Hydrogen-bond induced surface core-level shift in isonicotinic acid

Article Abstract:

X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS) were used for studying the intermolecular hydrogen-bonding in thick films of isonicotinic acid evaporated onto rutile TiO2(110). The presence of non-hydrogen-bonded nitrogen atoms in the surface layer may be responsible for the origin of the surface core-level shift.

author: O'Shea, James N., Schnadt, Joachim, Briihwiler, Paul A., Hillesheimer, Hendrik, Patthey, Luc, Krempasky, Juraj, Chuankui Wang, Yi Luo, Agren, Hans
Usage, Observations, Hydrogen bonding, X-ray spectroscopy, Chemical properties

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Nucleation stage in the Ti(OPr(super i))(sub 4) sol-gel process

Article Abstract:

A spectroscopic study of the initial stage of the Ti(OPr(super i))(sub 4) sol-gel process is carried out. The experimental results show that the hydrolysis/condensation reaction takes place during the mixing of the reagents and at times it results in the creation of nanosize .

author: Soloviev, A., Tufeu, R., Sanchez, C., Kanaev, A. V.
Nucleic acid bases

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Photoelectorchemical investigation on electron transfer mediating behaviors of polyoxometalate in UV-illuminated suspensions of TiO2 and Pt/TiO2

Article Abstract:

The study conducted reveals that polyoxometalates play an important role in semi conductor photocatalysis in order to determine its kinetics and mechanisms. In short, this study describes polyoxometalates as a reversible electron shuttle.

author: Fisher, Adrian C., Lim, Sangyun, Hyunwoong Park, Wonyong Choi
Electric properties, Electron transport, Dynamics, Dynamics (Mechanics)

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subjects list: Research, Optical properties, Chemistry, Physical and theoretical, Physical chemistry, Titanium compounds
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