High resolution X-ray photoelectron spectroscopy of chlorine-terminated GaAs(111)A surfaces

Article Abstract:

Oxide-terminated and Cl-terminated GaAs(111)A surfaces are characterized in the As and Ga 3d regions by high-resolution, soft X-ray photoelectron spectroscopy. The result has confirmed that wet chemical etching allows for the formation of well-defined, Cl-terminated GaAs(111)A surfaces free of detectable elemental As, which has provided a starting point for further functionalization of GaAs.

author: Webb, Lauren J., Brunschwig, Bruce S., Traub, Matthew C., Biteen, Julie S., Michalak, David J., Lweis, Nathan S.
Science & research, Research, Crystals, Optical properties, X-ray spectroscopy, Surface chemistry, Crystal etching

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TAT peptide immobilization on gold surfaces: A comparison study with a thiolated peptide and alkylthiols using AFM, XPS, and FT-IRRAS

Article Abstract:

A gold surface is functionalized by three different methods, adsorption from solution, microcontact printing, and dip-pen nanolithiography using a TAT peptide. It is concluded that the structure of the alkyl chains of the TAT peptides is fairly disordered and different after each procedure.

author: Ivanisevic, Albena, Youngnam Cho
All Other Basic Organic Chemical Manufacturing, All Other Basic Inorganic Chemical Manufacturing, Industrial Organic Chemicals, Industrial inorganic chemicals, not elsewhere classified, Mercaptans, Gold Compounds, Thiols

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Covalent attachment of TAT and thiolated alkyl molecules on GaAs surfaces

Article Abstract:

Four TAT peptide fragments are used to functionalize GaAs surfaces by adsorption from solution. Two well-studied alkylthiols, mercaptohexdeconoic acid (MHA) and 1-octadecanethiol (ODT) are utilized as references to understand the structure of the TAT peptide monolayer on GaAs.

author: Ivanisevic, Albena, Youngnam Cho
Photoelectron spectroscopy

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subjects list: Analysis, Gallium arsenide, Structure, Chemical properties, Spectra, Alkyl groups
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