629 HYDROFLUOROPROPENE BLOWING AGENTS FOR THERMOPLASTICS - The present invention relates to blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3, 3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited to, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32). The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.05-06-2010
20100105789BLOWING AGENT COMPOSITIONS OF HYDROFLUOROOLEFINS AND HYDROCHLOROFLUOROOLEFINS - The present invention relates to blowing agent compositions comprising (1) at least one hydrofluoroolefin (HFO) and (2) at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HFOs of component (1) include, but are not limited too, 3,3,3-trifluoropropene (HFO-1243zf), 1,2,3,3,3-pentafluoropropene (HFO-1225ye), cis- and/or trans-1,3,3,3-tetrafluoropropene (HFO-1234ze), and 2,3,3,3-tetrafluoropropene (HFO 1234yf), and mixtures thereof. The HCFOs of component (2) include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and mixtures thereof. The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.04-29-2010
20100105788BLOWING AGENT COMPOSITION OF HYDROCHLOROFLUOROOLEFIN - A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.04-29-2010
20100087557BLOWING AGENT COMPOSITION OF HYDROFLUOROPROPENE AND HYDROCHLOROFLUOROOLEFIN - A blowing agent for thermosetting foams is disclosed. The blowing agent is the hydrofluoropropene HFO-1243zf in combination with a hydrochlorofluoroolefin (HCFO) selected from HCFO-1233zd, HCFO-1233xf and HCFO-1223. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.04-08-2010
20100076100BLOWING AGENT COMPOSITION OF HYDROCHLOROFLUOROOLEFIN AND HYDROFLUOROOLEFIN - A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234yf in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.03-25-2010
20100062669MULTI-COMPONENT FIBERS CONTAINING HIGH CHAIN-LENGTH POLYAMIDES - This invention relates to multi-component fibers made of at least 40 weight percent, and preferably over 50 weight percent of one or more high chain length polyamides. The fibers have both a high tear strength and good tensile strength. The fibers can be used to produce woven and non-woven articles having excellent toughness.03-11-2010
20100056657BLOWING AGENT COMPOSITION OF HYDROCHLOROFLUOROOLEFIN AND HYDROFLUOROOLEFIN - A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234ze in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.03-04-2010
20100055198HARD SURFACE CLEANING AND DISINFECTING COMPOSITION - A neutral pH aqueous ready-to-use cleaning and disinfectant compositions include hydrogen peroxide as an active disinfecting constituent including a C1-C6 monohydric alcohol, and a surfactant or surfactant mixture. Methods of cleaning and disinfecting surfaces are also disclosed.03-04-2010
20100029835CARBOXYLIC ACID/ANHYDRIDE COPOLYMER NANOSCALE PROCESS AIDS - The present invention relates to copolymer process aids having a carboxylic anhydride or acid functionality and a hydrophobic functionality. The copolymer process aid can be used in the exfoliation of a nanoclay, where it can be made in situ; and can also serve as a compatibilizer for exfoliated nanoclays with a polymer matrix, including with impact modified polymer matrices.02-04-2010
20100010172IMPACT MODIFIER COMPOSITION FOR TRANSPARENT THERMOPLASTICS - The present invention relates to a toughened transparent thermoplastic composite of a transparent thermoplastic and a block copolymer having a block of a random copolymer and an elastomeric block. One preferred embodiment is a polycarbonate that is modified with a block copolymer having a methyl methacrylate (MMA) and naphthyl methacrylate or a substituted naphthyl methacrylate block and an elastomeric block. This block copolymer has excellent miscibility with polycarbonate resin, even at elevated temperature, producing transparent polycarbonate blends. The blend can provide a toughened strength polycarbonate while maintaining its excellent optical properties.01-14-2010
20100004375IMPACT MODIFIED POLYPHENYLENE SULFIDE - The invention relates to a process for improving the impact resistance of polyphenylene sulfide (PPS) using a functional polyolefin and an elastomer, in which the functional polyolefin and elastomer are pre-compounded prior to combination with the PPS. The pre-compounding of the PPS additives prior to addition of the additives to the PPS provides a composition having vastly improved impact and strain at break properties. Especially useful functional polyolefins are LOTADER resins (Arkema Inc.) and especially useful elastomers are PEBAX resins (Arkema Inc.).01-07-2010
