Molecular motion of ferrocene in a faujasite-type zeolite: a quasielastic neutron scattering study
Article Abstract:
An investigation into the dynamics of ferrocene in a KY zeolite at a range of temperatures is measured by quasielastic neutron scattering.
author: Santen, R.A. van, Kemner, E., Schepper, I.M. de, Schmets, A.J.M., Grimm, H., Overweg, A.R.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Ferrocene and dicarbonylcyclopentadienylcobalt in faujasite-type zeolites: a study of molecular motion
Article Abstract:
The anisotropic molecular motion of Fe(C5H5)2 and Co(C5H5)(CO)2 molecules in the supercages of faujasite-like zeolites was studied by NMR and Mossbauer spectroscopy. It was observed that below 225 K the Fe(C5H5)2 molecules have no translational freedom, the only motion being rapid rotation of the cyclopentadienyl rings about their 5-fold axes. As the temperature is increased, the molecules gain translational freedom, and at temperatures above 358 K isotropic molecular motion was determined as the only kind of molecular motion.
author: Santen, R.A. van, Overweg, A.R., Koller, H., Haan, J.W. de, Ven, L.J.M. van de, Kraan, A.M. van der
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
Zeolites, Molecules, Coordination compounds
Small-angle neutron scattering (SANS) study of vesicles and lamellar sheets formed from mixtures of an anionic and a cationic surfactant
Article Abstract:
A study comprising of the use of static light scattering and small-angle neutron scattering to investigate samples of stacks of lamellar sheets or vesicles.
author: Bergstrom, Magnus, Pedersen, Jan Skov, Schurtenberger, Peter, Egelhaaf, Stefan U.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
subjects list: Research, Analysis, Chemistry, Chemical research, Chemistry, Physical and theoretical, Physical chemistry
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