Clarification of phase separation mechanism of sodium borosilicate glasses in early stage by nuclear magnetic resonance

Article Abstract:

A new study uses nuclear magnetic resonance spectra to examine the atomic-scale structural changes in the early stage of spinodal phase separation for sodium borosilicate glasses.

author: Yazawa, Tetsuo, Kuraoka, Koji, Akai, Tomoko, Umesaki, Normiasa, Du, Wei-Feng
Metallic glasses

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Dynamics of proton transfer in the sol-gel-derived P(sub 2)O(sub 5)-SiO(sub 2) glasses

Article Abstract:

Water diffusion and its role on the proton conducted in the sol--gel-derived porous P(sub 2)O(sub 5)-SiO(sub 2) glasses are discussed, which display a conductivity higher than ~10(super -2)S/cm at room temperature. These inorganic glass membranes have potential as the electrolyte of fuel cells.

author: Koltypin, Yuri, Akai, Tomoko, Zaban, Afie, Gedanken, Aharon, Nogami, Masayuki, Daiko, Yusuke, Kasuga, Toshihiro
Science & research, All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Phosphorus & Compounds, Elemental Phosphorus, Charge transfer, Phosphorus, Chemical properties, Atomic properties

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Effect of cooling rate on pore distribution in quenched sodium borosilicate glasses

Article Abstract:

Research into the distribution of pores based on the spinodal phase separation in sodium borosilicate glass found the decreasing cooling rate lead to an increase in pore volume and surface area.

author: Yazawa, Tetsuo, Kuraoka, Koji, Du, Wei-Fang
Research and Development in the Physical, Engineering, and Life Sciences, Chemistry, Analysis, Chemical research

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subjects list: Research, Chemistry, Physical and theoretical, Physical chemistry
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