20100003486BREATHABLE, DEET-RESISTANT POLYETHER BLOCK POLYAMIDE - The invention relates to a polyether block amide film, having both resistance to N,N-diethyl-3-methylbenzamide (DEET) insecticide according to MTL-DTL-31011B along with a high level of breathability (>700 g/m01-07-2010
20090283451COMPOSITIONS TO MITIGATE COKE FORMATION IN STEAM CRACKING OF HYDROCARBONS - The invention relates to a combination of compounds and a process using such combination useful for reducing or preventing coke formation in thermal cracking furnaces such as ethylene steam crackers. The combination is comprised of one or more compound of the formula R—S11-19-2009
20090270559ACID FUNCTIONALIZED GRADIENT BLOCK COPOLYMERS - The present invention relates to a class of acid functionalized gradient block copolymers, processes for obtaining them and to their uses including but not limited to hair fixatives, toughening agents, and adhesives. Surprisingly, the applicant has discovered the aforementioned class of acid functionalized gradient block copolymers have advantageous properties and can find utility in a wide variety of application areas. These polymers are easily prepared by sequential monomer addition (i.e., “one-pot” synthesis) and the process does not require any post polymerization modification steps. The aforementioned polymers are derived from commonly utilized monomers. The use of common monomers provides both an economic advantage and an inherent safety advantage, e.g., the common monomers are considered biocompatible.10-29-2009
20090224421PROCESS FOR FORMING MULTI-LAYER MOLDED ARTICLES - The invention relates to a rotomolding process for forming a multi-layer article of two different polymers with different melting points in which an outer layer polymer powder is added to a rotational molder along with an inner layer polymer powder that is separated from the outer layer powder by a release film. The release film has a particular melting point that is greater than that of the outer layer polymer and preferably between the melting points of the inside layer and outside layer polymers. In one embodiment, the release layer forms an enclosure or bag in which the inner layer (higher melting point) powder is enclosed. In another embodiment the release film forms a barrier between an insulated cavity and the mold. The process provides a means for a “one-shot” rotomolding method.09-10-2009
20090221776POLYMERIZATION OF FLUOROPOLYMERS USING NON-FLUORINATED SURFACTANTS - The present invention relates to a method for the polymerization in an aqueous medium of monomers, and especially of fluoromonomers, using non-fluorinated surfactants; and the fluoropolymers formed therefrom. Specifically, the method of the polymerization uses one or more non-fluorinated surfactants selected from the group consisting of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid, and salts thereof. Additionally, the use of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid as surfactants in aqueous free radical polymerization is also novel.09-03-2009
20090208657SCRATCH MASKING COATING FOR GLASS CONTAINERS - The present invention provides a scratch masking coating system for glass containers such as bottles that is adaptable to a variety of bottle surface and application conditions. The scratch masking coating is applied as an oil in water emulsion which provides flexibility in handling and application techniques while minimizing handling problems. In the present invention, the oil in water emulsion is treated with an emulsion breaker or destabilizer so that the emulsion is destabilized or broken after application to the surface to be treated. The destabilization or breaking is instigated by the addition of an emulsion breaker or heat to the emulsion in sufficient quantity to provide the desired break time.08-20-2009
20090203864ULTRA-HIGH MOLECULAR WEIGHT POLY(VINYLIDENE FLUORIDE) - The invention relates to a polyvinylidene fluoride polymer having an ultra-high molecular weight, and unexpected physical properties. The ultra-high molecular weight polymer is clear, has a lower melting point, reduced crystallinity, excellent impact resistance, and a high elongation at the yield point. The ultra-high molecular weight polyvinylidene fluoride can be alone, or blended with other polymers, in final applications and articles.08-13-2009
20090202759FLEXIBLE MULTILAYER VINYLIDENE FLUORIDE TUBES - The invention relates to a tough, flexible multi-layer tube or other structure having a vinylidene fluoride contact layer. Such a tube is especially useful for high-purity contact applications, and contact where chemical resistance is needed. The vinylidene fluoride layer is melt-processible and may be a homopolymer, copolymer or terpolymer.08-13-2009
