Aggregation-induced emission enhancement of 2-(2'-hydroxyphenyl)benzothiazole-based excited-state intramolecular proton-transfer compounds

Article Abstract:

A novel class of 2-(2'-hydroxyphenyl)benzothiazole-based (HBT-based) excited-state intramolecular proton-transfer (ESIPT) compounds, N,N'-di[3-hydroxyl-4-(2'-benzothiazole)phenyl]isophthalic amide (DHIA) and N,N'-di[3-hydroxy-4-(2'-benzothiazole)phenyl]5-tert-butyl-isophthalic amide (DHBIA) is synthesized and their properties of their nanoparticles in THF/[H.sub.2]O mixed solvent are examined. The results have shown that the different stacking modes are responsible for different extents in the emission enhancement.

Author: Shayu Li, Guoqi Zhang, Yi Li, Guoqiang Yang, Qian Wang, Yan Qian, Shuangqing Wang, Huijun Xu, Changzhang Li
Observations, Optical properties, Calorimetry, Scanning electron microscopes, Phenyl compounds

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Aggregation-induced emission enhancement of 2-(2'-hydroxyphenyl)benzothiazole-based excited-state intramolecular proton-transfer compounds

Article Abstract:

A novel class of 2-(2'-hydroxyphenyl)benzothiazole-based (HBT-based) excited-state intramolecular proton-transfer (ESIPT) compounds, N,N'-di[3-hydroxyl-4-(2'-benzothiazole)phenyl]isophthalic amide (DHIA) and N,N'-di[3-hydroxy-4-(2'-benzothiazole)phenyl]5-tert-butyl-isophthalic amide (DHBIA) is synthesized and their properties of their nanoparticles in THF/[H.sub.2]O mixed solvent are examined. The results have shown that the different stacking modes are responsible for different extents in the emission enhancement.

Author: Shayu Li, Guoqi Zhang, Yi Li, Guoqiang Yang, Qian Wang, Yan Qian, Shuangqing Wang, Huijun Xu, Changzhang Li
Petrochemical Manufacturing, Benzene, Fluorescence, Thermogravimetry, Chemical synthesis, Chemical properties

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Subjects list: Analysis, Thermal properties, Structure
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