Raman and IR spectroscopy of silver iodide/silver selenate fast ion-cinducting glasses
Article Abstract:
A study of the high temperature phase of silver iodide alpha-AgI reports on the first Raman and IR spectra of x(AgI)2.(1-x)Ag2SeO4 which forms ionic glasses containing discrete Ag+, I- and SeO42- ions at room temperatures up to 573 K, covering the glassy, partially crystallized and liquid states. The Raman and IR spectra of x(AgI)2.(1-x)Ag2SeO4 can be considered as a composite of a spectral part at low frequencies related to AgI and a part at high frequency that resembles a broadened spectrum of c-Ag2SeO4.
author: Saboungi, Marie-Louise, Cramer, Cornelia, Grimsditch, Marcos
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
Case studies, Infrared spectroscopy, Raman spectroscopy, Ionic crystals
Formation of entrapment of noble metal clusters in silica aerogel monoliths by gamma-radiolysis
Article Abstract:
An experiment was done where noble metal clusters (Ag, Au) were formed in a silica aerogel matrix by gamma-irradiation of hydrogel precursors loaded with aqueous solutions containing Ag(super +) or [AuCl4](super-). Using various techniques, results obtained showed that clusters have a crystalline fcc structure.
author: Leventis, Nicholas, Sotiriou-Leventis, Chariklia, Hund, Jared F., Tokuhiro, Akira T., Bertino, Massimo F., Farmer John, Zhang, Guohui
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Science & research, All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Gold Compounds, Analysis, Chemical properties, Aerogels
Optical properties of gold-silver iodide nanoparticle pair-structures
Article Abstract:
A template-based synthesis of gold-silver iodide particle structures with variable average spacing between the metal and semiconductor particle segments is described.
author: El-Kouedi, Mahnaz, Foss, Colby A., Jr.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Organometallic compounds
subjects list: Research, Silver compounds, Iodides, Chemistry, Physical and theoretical, Physical chemistry, Gold compounds
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