20090176939SEEDED GROW-OUT RUBBER POLYMERIZATION PROCESS - The invention relates to a high productivity process for the production of rubber latex particles. This improved productivity process involves using a seeded grow-out process to prepare polybutadiene rubber latex. The use of a pre-formed seed latex reduces cycle time relative to an in situ polybutadiene seed process. It also provides better particle size control. The rubber latex particles can be used for impact modification of thermoplastic compositions.07-09-2009
20090149600IMPACT MODIFIED THERMOPLASTIC RESIN COMPOSITION - This invention relates to a thermoplastic resin composition having excellent impact resistance and molded appearance. The thermoplastic resin is a polycarbonate, polyester-based resin or a blend of polycarbonate and a polyester-based resin containing up to 30 percent by weight of at least one core-shell impact modifier having little or no styrene in the core.06-11-2009
20090142537TRANSPARENT POLYCARBONATE BLEND - The invention relates to a transparent thermoplastic blend of polycarbonate (PC) and a copolymer of methyl methacrylate (MMA) and naphthyl methacrylate or a substituted naphthyl methacrylate. This copolymer has excellent miscibility with polycarbonate resin, even at elevated temperature, producing transparent polycarbonate blends. The blend provides an improved scratch resistance of polycarbonate while maintaining its excellent optical properties.06-04-2009
20090111915ACRYLIC COPOLYMER FOR USE IN HIGHLY FILLED COMPOSITES - The invention relates to an acrylic copolymer additive useful as a process aid in highly filled polyvinyl chloride (PVC) and chlorinated polyvinyl chloride (CPVC) composites. The acrylic additive is especially useful in highly filled PVC flooring tiles, rolled flooring, pipe and siding. The acrylic copolymer additive contains from 50 to 79 weight percent of methyl methacrylate monomer units, and has a Tg of less than 90° C.04-30-2009
20090068386ALLOY COMPOSITION USEFUL FOR FLUID TRANSPORT OBJECTS - The present invention relates to a novel polyamide alloy composition that is useful for forming objects that may be used for the storage and transport of fluids. The polyamide alloy is a blend of at least one polyamide and at least one modified polyolefin having both medium to hard and soft domains. The polyamide forms the continuous phase of the alloy. The alloy may also contain, and preferably does contain, a thermal and light stabilization compound, at least one unmodified polyolefin, and at least one plasticizer. The polyamide alloy composition is useful in forming tanks, hoses and tubes used in the transport of liquid or gaseous fluids, including fluids under pressure.03-12-2009
20090065737POLYMERIZATION CONTROLLERS FOR COMPOSITES CURED BY ORGANIC PEROXIDE INITIATORS - The use of nitroxides to control free radical cured resin systems used in the production of thermosetting materials such as bulk molded compositions, sheet molded compositions, and pultrusions is disclosed. The invention could also be employed in other resin systems where control of kinetics would be desirable such as in adhesive formulations, in solid surface composites, and certain types of polyester casting resins.03-12-2009
20090048383CLAYS PRE-ACTIVATED WITH INTERCALATED POLYMERIZATION INITIATION SITES - A modified clay may be made by contacting a clay with an unsaturated cationic compound and an alkoxyamine, or an adduct thereof. The resulting pre-activated clay, which contains a cationic alkoxyamine bound to the clay, may be further treated with a monomer to provide a polymer that is bound to the clay, thereby forming a nanocomposite material. The nanocomposite material may in turn be blended with another polymer prepared from the same or a different monomer.02-19-2009
20080312377Low Surface Energy Block Copolymer Preparation Methods and Applications - Methods for the preparation of low surface energy block co-polymers are disclosed. The block co-polymers comprise at least two blocks, each of which comprises, in polymerized form, an acrylic monomer, a methacrylic monomer, or a mixture thereof. At least one block is a low surface energy block, which comprises, in polymerized form, a low surface energy monomer Low surface energy macroinitiators useful in forming the block co-polymers are also disclosed. The block co-polymers may be prepared by nitroxide mediated controlled free radical polymerization.12-18-2008
20080281012Block Copolymer Foam Additives - The present invention provides an additive for thermoplastic polymer foams which provide for enlarged cell size or with decreased density with minimal impact on the thermal mechanical properties of the thermoplastic foam. The additive is an essentially block copolymer blowing agent compatibilizer. Including the additive in a thermoplastic foaming composition comprised of a thermoplastic polymer resin and a physical blowing agent provides for the production of foam having enlarged cell size or with decreased density and minimal impact on the thermal mechanical properties of the thermoplastic foam. The block copolymer compatibilizer has at least a first block having at least one functionality compatible with the thermoplastic resin and at least one second block having a functionality compatible with the blowing agent.11-13-2008
20080261050Multilayer Fluoropolymer Films - The invention relates to a multi-layer film having at least one fluoropolymer layer, useful for high-purity contact applications. Preferably the fluoropolymer layer(s) are polyvinylidene fluoride polymers and copolymers.10-23-2008
20080261019Pvc/Wood Composite - The present invention relates to a thermoplastic/natural cellulosic fiber composite, and more specifically to a high molecular weight compatibilizer within that composite resulting in both a high flex strength and high modulus and significant reduction in water absorption. The compatibilizer is preferably a terpolymer comprising: a) 0.5-20 percent by weight of monomer units selected from the group consisting of maleic anhydride, substituted maleic anhydride, mono-ester of maleic anhydride, itaconic anhydride, maleic acid, fumaric acid, crotonic acid, acrylic acid and methacrylic acid; b) 0 to 40 percent by weight of monomer units selected from styrene and functionalized styrene; and c) 40 to 98.5 percent by weight of monomer units selected from the group consisting of C10-23-2008
20080242833BLEND OF IONIC (CO)POLYMER RESINS AND MATRIX (CO)POLYMERS - The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.10-02-2008
20080242819BLEND OF IONIC (CO)POLYMER RESINS AND MATRIX (CO)POLYMERS - The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.10-02-2008
20080242805BLEND OF IONIC (CO)POLYMER RESINS AND MATRIX (CO)POLYMERS - The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.10-02-2008
20080242791Methods of Producing Vinyl Aromatic Polymers Using (Meth)Acrylic Macroinitiators - The present invention relates to the use of poly acrylic and/or methacrylic macroinitiators in the free radical addition reaction of vinyl aromatic monomers to improve the properties of the resulting copolymer and/or composite. More particularly, the present invention relates to the production of poly acrylic and/or poly methacrylic macroinitiators having nitroxyl end groups. Using such macroinitiators in the free radical addition reaction of vinyl aromatics such as polystyrene compatibilizes the acrylic monomer in the vinyl aromatic matrix thereby improving the properties of the resulting polymer.10-02-2008
20080241630BLEND OF IONIC (CO)POLYMER RESINS AND MATRIX (CO) POLYMERS - The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.10-02-2008
20080214414Organosulfonyl Latent Acids for Petroleum Well Acidizing - Oil wells are treated with latent acids containing a sulfonyl moiety, wherein the latent acid is capable of providing an active acid after injection into an oil well. The latent acids are converted to active acids, such as mineral acids or strong organic acids, in the oil well, with resultant dissolution of acid-soluble minerals that impede oil or gas flow. RYSO2X is an exemplary latent acid, where: R is C(1)-C(30) hydrocaryl alone, or appended to an oligomeric or polymeric chain, or substituted; X is halogen; and Y is O, S, Se, or NR or a direct bond. M is a Group IVA metal, a Group IVB metal, a Group IB metal, or a Group HB metal. Other exemplary latent acids include amine functionality.09-04-2008
20080199618Method of Strengthening a Brittle Oxide Substrate with a Weatherable Coating - The present invention relates to a method of strengthening brittle oxide pieces such as glass pieces with a siloxane-acrylate coating system that has superior weatherability, particularly hydrolytic stability. The coating system comprises a combination of a silane solution and a radiation-curable acrylate solution. The mixture is applied to a clean, brittle oxide surface. The silane solution comprises one or more silanes in a non-aqueous solvent and the radiation-curable acrylate solution comprises one or more acrylate or methacrylate monomers, acrylate or methacrylate oligomers, and initiators, such as photoinitiators.08-21-2008

Patent applications by Arkema Inc.